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Helium Dimer
The helium dimer is a van der Waals molecule with formula He2 consisting of two helium atoms. This chemical is the largest diatomic molecule—a molecule consisting of two atoms bonded together. The bond that holds this dimer together is so weak that it will break if the molecule rotates, or vibrates too much. It can only exist at very low cryogenic temperatures. Two excited helium atoms can also bond to each other in a form called an excimer. This was discovered from a spectrum of helium that contained bands first seen in 1912. Written as He2* with the * meaning an excited state, it is the first known Rydberg molecule. Several dihelium ions also exist, having net charges of negative one, positive one, and positive two. Two helium atoms can be confined together without bonding in the cage of a fullerene. Molecule Based on molecular orbital theory, He2 should not exist, and a chemical bond cannot form between the atoms. However, the van der Waals force exists between helium ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
LiHe
LiHe is a compound of helium and lithium. The substance is a cold low-density gas made of Van der Waals molecules, each composed of a helium atom and lithium atom bound by van der Waals force. The preparation of LiHe opens up the possibility to prepare other helium dimers, and beyond that multi-atom clusters that could be used to investigate Efimov states and Casimir retardation effects. Detection It was detected in 2013. Previously 7Li4He was predicted to have a binding energy of 0.0039 cm−1 (7.7×10−8eV, 1.2×10−26J, or 6 mK), and a bond length of 28 Å. Other van der Waals-bound helium molecules were previously known including Ag3He and He2. Detection of LiHe was done via fluorescence. The lithium atom in the X2Σ state was excited to A2Π. The spectrum showed a pair of lines, each split into two with the hyperfine structure of 7Li. The lines had wavenumbers of 14902.563, 14902.591, 14902.740, and 14902.768 cm−1. The two pairs are separated by 0.177 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Van Der Waals Force
In molecular physics, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules. Named after Dutch physicist Johannes Diderik van der Waals, the van der Waals force plays a fundamental role in fields as diverse as supramolecular chemistry, structural biology, polymer science, nanotechnology, surface science, and condensed matter physics. It also underlies many properties of organic compounds In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The s ... and molecular solids, including their solubil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dimer (chemistry)
A dimer () ('' di-'', "two" + ''-mer'', "parts") is an oligomer consisting of two monomers joined by bonds that can be either strong or weak, covalent or intermolecular. Dimers also have significant implications in polymer chemistry, inorganic chemistry, and biochemistry. The term ''homodimer'' is used when the two molecules are identical (e.g. A–A) and ''heterodimer'' when they are not (e.g. A–B). The reverse of dimerization is often called dissociation. When two oppositely charged ions associate into dimers, they are referred to as ''Bjerrum pairs'', after Niels Bjerrum. Noncovalent dimers Anhydrous carboxylic acids form dimers by hydrogen bonding of the acidic hydrogen and the carbonyl oxygen. For example, acetic acid forms a dimer in the gas phase, where the monomer units are held together by hydrogen bonds. Under special conditions, most OH-containing molecules form dimers, e.g. the water dimer. Excimers and exciplexes are excited structures with a short lif ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bound State
Bound or bounds may refer to: Mathematics * Bound variable * Upper and lower bounds, observed limits of mathematical functions Physics * Bound state, a particle that has a tendency to remain localized in one or more regions of space Geography *Bound Brook (Raritan River), a tributary of the Raritan River in New Jersey *Bound Brook, New Jersey, a borough in Somerset County People * Bound (surname) * Bounds (surname) Arts, entertainment, and media Films * ''Bound'' (1996 film), an American neo-noir film by the Wachowskis * ''Bound'' (2015 film), an American erotic thriller film by Jared Cohn * ''Bound'' (2018 film), a Nigerian romantic drama film by Frank Rajah Arase Television * "Bound" (''Fringe''), an episode of ''Fringe'' * "Bound" (''The Secret Circle''), an episode of ''The Secret Circle'' * "Bound" (''Star Trek: Enterprise''), an episode of ''Star Trek: Enterprise'' Other arts, entertainment, and media * ''Bound'' (video game), a PlayStation 4 game * "Bound", a so ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no known components or substructure. The electron's mass is approximately 1/1836 that of the proton. Quantum mechanical properties of the electron include an intrinsic angular momentum ( spin) of a half-integer value, expressed in units of the reduced Planck constant, . Being fermions, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle. Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Double Ionization
