Gambier or gambir is an extract derived from the leaves of ''
Uncaria gambir
''Uncaria gambir'', the gambier or gambir, is a species of plant in the genus '' Uncaria'' found in Southeast Asia, mainly Malaysia and Indonesia.
Extract
Gambier extract is used or has been used as a catechu for chewing with areca and betel, ...
'', a climbing shrub native to tropical Southeast Asia. Gambier is produced in
Indonesia
Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Guine ...
and
Malaysia
Malaysia ( ; ) is a country in Southeast Asia. The federation, federal constitutional monarchy consists of States and federal territories of Malaysia, thirteen states and three federal territories, separated by the South China Sea into two r ...
where it was an important trade item into the late nineteenth century. It can be used as a
tanning
Tanning may refer to:
*Tanning (leather), treating animal skins to produce leather
*Sun tanning, using the sun to darken pale skin
**Indoor tanning, the use of artificial light in place of the sun
**Sunless tanning, application of a stain or dye t ...
agent, a brown
dye
A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...
,
a food additive
and as herbal medicine. Also known as pale catechu,
white catechu or Japan Earth,
it is often confused with other forms of
catechu
( or ) is an extract of acacia trees used variously as a food additive, astringent, tannin, and dye. It is extracted from several species of ''Acacia'', but especially ''Senegalia catechu'' (''Acacia catechu''), by boiling the wood in wate ...
.
History
Gambier production began as a traditional occupation in the Malay archipelago. By the middle of the seventeenth century, it was established in Sumatra and in the western parts of
Java
Java (; id, Jawa, ; jv, ꦗꦮ; su, ) is one of the Greater Sunda Islands in Indonesia. It is bordered by the Indian Ocean to the south and the Java Sea to the north. With a population of 151.6 million people, Java is the world's List ...
and the
Malay peninsula
The Malay Peninsula (Malay: ''Semenanjung Tanah Melayu'') is a peninsula in Mainland Southeast Asia. The landmass runs approximately north–south, and at its terminus, it is the southernmost point of the Asian continental mainland. The area ...
. It was initially used as medicine and chewed with
betel
The betel (''Piper betle'') is a vine of the family Piperaceae, which includes pepper and kava. The betel plant is native to Southeast Asia. It is an evergreen, dioecious perennial, with glossy heart-shaped leaves and white catkins. Betel plan ...
. Local Chinese also began to use gambier to tan hides. Chinese first got involved in gambier production at
Riau
Riau is a province of Indonesia. It is located on the central eastern coast of Sumatra along the Strait of Malacca. The province shares land borders with North Sumatra to the northwest, West Sumatra to the west, and Jambi to the south. Accord ...
, using
coolie
A coolie (also spelled koelie, kuli, khuli, khulie, cooli, cooly, or quli) is a term for a low-wage labourer, typically of South Asian or East Asian descent.
The word ''coolie'' was first popularized in the 16th century by European traders acros ...
labor and growing
black pepper
Black pepper (''Piper nigrum'') is a flowering vine in the family Piperaceae, cultivated for its fruit, known as a peppercorn, which is usually dried and used as a spice and seasoning. The fruit is a drupe (stonefruit) which is about in diame ...
as a supplemental crop.
Bugis
The Bugis people (pronounced ), also known as Buginese, are an ethnicity—the most numerous of the three major linguistic and ethnic groups of South Sulawesi (the others being Makassar and Toraja), in the south-western province of Sulawe ...
merchants traded the gambier for rice from
Java
Java (; id, Jawa, ; jv, ꦗꦮ; su, ) is one of the Greater Sunda Islands in Indonesia. It is bordered by the Indian Ocean to the south and the Java Sea to the north. With a population of 151.6 million people, Java is the world's List ...
and
Siam
Thailand ( ), historically known as Siam () and officially the Kingdom of Thailand, is a country in Southeast Asia, located at the centre of the Mainland Southeast Asia, Indochinese Peninsula, spanning , with a population of almost 70 mi ...
, helping the Bugis to become an important regional power in the late eighteenth century.
When the British settlement of
Singapore
Singapore (), officially the Republic of Singapore, is a sovereign island country and city-state in maritime Southeast Asia. It lies about one degree of latitude () north of the equator, off the southern tip of the Malay Peninsula, borde ...
was founded in 1819, about 20 gambier plantations had already been started in the area by Chinese. The peak of Singapore's gambier trade was in the 1830s through 1850s, driven by demand from the British dyeing and leather tanning industries.
Diplomat
Edmund Roberts noted that upon his visit to China in the 1830s, Chinese were using it for
tanning
Tanning may refer to:
*Tanning (leather), treating animal skins to produce leather
*Sun tanning, using the sun to darken pale skin
**Indoor tanning, the use of artificial light in place of the sun
**Sunless tanning, application of a stain or dye t ...
, and noted that the ''uncaria gambir'' made "leather porous and rotten". He also noted that the Chinese would chew it with
areca nut
''Areca'' is a genus of 51 species of palms in the family Arecaceae, found in humid tropical forests from the islands of the Philippines, Malaysia and India, across Southeast Asia to Melanesia. The generic name ''Areca'' is derived from a name ...
