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Gmelanone
Gmelanone is a lignan found in the heartwood of ''Gmelina arborea''. Arboreol can be transformed by acid catalysis In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H+) donor and the base is the proton acceptor. Typical reactions catalyze ... into gmelanone. References Lignans Benzodioxoles {{aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arboreol
Arboreol is an epoxylignan. Arboreol can be transformed by acid catalysis into gmelanone Gmelanone is a lignan found in the heartwood of ''Gmelina arborea''. Arboreol can be transformed by acid catalysis In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base t ....Acid catalysed rearrangements of arboreol: A biomimetic synthesis of gmelanone. L. Ramachandra Row and Reveru Ventkateswarlu, Tetrahedron Letters, 1980, Volume 21, Issue 30, Pages 2919–2922, References External links Lignans Benzodioxoles {{aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gmelina Arborea
''Gmelina arborea'', (in English beechwood, gmelina, goomar teak, Kashmir tree, Malay beechwood, white teak, yamane ), locally known as gamhar, is a fast-growing deciduous tree in the family Lamiaceae. Distribution and habitat ''Gmelina arborea'' grows naturally throughout India, Myanmar, Thailand, Laos, Cambodia, Vietnam and in southern provinces of China. It is found at altitudes from sea level to . Since the 1960s, it has been introduced extensively as fast-growing timber trees in Brazil, Gambia, Honduras, Ivory Coast, Malaysia, Malawi, Nigeria, the Philippines, and Sierra Leone. It is also planted in gardens and avenues. Utilization of the species The Lion Throne, the most important, and last surviving, of the eight royal thrones of Myanmar, now in the National Museum in Yangon, is carved from ''Gmelina arborea'' wood. Chemistry Lignans, such as 6" - bromo - isoarboreol, 4-hydroxysesamin, 4,8-dihydroxysesamin, 1,4-dihydroxysesamin (gummadiol), 2-piperonyl-3-hydroxyme ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lignan
The lignans are a large group of low molecular weight polyphenols found in plants, particularly seeds, whole grains, and vegetables. The name derives from the Latin word for "wood". Lignans are precursors to phytoestrogens. They may play a role as antifeedants in the defense of seeds and plants against herbivores. Biosynthesis and metabolism Lignans and lignin differ in their molecular weight, the former being small and soluble in water, the latter being high polymers that are undigestable. Both are polyphenolic substances derived by oxidative coupling of monolignols. Thus, most lignans feature a C18 cores, resulting from the dimerization of C9 precursors. The coupling of the lignols occurs at C8. Eight classes of lignans are: "furofuran, furan, dibenzylbutane, dibenzylbutyrolactone, aryltetralin, arylnaphthalene, dibenzocyclooctadiene, and dibenzylbutyrolactol." Many lignans are metabolized by mammalian gut microflora, producing so-called enterolignans. Food sources Flax s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acid Catalysis
In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H+) donor and the base is the proton acceptor. Typical reactions catalyzed by proton transfer are esterifications and aldol reactions. In these reactions, the conjugate acid of the carbonyl group is a better electrophile than the neutral carbonyl group itself. Depending on the chemical species that act as the acid or base, catalytic mechanisms can be classified as either specific catalysis and general catalysis. Many enzymes operate by general catalysis. Applications and examples Brønsted acids Acid catalysis is mainly used for organic chemical reactions. Many acids can function as sources for the protons. Acid used for acid catalysis include hydrofluoric acid (in the alkylation process), phosphoric acid, toluenesulfonic acid, polystyrene sulfonate, heteropoly acids, zeolites. Strong acids catalyze the hydr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lignans
The lignans are a large group of low molecular weight polyphenols found in plants, particularly seeds, whole grains, and vegetables. The name derives from the Latin word for "wood". Lignans are precursors to phytoestrogens. They may play a role as antifeedants in the defense of seeds and plants against herbivores. Biosynthesis and metabolism Lignans and lignin differ in their molecular weight, the former being small and soluble in water, the latter being high polymers that are undigestable. Both are polyphenolic substances derived by oxidative coupling of monolignols. Thus, most lignans feature a C18 cores, resulting from the dimerization of C9 precursors. The coupling of the lignols occurs at C8. Eight classes of lignans are: "furofuran, furan, dibenzylbutane, dibenzylbutyrolactone, aryltetralin, arylnaphthalene, dibenzocyclooctadiene, and dibenzylbutyrolactol." Many lignans are metabolized by mammalian gut microflora, producing so-called enterolignans. Food sources Flax se ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