Double ionization is a process of formation of doubly charged ions when laser radiation is exerted on neutral atoms or molecules. Double ionization is usually less probable than single-electron ionization. Two types of double ionization are distinguished: sequential and non-sequential. Sequential double ionization Sequential double ionization is a process of formation of doubly charged ions consisting of two single-electron ionization events: the first electron is removed from a neutral atom/molecule (leaving a singly charged ion in the ground state or an excited state) followed by detachment of the second electron from the ion. , chapter 8. Non-sequential double ionization Non-sequential double ionization is a process whose mechanism differs (in any detail) from the sequential one. For example, both the electrons leave the system simultaneously (as in alkaline earth atoms, see below), the second electron's liberation is assisted by the first electron (as in noble gas atoms, se ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always move at the speed of light in vacuum, (or about ). The photon belongs to the class of bosons. As with other elementary particles, photons are best explained by quantum mechanics and exhibit wave–particle duality, their behavior featuring properties of both waves and particles. The modern photon concept originated during the first two decades of the 20th century with the work of Albert Einstein, who built upon the research of Max Planck. While trying to explain how matter and electromagnetic radiation could be in thermal equilibrium with one another, Planck proposed that the energy stored within a material object should be regarded as composed of an integer number of discrete, equal-sized parts. To explain the photoelectr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ionized
Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule is called an ion. Ionization can result from the loss of an electron after collisions with subatomic particles, collisions with other atoms, molecules and ions, or through the interaction with electromagnetic radiation. Heterolytic bond cleavage and heterolytic substitution reactions can result in the formation of ion pairs. Ionization can occur through radioactive decay by the internal conversion process, in which an excited nucleus transfers its energy to one of the inner-shell electrons causing it to be ejected. Uses Everyday examples of gas ionization are such as within a fluorescent lamp or other electrical discharge lamps. It is also used in radiation detectors such as the Geiger-Müller counter or the ionization chamber. The ionizat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Binding Energy
In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly used in condensed matter physics, atomic physics, and chemistry, whereas in nuclear physics the term '' separation energy'' is used. A bound system is typically at a lower energy level than its unbound constituents. According to relativity theory, a decrease in the total energy of a system is accompanied by a decrease in the total mass, where . Types of binding energy There are several types of binding energy, each operating over a different distance and energy scale. The smaller the size of a bound system, the higher its associated binding energy. Mass–energy relation A bound system is typically at a lower energy level than its unbound constituents because its mass must be less than the total mass of its unbound constituents. For sy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vibronic
Vibronic coupling (also called nonadiabatic coupling or derivative coupling) in a molecule involves the interaction between electronic and nuclear vibrational motion. The term "vibronic" originates from the combination of the terms "vibrational" and "electronic", denoting the idea that in a molecule, vibrational and electronic interactions are interrelated and influence each other. The magnitude of vibronic coupling reflects the degree of such interrelation. In theoretical chemistry, the vibronic coupling is neglected within the Born–Oppenheimer approximation. Vibronic couplings are crucial to the understanding of nonadiabatic processes, especially near points of conical intersections. The direct calculation of vibronic couplings is not common due to difficulties associated with its evaluation. Definition Vibronic coupling describes the mixing of different electronic states as a result of small vibrations. : \mathbf_\equiv\langle\,\chi_(\mathbf;\mathbf)\,, \, \hat_\ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
ångström
The angstromEntry "angstrom" in the Oxford online dictionary. Retrieved on 2019-03-02 from https://en.oxforddictionaries.com/definition/angstrom.Entry "angstrom" in the Merriam-Webster online dictionary. Retrieved on 2019-03-02 from https://www.merriam-webster.com/dictionary/angstrom. (, ; , ) or ångström is a metric unit of length equal to m; that is, one ten-billionth ( US) of a metre, a hundred-millionth of a centimetre,Entry "angstrom" in the Oxford English Dictionary, 2nd edition (1986). Retrieved on 2021-11-22 from https://www.oed.com/oed2/00008552. 0.1 nanometre, or 100 picometres. Its symbol is Å, a letter of the Swedish alphabet. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals,Arturas Vailionis (2015):Geometry of Crystals Le ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
