Laurionite
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Laurionite
Laurionite (PbCl(OH)) is a lead halide mineral. It forms colorless to white crystals in the orthorhombic crystal system and is dimorphous with paralaurionite, both members of the matlockite group. It was first described in 1887 for an occurrence in the Laurium District, Attica, Greece, and named after the town Laurium. It occurs as an oxidation product in lead ore deposits, and is also produced on lead-bearing slag by reaction with saline solutions. It occurs associated with paralaurionite, penfieldite, fiedlerite, phosgenite, cerussite and anglesite Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and .... References Halide minerals Orthorhombic minerals Minerals in space group 62 Lead minerals {{halide-mineral-stub ...
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Paralaurionite
Paralaurionite is a colorless mineral consisting of a basic lead chloride PbCl(OH) that is dimorphous with laurionite. It is a member of the matlockite group. The name is derived from para-, the Greek for "near", and laurionite, because of its polymorphic relationship to it. Bright, yellow tips of thorikosite can form on paralaurionite crystals and paralaurionite may also be intergrown with mendipite. Occurrence It was first described in 1899 for an occurrence in slag in Laurium, Attica, Greece. In 1952 an occurrences of it was reported from the Mammoth Mine, Arizona. It occurs in lead bearing slag which has been exposed to seawater. It also occurs in polymetallic ore deposits. It occurs associated with laurionite, penfieldite, fiedlerite, phosgenite in slag deposits; and with leadhillite, matlockite, cerussite, hydrocerussite, diaboleite Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named ''diaboleite'', from the Gr ...
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Matlockite
Matlockite is a rare lead halide mineral, named after the town of Matlock in Derbyshire, England, where it was first discovered in a nearby mine. Matlockite (chemical formula: PbFCl) gives its name to the matlockite group which consists of rare minerals of a similar structure. Description The mineral, a lead fluorochloride (formula PbFCl), was discovered sometime around the early 1800s at Bage Mine at Bolehill near Matlock, together with specimens of phosgenite and anglesite. Although phosgenite was known at this time, it seems likely that matlockite itself remained unappreciated as a new mineral for some fifty years. It was given the name by Greg in 1851. The first mention of Matlockite may have been in Mawe's Mineralogy of Derbyshire in 1802 in which he gives a detailed description of phosgenite, which is then followed by a mention of a mineral he refers to as "glass lead" - a description which does rather equate to the appearance of matlockite. It is a light, translucent cr ...
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Halide Minerals
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have polyatomic anions. Examples include the following: *Atacamite * Avogadrite (K,Cs)BF *Bararite (β) *Bischofite * Brüggenite *Calomel *Carnallite *Carnallite * Cerargyrite/Horn silver AgCl * Chlorargyrite AgCl, bromargyrite AgBr, and iodargyrite AgI *Cryolite *Cryptohalite (a) Vanadates), 09 Silicates: * ''neso-'': insular (from Greek , "island") * ''soro-'': grouped (from Greek , "heap, pile, mound") * ''cyclo-'': ringed (from Greek , "circle") * ''ino-'': chained (from Greek , "fibre", rom Ancient Greek * ''phyllo-'': sheeted (from Greek , "leaf") * ''tecto-'': of three-dimensional framework (from Greek , "of building") ;Nickel–Strunz code scheme ''NN.XY.##x'': * ''NN'': Nickel–Strunz mineral class number * ''X'': Nickel–Strunz mineral division letter * ''Y'': Nickel–Strunz mineral family letter * ''##x'': Nickel–Strunz mineral/group n ...
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Halide Mineral
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have polyatomic anions. Examples include the following: *Atacamite * Avogadrite (K,Cs)BF *Bararite (β) *Bischofite * Brüggenite *Calomel *Carnallite *Carnallite * Cerargyrite/Horn silver AgCl * Chlorargyrite AgCl, bromargyrite AgBr, and iodargyrite AgI *Cryolite *Cryptohalite (a) Vanadates), 09 Silicates: * ''neso-'': insular (from Greek , "island") * ''soro-'': grouped (from Greek , "heap, pile, mound") * ''cyclo-'': ringed (from Greek , "circle") * ''ino-'': chained (from Greek , "fibre", rom Ancient Greek * ''phyllo-'': sheeted (from Greek , "leaf") * ''tecto-'': of three-dimensional framework (from Greek , "of building") ;Nickel–Strunz code scheme ''NN.XY.##x'': * ''NN'': Nickel–Strunz mineral class number * ''X'': Nickel–Strunz mineral division letter * ''Y'': Nickel–Strunz mineral family letter * ''##x'': Nickel–Strunz mineral/group n ...
