Ferroalloys
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Ferroalloys
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015. Compounds The main ferroalloys are: *FeAl – ferroaluminum *FeB – ferroboron – 12–20% of boron, max. 3% of silicon, max. 2% aluminium, max. 1% of carbon *FeCe – ferrocerium *FeCr – ferrochromium *FeMg – ferromagnesium *FeMn – ferromanganese *FeMo – ferromolybdenum – min. 60% Mo, max. 1% Si, max. 0.5% Cu *FeNb ...
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Ferronickel
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015. Compounds The main ferroalloys are: *FeAl – ferroaluminum *FeB – ferroboron – 12–20% of boron, max. 3% of silicon, max. 2% aluminium, max. 1% of carbon *FeCe – ferrocerium *FeCr – ferrochromium *FeMg – ferromagnesium *FeMn – ferromanganese *FeMo – ferromolybdenum – min. 60% Mo, max. 1% Si, max. 0.5% Cu *FeNb – ...
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Ferrosilicon Magnesium
Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerated in the presenc ...
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Ferrotitanium
Ferrotitanium is a ferroalloy, an alloy of iron and titanium with between 10–20% iron and 45–75% titanium and sometimes a small amount of carbon. It is used in steelmaking as a cleansing agent for iron and steel; the titanium is highly reactive with sulfur, carbon, oxygen, and nitrogen, forming insoluble compounds and sequestering them in slag, and is therefore used for deoxidizing, and sometimes for desulfurization and denitrogenation. In steelmaking the addition of titanium yields metal with finer grain structure. Ferrotitanium can be manufactured by mixing titanium sponge and scrap with iron and melting them together in an induction furnace. Ferrotitanium powder can be also used as a fuel in some pyrotechnic compositions. References External links *{{cite web , url = http://minerals.usgs.gov/minerals/pubs/commodity/ferroalloys/myb1-2006-feall.pdf , title =Minerals Yearbook 2006: Ferroalloys , publisher = United States Geological Survey The United States Geologica ...
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Ferrosilicon
Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerated in the presenc ...
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Ferromolybdenum
Ferro molybdenum is an important iron-molybdenum metal alloy, with a molybdenum content of 60-75% It is the main source for molybdenum alloying of HSLA steel. Production The alloy is produced by heating a mixture of molybdenum(VI) oxide MoO3, aluminium, and iron. The oxide and the aluminium combine via an aluminothermic reaction to give molybdenum in situ. The ferromolybdenum can be purified by electron beam melting Electron-beam additive manufacturing, or electron-beam melting (EBM) is a type of additive manufacturing, or 3D printing, for metal parts. The raw material (metal powder or wire) is placed under a vacuum and fused together from heating by an e ... or used as it is. For alloying with steel the ferromolybdenum is added to molten steel before casting. Among the biggest suppliers of ferromolybdenum in Europe are the English trading house Derek Raphael and Co Ltd and the English Trading House MTALX LTD in London. A large ferromolybdenum producer in the US is Langeloth ...
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Ferrochromium
Ferrochrome, or ferrochromium (FeCr) is a type of ferroalloy, that is, an alloy of chromium and iron, generally containing 50 to 70% chromium by weight. Ferrochrome is produced by electric arc carbothermic reduction of chromite. Most of the global output is produced in South Africa, Kazakhstan and India, which have large domestic chromite resources. Increasing amounts are coming from Russia and China. Production of steel, especially that of stainless steel with chromium content of 10 to 20%, is the largest consumer and the main application of ferrochrome. Usage Over 80% of the world's ferrochrome is utilised in the production of stainless steel. In 2006, 28,000,000 tons of stainless steel were produced. Stainless steel depends on chromium for its appearance and resistance to corrosion. Average chrome content in stainless steel is approx. 18%. It is also used to add chromium to carbon steel. FeCr from South Africa, known as "charge chrome" and produced from a Cr containing ...
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Ferrocerium
Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of iron and/or magnesium. When struck with a harder material, the mixture produces hot sparks that can reach temperatures of when rapidly oxidized by the process of striking the rod. Striking both scrapes fragments off, exposing them to the oxygen in the air, and easily ignites them by friction heat due to cerium's remarkably low ignition temperature of ~. Its easy flammability gives ferrocerium many commercial applications, such as the ignition source for lighters, strikers for gas welding and cutting torches, deoxidization in metallurgy, and ferrocerium rods. Because of ferrocerium's ability to ignite in adverse conditions, rods of ferrocerium (also called ferro rods, spark rods, and flint-spark-lighters) are commonly used as an emerge ...
