Isopropyl Methoxy Pyrazine
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Isopropyl Methoxy Pyrazine
Isopropyl methoxypyrazine (IPMP) is a methoxypyrazine, a class of chemical compounds that produce odors. The odor is rather undesirable and is produced by the Asian lady beetle or by the actinomycete ''Streptomyces'' sp. It can be detected by human taste at concentrations of as low as 2 nanograms per litre. Presence in wine grapes The odor of IPMP tends to be undesirable in the case of certain wines. Cabernet Sauvignon has high levels of methoxypyrazines.Oz Clarke ''Encyclopedia of Grapes'' pg 223 Harcourt Books 2001 Two methoxypyrazine compounds, 3-isobutyl-2-methoxypyrazine (IBMP) and 3-isopropyl-2-methoxypyrazine, are considered to be important determinants of green flavours in Sauvignon blanc wines. Presence in coffee IPMP is also an important flavour compound in coffee and is responsible for causing an off-taste called "potato taste" in East African coffee. The insects '' Antestiopsis'' are also implicated in causing the taste. See also * Alkylpyrazine Alkylpyrazi ...
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Methoxypyrazine
Methoxypyrazines are a class of chemical compounds that produce odors. The odors tend to be undesirable, as in the case of certain wines, or as defensive chemicals used by insects such as ''Harmonia axyridis'' which produces isopropyl methoxy pyrazine (IPMP). They have also been identified as additives in cigarette manufacture. Detection thresholds are very low, typically near 2 parts per trillion (1 ng/L). Examples of methoxypyrazines in wine grapes Cabernet Sauvignon has high levels of methoxypyrazines.Oz Clarke ''Encyclopedia of Grapes'' pg 223 Harcourt Books 2001 Two methoxypyrazine compounds, 3-isobutyl-2-methoxypyrazine (IBMP) and 3-isopropyl-2-methoxypyrazine (IPMP), are considered to be important determinants of green flavours in Sauvignon blanc wines.Marais, J., Hunter, J.J., & Haasbroek, P.D. (1999). Effect of microclimate, season and region on Sauvignon blanc grape composition and wine quality. South African Journal of Enology and Viticulture, 20, 19-30. ...
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Asian Lady Beetle
''Harmonia axyridis'' is a large Coccinellidae, lady beetle or ladybug species that is most commonly known as the harlequin, multicoloured Asian, or Asian lady beetle. This is one of the most variable species in the world, with an exceptionally wide range of colour forms. It is native to eastern Asia, but has been artificially introduced to North America and Europe to control aphids and scale insects. It is now common, well known, and spreading in those regions, and has also established in Africa and widely across South America. This species is conspicuous in North America, where it may locally be known as the Halloween beetle, as it often invades homes during October to Overwintering, overwinter. When the species first arrived in the UK, it was labelled in jest as the "many-named ladybird" due to the great quantity of vernacular names. Among those already listed other names include multivariate, southern, Japanese, and pumpkin ladybird.Ladybird Survey page "''Harmonia axyridis'' ( ...
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Streptomyces
''Streptomyces'' is the largest genus of Actinomycetota and the type genus of the family Streptomycetaceae. Over 500 species of ''Streptomyces'' bacteria have been described. As with the other Actinomycetota, streptomycetes are gram-positive, and have genomes with high GC content. Found predominantly in soil and decaying vegetation, most streptomycetes produce spores, and are noted for their distinct "earthy" odor that results from production of a volatile metabolite, geosmin. Streptomycetes are characterised by a complex secondary metabolism. They produce over two-thirds of the clinically useful antibiotics of natural origin (e.g., neomycin, streptomycin, cypemycin, grisemycin, bottromycins and chloramphenicol). The antibiotic streptomycin takes its name directly from ''Streptomyces''. Streptomycetes are infrequent pathogens, though infections in humans, such as mycetoma, can be caused by '' S. somaliensis'' and '' S. sudanensis'', and in plants can be caused by '' S. cavi ...
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Nanogram
To help compare different orders of magnitude, the following lists describe various mass levels between 10−59  kg and 1052 kg. The least massive thing listed here is a graviton, and the most massive thing is the observable universe. Typically, an object having greater mass will also have greater weight (see mass versus weight), especially if the objects are subject to the same gravitational field strength. Units of mass The table at right is based on the kilogram (kg), the base unit of mass in the International System of Units ( SI). The kilogram is the only standard unit to include an SI prefix (''kilo-'') as part of its name. The ''gram'' (10−3 kg) is an SI derived unit of mass. However, the ''names'' of all SI mass units are based on ''gram'', rather than on ''kilogram''; thus 103 kg is a ''megagram'' (106 g), not a *''kilokilogram''. The ''tonne'' (t) is an SI-compatible unit of mass equal to a megagram (''Mg''), or 103 kg. The unit is in common use for ...
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Cabernet Sauvignon
Cabernet Sauvignon () is one of the world's most widely recognized red wine grape varieties. It is grown in nearly every major wine producing country among a diverse spectrum of climates from Australia and British Columbia, Canada to Lebanon's Beqaa Valley. Cabernet Sauvignon became internationally recognized through its prominence in Bordeaux wines, where it is often blended with Merlot and Cabernet Franc. From France and Spain, the grape spread across Europe and to the New World where it found new homes in places like California's Santa Cruz Mountains, Paso Robles, Napa Valley, New Zealand's Hawke's Bay, South Africa's Stellenbosch region, Australia's Margaret River, McLaren Vale and Coonawarra regions, and Chile's Maipo Valley and Colchagua. For most of the 20th century, it was the world's most widely planted premium red wine grape until it was surpassed by Merlot in the 1990s. However, by 2015, Cabernet Sauvignon had once again become the most widely planted wine gra ...