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Penfieldite
Penfieldite is a rare lead hydroxychloride mineral from the class of halides. It was named after Samuel Lewis Penfield. It has been a valid species before the founding of IMA, and was first published in 1892. It had been grandfathered, meaning the name penfieldite is still believed to refer to a valid species. When it was first described by Genth in 1892 from Laurion, Greece, the mineral had the formula of Pb3Cl4O. Properties Penfieldite grows tabular pyramidal crystals, meaning it is longer instead of being wide, and grows in the shape of a pyramid. It is a secondary mineral, meaning that rock minerals went under transformation due to changes in pressure and temperature, and penfieldite is the newly formed stable mineral after this transformation. Singular crystals are usually striped, and can grow up to 3 cm. Pure penfieldite is colorless, however, due to lattice defects or foreign admixtures, it can be white, yellow or even blue. It mainly consists of lead (77.06%) and ...
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Slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-products of recovering non-ferrous materials like copper, nickel, zinc and phosphorus). Within these general categories, slags can be further categorized by their precursor and processing conditions (e.g., Blast furnace (BF) slags, air-cooled blast furnace (ACBF) slag, basic oxygen furnace (BOF) slag, and electric arc furnace (EAF) slag) . Due to the large demand for these materials, slag production has also significantly increased throughout the years despite recycling (most notably in the iron and steelmaking industries) and upcycling efforts. The World Steel Association (WSA) estimates that 600 kg of by-products (~90 wt% is slags) are generated per tonne of steel produced. Composition Slag is usually a mixture of metal oxides and sili ...
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Orthorhombic Minerals
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primiti ...
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Anglesite
Anglesite is a lead sulfate mineral with the chemical formula PbSO4. It occurs as an oxidation product of primary lead sulfide ore, galena. Anglesite occurs as prismatic orthorhombic crystals and earthy masses, and is isomorphous with barite and celestine. It contains 74% of lead by mass and therefore has a high specific gravity of 6.3. Anglesite's color is white or gray with pale yellow streaks. It may be dark gray if impure. It was first recognized as a mineral species by William Withering in 1783, who discovered it in the Parys copper-mine in Anglesey; the name anglesite, from this locality, was given by F. S. Beudant in 1832. The crystals from Anglesey, which were formerly found abundantly on a matrix of dull limonite, are small in size and simple in form, being usually bounded by four faces of a prism and four faces of a dome; they are brownish-yellow in colour owing to a stain of limonite. Crystals from some other localities, notably from in Sardinia, are transparent and ...
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Cerussite
Cerussite (also known as lead carbonate or white lead ore) is a mineral consisting of lead carbonate (PbCO3), and is an important ore of lead. The name is from the Latin ''cerussa'', white lead. ''Cerussa nativa'' was mentioned by Conrad Gessner in 1565, and in 1832 F. S. Beudant applied the name ''céruse'' to the mineral, whilst the present form, cerussite, is due to W. Haidinger (1845). Miners' names in early use were lead-spar and white-lead-ore. Cerussite crystallizes in the orthorhombic crystal system and is isomorphous with aragonite. Like aragonite it is very frequently twinned, the compound crystals being pseudo-hexagonal in form. Three crystals are usually twinned together on two faces of the prism, producing six-rayed stellate groups with the individual crystals intercrossing at angles of nearly 60°. Crystals are of frequent occurrence and they usually have very bright and smooth faces. The mineral also occurs in compact granular masses, and sometimes in fibrous fo ...
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Phosgenite
Phosgenite is a rare mineral consisting of lead chlorocarbonate, (PbCl)2CO3. The tetragonal crystals are prismatic or tabular in habit: they are usually colorless and transparent, and have a brilliant adamantine lustre. Sometimes the crystals have a curious helical twist about the tetrad or principal axis. The hardness is 3 and the specific gravity 6.3. The mineral is rather sectile, and consequently was earlier known as corneous lead, (German ''Hornblei''). Name and occurrence The name phosgenite was given by August Breithaupt in 1820, from phosgene, carbon oxychloride, because the mineral contains the elements carbon, oxygen and chlorine. It was found associated with anglesite and matlockite in cavities within altered galena in a lead mine at Cromford, near Matlock: hence its common name cromfordite.
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Laurium
Laurium or Lavrio ( ell, Λαύριο; grc, Λαύρειον (later ); before early 11th century BC: Θορικός ''Thorikos''; from Middle Ages until 1908: Εργαστήρια ''Ergastiria'') is a town in southeastern part of Attica, Greece. It is part of Athens metropolitan area and the seat of the municipality of Lavreotiki. Laurium was famous in Classical antiquity for its silver mines, which was one of the chief sources of revenue of the Athenian state. The metallic silver was mainly used for coinage. The Archaeological Museum of Lavrion shows much of the story of these mines. It is located about 60 km SE of Athens city center, SE of Keratea and N of Cape Sounio. Laurium is situated on a bay overlooking the island of Makronisos (ancient times: Helena) in the east. The port is in the middle and gridded streets cover the residential area of Lavrio. GR-89 runs through Lavrio and ends south in Sounio. History The modern town of Laurium is at the site of the an ...
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