Hydridonitrides
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Hydridonitrides
In chemistry, a hydridonitride (nitridohydride, nitride hydride, or hydride nitride) is a chemical compound that contains hydride () and nitride () ions in a single phase. These inorganic compounds are distinct from inorganic amides and imides as the hydrogen does not share a bond with nitrogen, and contain a larger proportion of metals. Structure The hydride ion H− is stabilised by being surrounded by electropositive elements such as alkalis or alkaline earths. Quaternary compounds exist where nitrogen forms a complex with bonds to a transition or main group element. The hydride requires the presence of another alkaline earth element. Production Hydridonitrides may be produced by a process called self-propagating high-temperature synthesis (SHS) where a metal nitride is ignited in a hydrogen atmosphere. A metal (Ti, Zr, Hf, Y) can also be ignited in an atmosphere mixing hydrogen and nitrogen, and a hydridonitride is formed exothermicly. The molten metal flux technique invol ...
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Chemistry
Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions: their composition, structure, properties, behavior and the changes they undergo during a Chemical reaction, reaction with other Chemical substance, substances. Chemistry also addresses the nature of chemical bonds in chemical compounds. In the scope of its subject, chemistry occupies an intermediate position between physics and biology. It is sometimes called the central science because it provides a foundation for understanding both Basic research, basic and Applied science, applied scientific disciplines at a fundamental level. For example, chemistry explains aspects of plant growth (botany), the formation of igneous rocks (geology), how atmospheric ozone is formed and how environmental pollutants are degraded (ecology), the properties ...
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Liquid Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both causti ...
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Nitrides
In chemistry, a nitride is an inorganic compound of nitrogen. The "nitride" anion, N3- ion, is very elusive but compounds of nitride are numerous, although rarely naturally occuring. Some nitrides have a find applications, such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si3N4), and semiconductors (e.g., gallium nitride, GaN). The development of GaN-based light emitting diodes was recognized by the 2014 Nobel Prize in Physics. Metal nitrido complexes are also common. Synthesis of inorganic metal nitrides is challenging because nitrogen gas (N2) is not very reactive at low temperatures, but it becomes more reactive at higher temperatures. Therefore, a balance must be achieved between the low reactivity of nitrogen gas at low temperatures and the entropy driven formation of N2 at high temperatures. However, synthetic methods for nitrides are growing more sophisticated and the materials are of increasing technological re ...
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Neil Ashcroft
Neil William Ashcroft (27 November 1938 – 15 March 2021) was a British solid-state physicist. Early life and education Ashcroft was born in London on 27 November 1938, and migrated to New Zealand in 1947. He was educated at Hutt Valley High School, and completed his undergraduate studies at Victoria University College, earning a Bachelor of Science degree, in 1958. He received his PhD in 1964 from the University of Cambridge for research investigating the Fermi surfaces of metals. Career Following his PhD, Ashcroft completed postdoctoral research at the University of Chicago and at Cornell University, where he became a Professor in 1975. In 1990 he was named the Horace White Professor of Physics, and was elected to emeritus status in 2006. He served as the director for the Laboratory of Atomic and Solid State Physics at Cornell University (1979–1984), the director for the Cornell Center for Materials Research (1997–2000), and as the deputy director for the High Energy Sy ...
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Metallic Hydrogen
Metallic hydrogen is a phase of hydrogen in which it behaves like an electrical conductor. This phase was predicted in 1935 on theoretical grounds by Eugene Wigner and Hillard Bell Huntington. At high pressure and temperatures, metallic hydrogen can exist as a partial liquid rather than a solid, and researchers think it might be present in large quantities in the hot and gravitationally compressed interiors of Jupiter and Saturn, as well as in some exoplanets. Theoretical predictions Hydrogen under pressure Though often placed at the top of the alkali metal column in the periodic table, hydrogen does not, under ordinary conditions, exhibit the properties of an alkali metal. Instead, it forms diatomic molecules, analogous to halogens and some nonmetals in the second period of the periodic table, such as nitrogen and oxygen. Diatomic hydrogen is a gas that, at atmospheric pressure, liquefies and solidifies only at very low temperature (20 degrees and 14 degrees above absolute ze ...
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Simons Foundation
The Simons Foundation is a private foundation established in 1994 by Marilyn and Jim Simons with offices in New York City. As one of the largest charitable organizations in the US with assets of over $5 billion in 2022, the foundation's mission is to advance the frontiers of research in mathematics and the basic sciences. The foundation supports science by making grants to individual researchers and their projects. In 2021, Marilyn Simons stepped down as president after 26 years at the helm, and astrophysicist David Spergel was appointed president. The Flatiron Institute In 2016, the foundation launched the Flatiron Institute, its in-house multidisciplinary research institute focused on computational science. The Flatiron Institute hosts centers for computational science in five areas: Funding Areas The foundation makes grants in four program areas: Simons Investigators awardees Among other programs, the Simons Foundation funds the Simons Investigators in MPS program ...