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Sauvignon Blanc
is a green-skinned grape variety that originates from the Bordeaux region of France. The grape most likely gets its name from the French words ''sauvage'' ("wild") and ''blanc'' ("white") due to its early origins as an indigenous grape in South West France. It is possibly a descendant of Savagnin. is planted in many of the world's wine regions, producing a crisp, dry, and refreshing white varietal wine. The grape is also a component of the famous dessert wines from Sauternes and Barsac. Sauvignon blanc is widely cultivated in France, Chile, Romania, Canada, Australia, New Zealand, South Africa, Bulgaria, the states of Oregon, Washington, and California in the US. Some New World Sauvignon blancs, particularly from California, may also be called "Fumé Blanc", a marketing term coined by Robert Mondavi in reference to Pouilly-Fumé. Depending on the climate, the flavor can range from aggressively grassy to sweetly tropical. In cooler climates, the grape has a tendency to pr ...
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Antestiopsis
''Antestiopsis'' is a genus of shield bug, commonly known as antestia and the variegated coffee bug. Several species in eastern Africa are pests of coffee plants, giving the coffee beans a distinctive 'potato taste', which is thought to be caused indirectly by bacteria entering through wounds created by the insects, leading to an increase in the concentration of isopropyl methoxy pyrazine. They feed on flowers, berries and growing tips, injecting a toxic saliva that often contains the spores of the ''Ashbya'' fungus, and then suck juices out. Species Species include: *''Antestiopsis intricata'' (Ghesquiere and Carayon) *''Antestiopsis thunbergii'' (Gmelin) Control Throughout history, ''Antestiopsis'' was controlled in Kenya using pyrethrum powder. The organophosphate fenthion has been used to control the pest in Burundi. Laboratory experiments have found the essential oils of ''Thymus vulgaris'', ''Ruta chalepensis'' and ''Chenopodium ambrosioides ''Dysphania ambrosi ...
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Alkylpyrazine
Alkylpyrazines are chemical compounds based on pyrazine with different substitution patterns. Some alkylpyrazines are naturally occurring highly aromatic substances which often have a very low odor threshold and contribute to the taste and aroma of various foods including cocoa, baked goods, coffee and wines. Alkylpyrazines are also formed during the cooking of some foods via Maillard reactions. Examples File:2-Methylpyrazine.png , 2-Methylpyrazine (found in roasted sesame) File:2,3-Dimethyl Pyrazine Structural Formula V1.svg , 2,3-Dimethylpyrazine (found in roasted sesame) File:2,5-Dimethylpyrazin V1.svg , 2,5-Dimethylpyrazine (asparagus, tea, crispbread, malt, shrimp, soy, squid, Swiss chease, bread, roasted sesame) File:Tetramethylpyrazine.PNG , 2,3,5,6-Tetramethylpyrazine (nattō, fermented cocoa beans) 2-Methylpyrazine 2-Methylpyrazine was the volatile odorant found at the highest concentration in roasted sesame seed oil. 2,3-Dimethylpyrazine 2,3-Dimethylpyrazine is ...
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Pyrazines
Pyrazine is a heterocyclic aromatic organic compound with the chemical formula C4H4N2. It is a symmetrical molecule with point group D2h. Pyrazine is less basic than pyridine, pyridazine and pyrimidine. It is a ''"deliquescent crystal or wax-like solid with a pungent, sweet, corn-like, nutty odour"''. Pyrazine and a variety of alkylpyrazines are flavor and aroma compounds found in baked and roasted goods. Tetramethylpyrazine (also known as ligustrazine) is reported to scavenge superoxide anion and decrease nitric oxide production in human Granulocytes. Synthesis Many methods exist for the organic synthesis of pyrazine and its derivatives. Some of these are among the oldest synthesis reactions still in use. In the Staedel–Rugheimer pyrazine synthesis (1876), 2-chloroacetophenone is reacted with ammonia to the amino ketone, then condensed and then oxidized to a pyrazine. A variation is the Gutknecht pyrazine synthesis (1879) also based on this selfcondensation, but differ ...
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Isopropyl Compounds
In organic chemistry, propyl is a three-carbon alkyl substituent with chemical formula for the linear form. This substituent form is obtained by removing one hydrogen atom attached to the terminal carbon of propane. A propyl substituent is often represented in organic chemistry with the symbol Pr (not to be confused with the element praseodymium). An isomeric form of propyl is obtained by moving the point of attachment from a terminal carbon atom to the central carbon atom, named 1-methylethyl or isopropyl. To maintain four substituents on each carbon atom, one hydrogen atom has to be moved from the middle carbon atom to the carbon atom which served as attachment point in the ''n''-propyl variant, written as . Linear propyl is sometimes termed normal and hence written with a prefix ''n''- (i.e., ''n-''propyl), as the absence of the prefix ''n''- does not indicate which attachment point is chosen, i.e. absence of prefix does not automatically exclude the possibility of it be ...
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