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Hexadecacarbonylhexarhodium
Hexadecacarbonylhexarhodium is a metal carbonyl cluster with the formula Rh6(CO)16. It exists as purple-brown crystals that are slightly soluble in dichloromethane and chloroform. It is the principal binary carbonyl of rhodium. Discovery and synthesis Rh6(CO)16 was first prepared by Hieber in 1943 by carbonylation of RhCl3·3H2O at 80–230 °C and 200 atm carbon monoxide with silver or copper as a halide acceptor. Hieber correctly formulated the compound as a binary carbonyl, but suggested the formula Rh4(CO)11, i.e., CO/Rh ratio of 2.75. The correct formula and structure was subsequently established by Dahl et al. using X-ray crystallography. The correct CO/Rh ratio is 2.66. Relative to the original preparation, the carbonylation of a mixture of anhydrous rhodium trichloride and iron pentacarbonyl was shown to give good yields of Rh6(CO)16. Other compounds of rhodium are also effective precursors such as 2.html" ;"title="CO)2Rh(μ-Cl)sub>2">CO)2Rh(μ-Cl)s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrarhodium Dodecacarbonyl
Tetrarhodium dodecacarbonyl is the chemical compound with the formula Rh4(CO)12. This dark-red crystalline solid is the smallest binary rhodium carbonyl that can be handled as a solid under ambient conditions. It is used as a catalyst in organic synthesis. Structure, synthesis, reactions According to X-ray crystallography, features a tetrahedral array of four Rh atoms with nine terminal CO ligands and three bridging CO ligands. The structure can be expressed as Rh4(CO)9(µ-CO)3. is prepared by treatment of an aqueous solution of rhodium trichloride with activated copper metal under an atmosphere of CO. :4 RhCl3(H2O)3 + 8 Cu + 22 CO → + 2 CO2 + 8 Cu(CO)Cl + 4 HCl + 10 H2O Alternatively, the compound can be prepared by treatment of a methanolic solution of RhCl3(H2O)3 with CO to afford H hCl2(CO)2 followed by carbonylation in the presence ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metal Carbonyl Cluster
In chemistry, a metal carbonyl cluster is a compound that contains two or more metals linked in part by metal-metal bonds and containing carbon monoxide (CO) as the exclusive or predominant ligand. The area is a subfield of metal carbonyl chemistry, and many metal carbonyl clusters are in fact prepared from simple metal carbonyls. Simple examples include Fe2(CO)9, Fe3(CO)12, Mn2(CO)10. High nuclearity clusters include h13(CO)24H3sup>2− and the stacked Pt3 triangules t3n(CO)6nsup>2− (n = 2–6). History The first metal carbonyl clusters, Fe3(CO)12, Ir4(CO)12, and Rh6(CO)16, were reported starting in the 1930s, often by Walter Hieber. The structures were subsequently established by X-ray crystallography.. Paolo Chini (1928–1980) was a pioneer for the synthesis and characterization of high nuclearity metal carbonyl clusters. His first studies started in 1958, in the attempt to repeat a patent that claimed an improved selectivity in hydroformylation. From a mixture of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Walter Hieber
Walter Hieber (18 December 1895 – 29 November 1976) was an inorganic chemist, known as the father of metal carbonyl chemistry. He was born 18 December 1895 and died 29 November 1976. Hieber's father was Johannes Hieber, an influential evangelical minister and politician. Hieber was educated at Tübingen, Würzburg, and Heidelberg. In 1935 he was appointed Director of the Inorganic Chemical Institute at the Technical University in Münich. Among his numerous research findings, Hieber prepared the first metal carbonyl hydrides such as H2Fe(CO)4 and HMn(CO)5. He discovered that metal carbonyls undergo nucleophilic attack by hydroxide, the “Hieber base reaction.” He and his students discovered several metal carbonyl compounds such as Re2(CO)10 and Os3(CO)12 He pioneered the development of metal carbonyl sulfides.Hieber, W. and Scharfenberg, C., "Einwirkung organischer Schwefelverbindungen auf die Carbonyls des Eisens", Chemische Berichte, 1940, volume 73, pages 1012 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rhodium Trichloride
Rhodium(III) chloride refers to inorganic compounds with the formula RhCl3(H2O)''n'', where ''n'' varies from 0 to 3. These are diamagnetic solids featuring octahedral Rh(III) centres. Depending on the value of ''n'', the material is either a dense brown solid or a soluble reddish salt. The soluble trihydrated (n = 3) salt is widely used to prepare compounds used in homogeneous catalysis, notably for the industrial production of acetic acid and hydroformylation. Structures Aqueous solutions of RhCl3(H2O)3 have been characterized by 103Rh NMR spectroscopy, which shows the presence of several species. The proportions of which change with time and depend on the concentration of chloride. The relative distribution of these species determines the colour of the solutions, which can range from yellow (the hexaaquo ion) to "raspberry-red". Some of these species are h(H2O)6sup>3+, hCl(H2O)5sup>2+, ''cis''- and ''trans''- hCl2(H2O)4sup>+, and hCl3(H2O)3 Individual ions have been sep ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbon Monoxide
Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest molecule of the oxocarbon family. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds, when insufficient oxygen or heat is present to produce carbon dioxide. There are also numerous environmental and biological sources that generate and emit a significant amount of carbon monoxide. It is important in the production of many compounds, including drugs, fragrances, and fuels. Upon emission into the atmosphere, carbon monoxide affects several processes that contribute to climate change. Carbon monoxide has important biological roles across phylogenetic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Crystallography