.
In the 1860s through 1880s, gambier production was expanded in nearby
Johor
Johor (; ), also spelled as Johore, is a States and federal territories of Malaysia, state of Malaysia in the south of the Malay Peninsula. Johor has land borders with the Malaysian states of Pahang to the north and Malacca and Negeri Sembilan ...
under the
kangchu system
The Kangchu system was a socio-economic system of organisation and administration developed by Chinese agricultural settlers in Johor during the 19th century. The settlers organised themselves into informal associations (similar to the Kongsi ...
.
Production
To make gambier, the leaves are first boiled in water. They absorb it and turn brownish in color. The leaves are then pressed mechanically to squeeze and extract liquid. This liquid is then dried into a semi-solid paste and molded into cubes, which are dried in the sun.
Physical properties and composition
Gambier has a highly astringent taste with no odor, ranging in color from yellow to brown. It is mainly composed of cattechu-tanic acid (a
tannin
Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids.
The term ''tannin'' (from Anglo-Norman ''tanner'', ...
) and
catechin
Catechin is a flavan-3-ol, a type of secondary metabolite providing antioxidant roles in plants. It belongs to the subgroup of polyphenols called flavonoids.
The name of the catechin chemical family derives from ''catechu'', which is the tannic ...
(a
flavan-3-ol
Flavan-3-ols (sometimes referred to as flavanols) are a subgroup of flavonoids. They are derivatives of flavans that possess a 2-phenyl-3,4-dihydro-2''H''-chromen-3-ol skeleton. Flavan-3-ols are structurally diverse and include a range of comp ...
). Commercially produced gambier may range in catechin content of less than 20% to more than 40% depending on quality. When used for making leather, catechin is converted into cattechu-tanic acid by the tanning process.
Trace components include quercetin, wax, oil, cattechu red, and gambier-flourescien.
Gambier extracts further contain chalcane-flavan dimers (
gambiriins A1,
A2,
B1 and
B2) in addition to (+)-
catechin
Catechin is a flavan-3-ol, a type of secondary metabolite providing antioxidant roles in plants. It belongs to the subgroup of polyphenols called flavonoids.
The name of the catechin chemical family derives from ''catechu'', which is the tannic ...
, (+)-epicatechin, and dimeric proanthocyanidins including
procyanidin B1
Procyanidin B1 is a procyanidin dimer.
It is a molecule with a 4→8 bond (epicatechin-(4β→8)-catechin). Proanthocyanidin-B1 can be found in ''Cinnamomum verum'' (Ceylon cinnamon, in the rind, bark or cortex), in ''Uncaria guianensis'' (cat's ...
,
procyanidin B3
Procyanidin B3 is a B type proanthocyanidin. Procyanidin B3 is a catechin dimer (catechin-(4α→8)-catechin).
Natural occurrences
It can be found in red wine, in barley, in beer, in peach or in '' Jatropha macrantha'', the Huanarpo Macho.
H ...
, and
gambiriin C.
Uses
Gambier has been used as a form of
catechu
( or ) is an extract of acacia trees used variously as a food additive, astringent, tannin, and dye. It is extracted from several species of ''Acacia'', but especially ''Senegalia catechu'' (''Acacia catechu''), by boiling the wood in wate ...
for chewing with
areca nut
''Areca'' is a genus of 51 species of palms in the family Arecaceae, found in humid tropical forests from the islands of the Philippines, Malaysia and India, across Southeast Asia to Melanesia. The generic name ''Areca'' is derived from a name ...
. Particularly in the nineteenth century, it was economically important as a brown dye and tanning agent.
It is still used as herbal medicine, and occasionally as a food additive.
Notes
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[{{cite web , url=http://eresources.nlb.gov.sg/infopedia/articles/SIP_337_2005-01-03.html , title=Gambier , last1=Thulaja , first1=Naidu Ratnala , date= 2003, website= Singapore Infopedia , publisher= National Library Board of Singapore, access-date=December 28, 2014]
[{{cite book, last=Roberts, first=Edmund, title=Embassy to the Eastern Courts of Cochin-China, Siam, and Muscat, year=1837, publisher=Harper & Brothers, location=New York, page=138, url=http://www.wdl.org/en/item/7317/view/1/138/]
[{{cite journal , vauthors=Taniguchi S, Kuroda K, Doi K, etal , title=Revised structures of gambiriins A1, A2, B1, and B2, chalcane-flavan dimers from gambir (Uncaria gambir extract) , journal=Chemical and Pharmaceutical Bulletin , volume=55 , issue=2 , pages=268–72 , date=February 2007 , pmid=17268100 , doi= 10.1248/cpb.55.268, doi-access=free ]
[{{cite book, author=Carl A. Trocki, title=Prince of Pirates: The Temenggongs and the Development of Johor and Singapore, 1784-1885, url=https://books.google.com/books?id=4VNEr574cQIC, year=2007, publisher=NUS Press, isbn=978-9971-69-376-3, pages=34–35]
Tannins
Plant dyes
Astringent flavors
Ayurvedic medicaments
Traditional Chinese medicine