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Gas Works
A gasworks or gas house is an industrial plant for the production of flammable gas. Many of these have been made redundant in the developed world by the use of natural gas, though they are still used for storage space. Early gasworks Coal gas was introduced to Great Britain in the 1790s as an illuminating gas by the Scottish inventor William Murdoch. Early gasworks were usually located beside a river or canal so that coal could be brought in by barge. Transport was later shifted to railways and many gasworks had internal railway systems with their own locomotives. Early gasworks were built for factories in the Industrial Revolution from about 1805 as a light source and for industrial processes requiring gas, and for lighting in country houses from about 1845. Country house gas works are extant at Culzean Castle in Scotland and Owlpen in Gloucestershire. Equipment A gasworks was divided into several sections for the production, purification and storage of gas. Retort hou ...
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Syngas
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principly used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII (in Germany alone half a million cars were built or rebuilt to run on wood gas). Production Syngas is produced by steam reforming or partial oxidation of natural gas or liquid hydrocarbons, or coal gasification. Steam reforming of methane is an endothermic reaction requiring 206 kJ/mol of methane: : In principle, but rarely in practice, biomass and related hydrocarbon feedstocks could be used to generate biogas and biochar in waste-to-energy gasification facilities. The gas generated (mostly methane and carbon dioxide) is sometimes described as ''syngas'' but its co ...
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Owlpen Manor
Owlpen Manor is a Tudor Grade I listed manor house of the Mander family, situated in the village of Owlpen in the Stroud district in Gloucestershire, England. There is an associated estate set in a valley within the Cotswold Area of Outstanding Natural Beauty. The manor house is about one mile east of Uley, and three miles east of Dursley. History The manor house is of medieval origins, incorporating fabric dated by dendrochronology to c. 1270. It was largely built and rebuilt in the Tudor period by the Daunt family between 1464 and 1616. Since then it has not seen significant development, except for some improvements early in the 18th century, when the east wing of the house, together with the gardens, church and Grist Mill, were reordered by Thomas Daunt IV between 1719 and 1726. Medieval period Owlpen (pronounced locally "Ole-pen") derives its name, it is thought, from the Saxon thegn, Olla, who first set up his ''pen'', or enclosure, by the springs that rise under the f ...
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Iron Sulfide
Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monoclinic or hexagonal) * Troilite, FeS, the endmember of pyrrhotite (hexagonal) * Mackinawite, Fe1+xS (where x = 0 to 0.1) (tetragonal) * Marcasite, orthorhombic FeS2 * Pyrite, cubic FeS2 (fool's gold) * Arsenopyrite (''mispickel''), FeAsS, or Fe(As-S), Fe(III) mixed arseno-sulfide (monoclinic) Synthetic * Iron(III) sulfide, Fe2S3 * Iron-sulfur clusters, includes both synthetic and biological Biological * Iron–sulfur protein Iron–sulfur proteins (or iron–sulphur proteins in British spelling) are proteins characterized by the presence of iron–sulfur clusters containing sulfide-linked di-, tri-, and tetrairon centers in variable oxidation states. Iron–sulfur cl ... {{DEFAULTSORT:Iron Sulfide Iron compounds Iron minerals Sulfur ...
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Ferric Oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the main source of iron for the steel industry. Fe2O3 is readily attacked by acids. Iron(III) oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as Hydrous ferric oxide. Structure Fe2O3 can be obtained in various polymorphs. In the main one, α, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands. In the γ polymorph, some of the Fe sit on tetrahedral sites, with four oxygen ligands. Alpha phase α-Fe2O3 has the rhombohedral, corundum (α-Al2O3) structure and i ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ...
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Ammonium
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are co ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Ammonium Hydroxide
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with chemical formula, composition , it is actually impossible to isolate samples of NH4OH. The ions and OH− do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions. Basicity of ammonia in water In aqueous solution, ammonia deprotonation, deprotonates a small fraction of the water to give ammonium and hydroxide according to the following chemical equilibrium, equilibrium: : NH3 + H2O NH4+ + OH−. In a 1 Molar concentration, M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH4+] = 0.0042 M, [OH−] = 0.0042 M, [NH3] = 0.9958 M, and pH = 14 + log10[OHâ ...
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Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct reversibility scenarios emerge here with respect to the n ...
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Coal Tar
Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and used in the surfacing of roads. Coal tar was listed as a known human carcinogen in the first Report on Carcinogens from the U.S. Federal Government. Coal tar was discovered circa 1665 and used for medical purposes as early as the 1800s. Circa 1850, the discovery that it could be used as the main ingredient in synthetic dyes engendered an entire industry. It is on the World Health Organization's List of Essential Medicines. Coal tar is available as a generic medication and over the counter. Side effects include skin irritation, sun sensitivity, allergic reactions, and skin discoloration. ...
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Coke (fuel)
Coke is a grey, hard, and porous coal-based fuel with a high carbon content and few impurities, made by heating coal or oil in the absence of air—a destructive distillation process. It is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges when air pollution is a concern. The unqualified term "coke" usually refers to the product derived from low-ash and low-sulphur bituminous coal by a process called coking. A similar product called petroleum coke, or pet coke, is obtained from crude oil in oil refineries. Coke may also be formed naturally by geologic processes.B. Kwiecińska and H. I. Petersen (2004): "Graphite, semi-graphite, natural coke, and natural char classification — ICCP system". ''International Journal of Coal Geology'', volume 57, issue 2, pages 99-116. History China Historical sources dating to the 4th century describe the production of coke in ancient China. The Chinese first used coke for heating ...
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Condenser (heat Transfer)
In systems involving heat transfer, a condenser is a heat exchanger used to condense a gaseous substance into a liquid state through cooling. In so doing, the latent heat is released by the substance and transferred to the surrounding environment. Condensers are used for efficient heat rejection in many industrial systems. Condensers can be made according to numerous designs, and come in many sizes ranging from rather small (hand-held) to very large (industrial-scale units used in plant processes). For example, a refrigerator uses a condenser to get rid of heat extracted from the interior of the unit to the outside air. Condensers are used in air conditioning, industrial chemical processes such as distillation, steam power plants and other heat-exchange systems. Use of cooling water or surrounding air as the coolant is common in many condensers. History The earliest laboratory condenser, a " Gegenstromkühler" (counter-flow condenser), was invented in 1771 by the Swedish-German ...
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