X-ray crystallography is the experimental science determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to diffract into many specific directions. By measuring the angles and intensities of these diffracted beams, a crystallographer can produce a three-dimensional picture of the density of electrons within the crystal. From this electron density, the mean positions of the atoms in the crystal can be determined, as well as their chemical bonds, their crystallographic disorder, and various other information. Since many materials can form crystals—such as salts, metals, minerals, semiconductors, as well as various inorganic, organic, and biological molecules—X-ray crystallography has been fundamental in the development of many scientific fields. In its first decades of use, this method determined the size of atoms, the lengths and types of chemical bonds, and the atomic-scale differences among various mat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron Pentacarbonyl
Iron pentacarbonyl, also known as iron carbonyl, is the compound with formula . Under standard conditions Fe( CO)5 is a free-flowing, straw-colored liquid with a pungent odour. Older samples appear darker. This compound is a common precursor to diverse iron compounds, including many that are useful in small scale organic synthesis. Properties Iron pentacarbonyl is a homoleptic metal carbonyl, where carbon monoxide is the only ligand complexed with a metal. Other examples include octahedral Cr(CO)6 and tetrahedral Ni(CO)4. Most metal carbonyls have 18 valence electrons, and Fe(CO)5 fits this pattern with 8 valence electrons on Fe and five pairs of electrons provided by the CO ligands. Reflecting its symmetrical structure and charge neutrality, Fe(CO)5 is volatile; it is one of the most frequently encountered liquid metal complexes. Fe(CO)5 adopts a trigonal bipyramidal structure with the Fe atom surrounded by five CO ligands: three in equatorial positions and two axially b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rhodium Carbonyl Chloride
Rhodium carbonyl chloride is an organorhodium compound with the formula Rh2Cl2(CO)4. It is a red-brown volatile solid that is soluble in nonpolar organic solvents. It is a precursor to other rhodium carbonyl complexes, some of which are useful in homogeneous catalysis. Structure The molecule consists of two planar Rh(I) centers linked by two bridging chloride ligands and four CO ligands. X-ray crystallography shows that the two Rh(I) centers are square planar with the dihedral angle of 53° between the two RhCl2 planes. The metals are nonbonding. Synthesis and reactions First prepared by Walter Hieber, it is typically prepared by treating hydrated rhodium trichloride with flowing carbon monoxide, according to this idealized redox equation: :2 RhCl3(H2O)3 + 6 CO → Rh2Cl2(CO)4 + 2 COCl2 + 6 H2O.McCleverty, J. A.; Wilkinson, G. "Dichlorotetracarbonyldirhodium (rhodium carbonyl chloride)" Inorganic Syntheses 1966, volume 8, pp. 211-14. The complex reacts with triph ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rhodium(II) Acetate
Rhodium(II) acetate is the coordination compound with the formula Rh2(AcO)4, where AcO− is the acetate ion (). This dark green powder is slightly soluble in polar solvents, including water. It is used as a catalyst for cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex. Preparation Rhodium(II) acetate is usually prepared by the heating of hydrated rhodium(III) chloride in acetic acid (CH3COOH): Rhodium(II) acetate dimer undergoes ligand exchange, the replacement of the acetate group by other carboxylates and related groups. :Rh2(OAc)4 + 4 HO2CR → Rh2(O2CR)4 + 4 HOAc Structure and properties The structure of rhodium(II) acetate features a pair of rhodium atoms, each with octahedral molecular geometry, defined by four acetate oxygen atoms, water, and a Rh–Rh bond of length 2.39 Å. The water adduct is exchangeable, and a variety of other Lewis bases bind to the axial positions. Copper(II) acetate and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogenation
Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a Catalysis, catalyst such as nickel, palladium or platinum. The process is commonly employed to redox, reduce or Saturated and unsaturated compounds, saturate organic compounds. Hydrogenation typically constitutes the addition of pairs of hydrogen atoms to a molecule, often an alkene. Catalysts are required for the reaction to be usable; non-catalytic hydrogenation takes place only at very high temperatures. Hydrogenation reduces Double bond, double and Triple bond, triple bonds in hydrocarbons. Process Hydrogenation has three components, the Saturated and unsaturated compounds, unsaturated substrate, the hydrogen (or hydrogen source) and, invariably, a catalyst. The redox, reduction reaction is carried out at different temperatures and pressures depending upon the substrate and the activity of the catalyst. Related or competing reactions The same ca ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroformylation
Hydroformylation, also known as oxo synthesis or oxo process, is an industrial process for the production of aldehydes from alkenes. This chemical reaction entails the net addition of a formyl group (CHO) and a hydrogen atom to a carbon-carbon double bond. This process has undergone continuous growth since its invention: Production capacity reached 6.6×106 tons in 1995. It is important because aldehydes are easily converted into many secondary products. For example, the resulting aldehydes are hydrogenated to alcohols that are converted to detergents. Hydroformylation is also used in speciality chemicals, relevant to the organic synthesis of fragrances and drugs. The development of hydroformylation is one of the premier achievements of 20th-century industrial chemistry. The process entails treatment of an alkene typically with high pressures (between 10 and 100 atmospheres) of carbon monoxide and hydrogen at temperatures between 40 and 200 °C. In one variation, formaldehyd ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