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Ferroniobium
Ferroniobium is an important iron-niobium alloy, with a niobium content of 60-70%. It is the main source for niobium alloying of HSLA steel and covers more than 80% of the worldwide niobium production. The niobium is mined from pyrochlore deposits and is subsequently transformed into the niobium pentoxide Nb2O5. This oxide is mixed with iron oxide and aluminium and is reduced in an aluminothermic reaction to niobium and iron. The component metals can be purified in an electron beam furnace or the alloy can be used as it is. For alloying with steel the ferroniobium is added to molten steel before casting. The largest producers of ferroniobium are the same as for niobium and are located in Brazil and Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot .... External links * *ISO 545 ...
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Ferromanganese
Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a blast furnace or an electric arc furnace-type system, called a submerged arc furnace. The oxides undergo carbothermal reduction in the furnaces, producing the ferromanganese. Ferromanganese is used as a deoxidizer for steel. A North American standard specification is ASTM A99. The ten grades covered under this specification includes; *Standard ferromanganese *Medium-carbon ferromanganese *Low-carbon ferromanganese A similar material is a pig iron with high content of manganese, is called spiegeleisen, or specular pig iron. History 350px, lang=en, Evolution of global manganese production, by processes. In 1856, Robert Forester Mushet "used manganese to improve the ability of steel produced by the Bessemer process to withstand rolling and f ...
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Ferroboron
Ferroboron (FeB) is a ferroalloy consisting of iron and boron. The metal usually contains 17.5% to 20% boron and is used to produce boron steels. Description Ferroboron is (CAS Registry Number 11108–67-1) is a ferroalloy of iron and boron with boron content between 17.5 and 20%. It is manufactured either by carbothermic reduction of boric acid in an electric arc furnace together with carbon steel, or by the aluminothermic reduction of boric acid in the presence of iron. Ferroboron is added to C-Mn and other low alloy steels to improve hardenability (see Boron steel), and can also act as a nitrogen scavenger in steel, and in the production of NdFeB magnets. See also *Iron boride *Boriding Boriding, also called boronizing, is the process by which boron is added to a metal or alloy. It is a type of surface hardening. In this process boron atoms are diffused into the surface of a metal component. The resulting surface contains metal ... References {{reflist, refs = {{Citatio ...
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Ferroaluminum
Ferroaluminum (FeAl) is a ferroalloy, consisting of iron and aluminium. The metal usually consists of 40% to 60% aluminium and applications of ferroaluminum include the deoxidation of steel, hardfacing applications, reducing agent, thermite reactions, AlNiCo magnets, and alloying additions to welding wires and fluxes. The alloy is also known for the ability to manufacture low melting point alloys and its ability to carry out aluminothermic welding. Ferroaluminum does not currently have a CAS Registry Number. The presence of iron in aluminum helps in the decrease of casting defects, improves tensile, yield, hardness, and maintains strength at high temperatures. The first recorded usage of the word "ferroaluminum" was in 1887. Ferroaluminum can also be nitrided, as the aluminium bonds well with the nitrogen forming a hard case. The aluminum provided in the alloy helps with this process. The majority of the world's ferroaluminum is produced by Australia, China, Russia, the US and Ca ...
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Ferrovanadium
Ferrovanadium (FeV) is an alloy formed by combining iron and vanadium with a vanadium content range of 35–85%. The production of this alloy results in a grayish silver crystalline solid that can be crushed into a powder called "ferrovanadium dust".Hathaway, G. J.; Proctor, N. H. ''Proctor and Hughes chemical hazards of the workplace''; Wiley-Interscience: Hoboken, 2004. Ferrovanadium is a universal hardener, strengthener and anti-corrosive additive for steels like high-strength low-alloy steel, tool steels, as well as other ferrous-based products. It has significant advantages over both iron and vanadium individually. Ferrovanadium is used as an additive to improve the qualities of ferrous alloys. One such use is to improve corrosion resistance to alkaline reagents as well as sulfuric and hydrochloric acids. It is also used to improve the tensile strength to weight ratio of the material. One application of such steels is in the chemical processing industry for high pressure h ...
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