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Germacrene B
Germacrenes are a class of volatile organic hydrocarbons, specifically, sesquiterpenes. Germacrenes are typically produced in a number of plant species for their antimicrobial and insecticidal properties, though they also play a role as insect pheromones. Two prominent molecules are germacrene A and germacrene D. Structures Germacrene has five isomers. Natural occurrences The essential oils of red deadnettle (''Lamium purpureum'') and hedgenettles (genus ''Stachys'') are characterized by their high contents of germacrene D, as is ''Clausena anisata :''Should not be confused with syzygium anisatum, a tree native to eastern Australian rainforests, used as a culinary herb.'' ''Clausena anisata'' (Willd.) Hook.f. ex Benth. is a deciduous shrub or small tree, belonging to the Rutaceae or Citr ...''. It is also a major component of patchouli oil. References Further reading General * Germacrene A * * * * * * Germacrene D ...
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Hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or exemplified by the odors of gasoline and lighter fluid. They occur in a diverse range of molecular structures and phases: they can be gases (such as methane and propane), liquids (such as hexane and benzene), low melting solids (such as paraffin wax and naphthalene) or polymers (such as polyethylene and polystyrene). In the fossil fuel industries, ''hydrocarbon'' refers to the naturally occurring petroleum, natural gas and coal, and to their hydrocarbon derivatives and purified forms. Combustion of hydrocarbons is the main source of the world's energy. Petroleum is the dominant raw-material source for organic commodity chemicals such as solvents and polymers. Most anthropogenic (human-generated) emissions of greenhouse gases are carbon di ...
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Stachys
''Stachys'' is a genus of plants, one of the largest in the mint family Lamiaceae.Harley, R. M., et al. 2004. "Labiatae". pages 167–275. In: Kubitzki, K. (editor) and J. W. Kadereit (volume editor). ''The Families and Genera of Vascular Plants'' volume VII. Springer-Verlag: Berlin; Heidelberg, Germany. Estimates of the number of species vary from about 300, to about 450.Mabberley, D. J. 2008. ''Mabberley's Plant-Book'' third edition (2008). Cambridge University Press: UK. ''Stachys'' is in the subfamily Lamioideae and its type species is '' Stachys sylvatica''.''Stachys'' In: Index Nominum Genericorum. In: Regnum Vegetabile (see ''External links'' below). The precise extent of the genus and its relationship to other genera in the subfamily are poorly known. Range and naming The distribution of the genus covers Europe, Asia, Africa, Australasia and North America. Common names include hedgenettle, heal-all, self-heal, woundwort, betony, and lamb's ears. Wood betony, ''S. offici ...
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Sesquiterpenes
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many unique combinations. Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. Sesquiterpenes are found naturally in plants and insects, as semiochemicals, e.g. defensive agents or pheromones. Biosynthesis and examples The reaction of geranyl pyrophosphate with isopentenyl pyrophosphate results in the 15-carbon farnesyl pyrophosphate (FPP), which is an intermediate in the biosynthesis of sesquiterpenes such as farnesene. Cyclic sesquiterpenes are more common than cyclic monoterpenes because of the increased chain length and additional double bond in the sesquiterpene precursors. In addition to common six-membered ring systems such as the ones found in zingiberene and bisacurone, cyclization of one end of the chain to the other end can l ...
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Alkene Derivatives
In organic chemistry, an alkene is a hydrocarbon containing a carbon–carbon double bond. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds.H. Stephen Stoker (2015): General, Organic, and Biological Chemistry'. 1232 pages. Two general types of monoalkenes are distinguished: terminal and internal. Also called α-olefins, terminal alkenes are more useful. However, the International Union of Pure and Applied Chemistry (IUPAC) recommends using the name "alkene" only for acyclic hydrocarbons with just one double bond; alkadiene, alkatriene, etc., or polyene for acyclic hydrocarbons with two or more double bonds; cycloalkene, cycloalkadiene, etc. for cyclic ones; and "olefin" for the general class – cyclic or acyclic, with one or more double bonds. Acyclic alkenes, with only one double bond and no other functional groups (also known as mono-enes) form a homologous series of hydrocarbons with the general formula with '' ...
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Angelica Glauca
''Angelica glauca'', the smooth angelica, is a species of flowering plant in the family Apiaceae. It is found from eastern Afghanistan through the western Himalayas to western Tibet. Collecting in the wild for its essential oil has driven this species to Endangered An endangered species is a species that is very likely to become extinct in the near future, either worldwide or in a particular political jurisdiction. Endangered species may be at risk due to factors such as habitat loss, poaching and inva ... status. References glauca Flora of Afghanistan Flora of Pakistan Flora of West Himalaya Flora of Tibet Plants described in 1846 {{Apiaceae-stub ...
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Patchouli
PatchouliAlso spelled ''patchouly'' or ''pachouli''. (; ''Pogostemon cablin'') is a species of flowering plant in the family Lamiaceae, commonly called the mint or deadnettle family. The plant grows as a bushy perennial herb, with erect stems reaching up to 75 centimetres (2.5 ft) in height and bearing small, pale pink-white flowers. It is native to the island region of Southeast Asia, including Sri Lanka, Indonesia, the Malay Peninsula, New Guinea and the Philippines. It is also found in many parts of North East India. Noted for its fragrant essential oil, it has many commercial uses and is now extensively cultivated in tropical climates around the world, especially in Asia, Madagascar, South America and the Caribbean. Indonesia currently produces over 90% of the global volume of patchouli oil (~1,600 metric tons). Etymology The word derives from the Tamil ''patchai'' ( ta, பச்சை) or paccuḷi, meaning "green", and ''ellai'' ( ta, இலை), meaning "leaf". ...
