Gambier (extract)
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Gambier (extract)
Gambier or gambir is an extract derived from the leaves of ''Uncaria gambir'', a climbing shrub native to tropical Southeast Asia. Gambier is produced in Indonesia and Malaysia where it was an important trade item into the late nineteenth century. It can be used as a tanning agent, a brown dye, a food additive and as herbal medicine. Also known as pale catechu, white catechu or Japan Earth, it is often confused with other forms of catechu. History Gambier production began as a traditional occupation in the Malay archipelago. By the middle of the seventeenth century, it was established in Sumatra and in the western parts of Java and the Malay peninsula. It was initially used as medicine and chewed with betel. Local Chinese also began to use gambier to tan hides. Chinese first got involved in gambier production at Riau, using coolie labor and growing black pepper as a supplemental crop. Bugis merchants traded the gambier for rice from Java and Siam, helping the Bugis to become an i ...
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Uncaria Gambir - Köhler–s Medizinal-Pflanzen-275
''Uncaria'' is a genus of flowering plants in the family Rubiaceae. It has about 40 species.''Uncaria'' At: World Checklist of Rubiaceae At: Kew Gardens Website. (see ''External links'' below). Their distribution is pantropical, with most species native to tropical Asia, three from Africa and the Mediterranean and two from the neotropics.David J. Mabberley. 2008. ''Mabberley's Plant-Book'' third edition (2008). Cambridge University Press: UK. They are known colloquially as gambier, cat's claw or uña de gato. The latter two names are shared with several other plants. The type species for the genus is ''Uncaria guianensis''.''Uncaria'' In: Index Nominum Genericorum. In: Regnum Vegetabile (see ''External links'' below). Indonesian Gambier ('' U. gambir'') is a large tropical vine with leaves typical of the genus, being opposite and about long. The South American ''U. tomentosa'' is called Uña de Gato. ''Uncaria sinensis'' is common in China. ''Uncaria'' was named in 1789 by ...
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Areca Nut
''Areca'' is a genus of 51 species of palms in the family Arecaceae, found in humid tropical forests from the islands of the Philippines, Malaysia and India, across Southeast Asia to Melanesia. The generic name ''Areca'' is derived from a name used locally on the Malabar Coast of India. Usage The best-known member of the genus is '' A. catechu'', the areca nut palm. Several species of areca nuts, known for their bitter and tangy taste, raw or dried, are routinely used for chewing, especially in combination with the leaves of betel and dried leaves of tobacco. Areca nut is also popularly referred to as betel nut because of its usage for chewing with betel leaves. In Assam, areca nut is also known as ''tamul'' in the local dialect. Species (51 species) *''Areca abdulrahmanii'' J.Dransf. *''Areca ahmadii'' J.Dransf. *'' Areca andersonii'' J.Dransf. *''Areca gandamatu'' Sultan Mardan Plantation *''Areca arundinacea'' Becc. *''Areca brachypoda'' J.Dransf. *''Areca caliso'' ...
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Tannins
Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' (from Anglo-Norman ''tanner'', from Medieval Latin ''tannāre'', from ''tannum'', oak bark) refers to the use of oak and other bark in tanning animal hides into leather. By extension, the term ''tannin'' is widely applied to any large polyphenolic compound containing sufficient hydroxyls and other suitable groups (such as carboxyls) to form strong complexes with various macromolecules. The tannin compounds are widely distributed in many species of plants, where they play a role in protection from predation (acting as pesticides) and might help in regulating plant growth. The astringency from the tannins is what causes the dry and puckery feeling in the mouth following the consumption of unripened fruit, red wine or tea. Likewise, the destruction or modification of tann ...
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Procyanidin B3
Procyanidin B3 is a B type proanthocyanidin. Procyanidin B3 is a catechin dimer (catechin-(4α→8)-catechin). Natural occurrences It can be found in red wine, in barley, in beer, in peach or in '' Jatropha macrantha'', the Huanarpo Macho. Health effects It has been identified as a hair-growth stimulant. Chemical synthesis Molar equivalents of synthetic (2R,3S,4R or S)- leucocyanidin and (+)-catechin condense with exceptional rapidity at pH 5 under ambient conditions to give the all-trans- ,8 and ,6bi- +)-catechins(procyanidins B3, B6) the all-trans- ,8:4,8 and ,8:4,6tri- +)-catechins(procyanidin C2 and isomer). See also * Phenolic content in wine The phenolic content in wine refers to the phenolic compounds—natural phenol and polyphenols—in wine, which include a large group of several hundred chemical compounds that affect the taste, color and mouthfeel of wine. These compounds include ... References Procyanidin dimers {{Aromatic-stub ...
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Procyanidin B1
Procyanidin B1 is a procyanidin dimer. It is a molecule with a 4→8 bond (epicatechin-(4β→8)-catechin). Proanthocyanidin-B1 can be found in ''Cinnamomum verum'' (Ceylon cinnamon, in the rind, bark or cortex), in ''Uncaria guianensis'' (cat's claw, in the root), and in ''Vitis vinifera'' (common grape vine, in the leaf) or in peach. Procyanidin B1 can be converted into procyanidin A1 by radical oxidation using 1,1-diphenyl-2-picrylhydrazyl (DPPH) radicals under neutral conditions.Conversion of procyanidin B-type (catechin dimer) to A-type: evidence for abstraction of C-2 hydrogen in catechin during radical oxidation. Kazunari Kondo, Masaaki Kurihara, Kiyoshi Fukuhara, Takashi Tanaka, Takashi Suzuki, Naoki Miyata and Masatake Toyoda, Tetrahedron Letters, 22 January 2000, Volume 41, Issue 4, Pages 485–488, See also * Phenolic content in wine The phenolic content in wine refers to the phenolic compounds—natural phenol and polyphenols—in wine, which include a large gro ...
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Flavan-3-ol
Flavan-3-ols (sometimes referred to as flavanols) are a subgroup of flavonoids. They are derivatives of flavans that possess a 2-phenyl-3,4-dihydro-2''H''-chromen-3-ol skeleton. Flavan-3-ols are structurally diverse and include a range of compounds, such as catechin, epicatechin gallate, epigallocatechin, epigallocatechin gallate, proanthocyanidins, theaflavins, thearubigins. They are found in most plants and have a role in plant defense. Chemical structure The single-molecule (monomer) catechin, or isomer epicatechin (see diagram), adds four hydroxyls to flavan-3-ol, making building blocks for concatenated polymers (proanthocyanidins) and higher order polymers (anthocyanidins). Flavan-3-ols possess two chiral carbons, meaning four diastereoisomers occur for each of them. They are distinguished from the yellow, ketone-containing flavonoids such as quercitin and rutin, which are called flavonols. Early use of the term bioflavonoid was imprecisely applied to include the flava ...
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Catechin
Catechin is a flavan-3-ol, a type of secondary metabolite providing antioxidant roles in plants. It belongs to the subgroup of polyphenols called flavonoids. The name of the catechin chemical family derives from ''catechu'', which is the tannic juice or boiled extract of ''Mimosa catechu'' (''Acacia catechu'' L.f). Chemistry Catechin possesses two benzene ring Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atom ...s (called the A- and B-rings) and a dihydropyran heterocycle (the C-ring) with a hydroxyl group on carbon 3. The A-ring is similar to a resorcinol moiety while the B-ring is similar to a catechol moiety. There are two chirality (chemistry), chiral centers on the molecule on carbons 2 and 3. Therefore, it has four diastereoisomers. Two of the isomers are in trans configura ...
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