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Quanta Magazine
''Quanta Magazine'' is an editorially independent online publication of the Simons Foundation covering developments in physics, mathematics, biology and computer science. ''Undark Magazine'' described ''Quanta Magazine'' as "highly regarded for its masterful coverage of complex topics in science and math." The science news aggregator ''RealClearScience'' ranked ''Quanta Magazine'' first on its list of "The Top 10 Websites for Science in 2018." In 2020, the magazine received a National Magazine Award for General Excellence from the American Society of Magazine Editors for its "willingness to tackle some of the toughest and most difficult topics in science and math in a language that is accessible to the lay reader without condescension or oversimplification." The articles in the magazine are freely available to read online. ''Scientific American'', ''Wired'', ''The Atlantic'', and ''The Washington Post'', as well as international science publications like ''Spektrum der Wissensch ...
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Institute Of Electrical And Electronics Engineers
The Institute of Electrical and Electronics Engineers (IEEE) is a 501(c)(3) professional association for electronic engineering and electrical engineering (and associated disciplines) with its corporate office in New York City and its operations center in Piscataway, New Jersey. The mission of the IEEE is ''advancing technology for the benefit of humanity''. The IEEE was formed from the amalgamation of the American Institute of Electrical Engineers and the Institute of Radio Engineers in 1963. Due to its expansion of scope into so many related fields, it is simply referred to by the letters I-E-E-E (pronounced I-triple-E), except on legal business documents. , it is the world's largest association of technical professionals with more than 423,000 members in over 160 countries around the world. Its objectives are the educational and technical advancement of electrical and electronic engineering, telecommunications, computer engineering and similar disciplines. History Origins ...
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IEEE Spectrum
''IEEE Spectrum'' is a magazine edited by the Institute of Electrical and Electronics Engineers. The first issue of ''IEEE Spectrum'' was published in January 1964 as a successor to ''Electrical Engineering''. The magazine contains peer-reviewed articles about technology and science trends affecting business and society. In 2010, ''IEEE Spectrum'' was the recipient of ''Utne Reader'' magazine's Utne Independent Press Award for Science/Technology Coverage. In 2012, ''IEEE Spectrum'' was selected as the winner of the National Magazine Awards' "General Excellence Among Thought Leader Magazines" category. References External links * {{Official website, https://spectrum.ieee.org/ Monthly magazines published in the United States Science and technology magazines published in the United States Engineering magazines Spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a ...
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Polyhydride
A polyhydride or superhydride is a compound that contains an abnormally large amount of hydrogen. This can be described as high hydrogen stoichiometry. Examples include iron pentahydride FeH5, LiH6, and LiH7. By contrast, the more well known lithium hydride only has one hydrogen atom. Polyhydrides are only known to be stable under high pressure. Polyhydrides are important because they can form substances with a very high density of hydrogen. They may resemble the elusive metallic hydrogen, but can be made under lower pressures. One possibility is that they could be superconductors. Hydrogen sulfide under high pressures forms SH3 units, and can be a superconductor at and a pressure of 1.5 million atmospheres. Structures The polyhydrides of alkaline earth and alkali metals contain cage structures. Also hydrogen may be clustered into H−, H3−, or H2 units. Polyhydrides of transition metals may have the hydrogen atoms arranged around the metal atom. Computations suggest t ...
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Room-temperature Superconductor
A room-temperature superconductor is a material that is capable of exhibiting superconductivity at operating temperatures above , that is, temperatures that can be reached and easily maintained in an everyday environment. , the material with the highest accepted superconducting temperature is an extremely pressurized carbonaceous sulfur hydride with a critical transition temperature of +15 °C at 267 GPa. On 22 September 2022, the original article reporting superconductivity in the carbonaceous sulfur hydride material was retracted by ''Nature'' journal editorial board due to a non standard, user-defined data analysis, calling into question the scientific validity of the claim. At atmospheric pressure the temperature record is still held by cuprates, which have demonstrated superconductivity at temperatures as high as . Although researchers once doubted whether room-temperature superconductivity was actually achievable, superconductivity has repeatedly been discovered at tem ...
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Non-stoichiometric Compound
In chemistry, non-stoichiometric compounds are chemical compounds, almost always solid inorganic compounds, having elemental composition whose proportions cannot be represented by a ratio of small natural numbers (i.e. an empirical formula); most often, in such materials, some small percentage of atoms are missing or too many atoms are packed into an otherwise perfect lattice work. Contrary to earlier definitions, modern understanding of non-stoichiometric compounds view them as homogeneous, and not mixtures of stoichiometric chemical compounds. Since the solids are overall electrically neutral, the defect is compensated by a change in the charge of other atoms in the solid, either by changing their oxidation state, or by replacing them with atoms of different elements with a different charge. Many metal oxides and sulfides have non-stoichiometric examples; for example, stoichiometric iron(II) oxide, which is rare, has the formula , whereas the more common material is nonstoichi ...
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