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Clausena Anisata
:''Should not be confused with syzygium anisatum, a tree native to eastern Australian rainforests, used as a culinary herb.'' ''Clausena anisata'' (Willd.) Hook.f. ex Benth. is a deciduous shrub or small tree, belonging to the Rutaceae or Citrus family, and widespread in the Afrotropical realm or Sub-Saharan Africa, but absent from the drier regions. It is also found in tropical and South-East Asia, growing in India and Sri Lanka and extending as far as Queensland in north-eastern Australia and some Pacific islands. It is cultivated in Malaysia and Indonesia. As with other plants useful to mankind its large range of medicinal properties has led to a global distribution and its growth wherever the climate is suitable. It grows in higher-rainfall regions in savanna, thickets, riverine forest, disturbed areas and secondary forest, up to an altitude of 3000 m. The leaves, which are foetid when bruised, give rise to the common name 'Horsewood' or the more descriptive Afrikaans com ...
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Stachys Byzantina
''Stachys byzantina'' (syn. ''S. lanata''), the lamb's-ear (lamb's ear) or woolly hedgenettle, is a species of flowering plant in the mint family Lamiaceae, native to Armenia, Iran, and Turkey.Euro+Med Plantbase''Stachys byzantina''/ref>Huxley, A., ed. (1992). ''New RHS Dictionary of Gardening''. Macmillan . It is cultivated over much of the temperate world as an ornamental plant, and is naturalised in some locations as an escapee from gardens. Plants are very often found under the synonym ''Stachys lanata'' or ''Stachys olympica''. Lamb's-ear flowers in late spring and early summer; plants produce tall spike-like stems with a few reduced leaves. The flowers are small and light purple. The plants tend to be evergreen but can "die" back during cold winters and regenerate new growth from the crowns. Description Lamb's-ears are herbaceous perennials, usually densely covered with gray or silver-white, silky-lanate hairs. They are named lamb's ears because of the leaves' curved shape ...
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Lamium
''Lamium'' (dead-nettles) is a genus of about 30 species of flowering plants in the family Lamiaceae, of which it is the type genus. They are all herbaceous plants native to Europe, Asia, and northern Africa, but several have become very successful weeds of crop fields and are now widely naturalised across much of the temperate world. Description The genus includes both annual and perennial species; they spread by both seeds and stems rooting as they grow along the ground. They have square stems and coarsely textured pairs of leaves, often with striking patterns or variegation. They produce double-lipped flowers in a wide range of colours. The common name "dead-nettle" has been derived from the German ''taube-nessel'' ("deaf nettle", or "nettle without a kernel"), and refers to the resemblance of ''Lamium album'' to the very distantly related stinging nettles, but unlike those, they do not have stinging hairs and so are harmless or apparently "dead". Several closely related ge ...
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Sesquiterpene
Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many unique combinations. Biochemical modifications such as oxidation or rearrangement produce the related sesquiterpenoids. Sesquiterpenes are found naturally in plants and insects, as semiochemicals, e.g. defensive agents or pheromones. Biosynthesis and examples The reaction of geranyl pyrophosphate with isopentenyl pyrophosphate results in the 15-carbon farnesyl pyrophosphate (FPP), which is an intermediate in the biosynthesis of sesquiterpenes such as farnesene. Cyclic sesquiterpenes are more common than cyclic monoterpenes because of the increased chain length and additional double bond in the sesquiterpene precursors. In addition to common six-membered ring systems such as the ones found in zingiberene and bisacurone, cyclization of one end of the chain to the other end can l ...
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Lamium Purpureum
''Lamium purpureum'', known as red dead-nettle, purple dead-nettle, or purple archangel, is an annual herbaceous flowering plant native to Europe and Asia. Varieties: * ''Lamium purpureum'' var. ''hybridum'' (Vill.) Vill. (synonym: ''Lamium hybridum'' Vill.) Description ''Lamium purpureum'' grows with square stems to 5–20 cm Parnell, J. and Curtis, T. 2012. ''Webb's An Irish Flora.'' Cork University Press. (rarely 30 cm) in height. The leaf, leaves have fine hairs, are green at the bottom and shade to purplish at the top; they are 2–4 cm long and broad, with a 1–2 cm petiole (leaf stalk), and wavy to serrated margins. The Floral symmetry, zygomorphic flowers are bright red-purple, with a top hood-like petal, two lower lip petal lobes and minute fang-like lobes between. The Petal, corolla shows a line of hairs near the base of the tube. They may be produced throughout the year, including mild weather in winter. This allows bees to gather its nectar for f ...
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Germacrene E Chemical Structure
Germacrenes are a class of volatile organic hydrocarbons, specifically, sesquiterpenes. Germacrenes are typically produced in a number of plant species for their antimicrobial and insecticidal properties, though they also play a role as insect pheromones. Two prominent molecules are germacrene A and germacrene D. Structures Germacrene has five isomers. Natural occurrences The essential oils of red deadnettle (''Lamium purpureum'') and hedgenettles (genus ''Stachys'') are characterized by their high contents of germacrene D, as is ''Clausena anisata :''Should not be confused with syzygium anisatum, a tree native to eastern Australian rainforests, used as a culinary herb.'' ''Clausena anisata'' (Willd.) Hook.f. ex Benth. is a deciduous shrub or small tree, belonging to the Rutaceae or Citrus ...''. It is also a major component of patchouli oil. References Further reading General * Germacrene A * * * * * * Germacrene D ...
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