Ferro Alloys
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Ferro Alloys
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015. Compounds The main ferroalloys are: *FeAl – ferroaluminum *FeB – ferroboron – 12–20% of boron, max. 3% of silicon, max. 2% aluminium, max. 1% of carbon *FeCe – ferrocerium *FeCr – ferrochromium *FeMg – ferromagnesium *FeMn – ferromanganese *FeMo – ferromolybdenum – min. 60% Mo, max. 1% Si, max. 0.5% Cu *FeNb – ...
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Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ...
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Ferrocerium
Ferrocerium (also known in Europe as Auermetall) is a synthetic pyrophoric alloy of mischmetal (cerium, lanthanum, neodymium, other trace lanthanides and some iron – about 95% lanthanides and 5% iron) hardened by blending in oxides of iron and/or magnesium. When struck with a harder material, the mixture produces hot sparks that can reach temperatures of when rapidly oxidized by the process of striking the rod. Striking both scrapes fragments off, exposing them to the oxygen in the air, and easily ignites them by friction heat due to cerium's remarkably low ignition temperature of ~. Its easy flammability gives ferrocerium many commercial applications, such as the ignition source for lighters, strikers for gas welding and cutting torches, deoxidization in metallurgy, and ferrocerium rods. Because of ferrocerium's ability to ignite in adverse conditions, rods of ferrocerium (also called ferro rods, spark rods, and flint-spark-lighters) are commonly used as an emerge ...
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Ferrouranium
Ferrouranium, also called ferro-uranium, is a ferroalloy, an alloy of iron and uranium, after World War II usually depleted uranium. Composition and properties The alloy contains about 35–50% uranium and 1.5–4.0% carbon. At least two intermetallic compounds of iron and uranium were identified: U6Fe and UFe2. Small amounts of uranium can drastically lower the melting point of iron and vice versa. reportedly melts at 1230 °C, at 805 °C; a mixture of these two can have melting point as low as 725 °C, a mixture of iron and can have melting point of 1055 °C. As ferrouranium readily dissolves in mineral acids, its chemical analysis is not problematic. Use The first uses of ferrouranium date back to 1897, when the French government attempted to use it for guns. Ferrouranium is used as a deoxidizer (more powerful than ferrovanadium), for denitrogenizing steel, for forming carbides, and as an alloying element. In ferrous alloys, uranium increases the elastic limit and the tensile ...
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Ferrotitanium
Ferrotitanium is a ferroalloy, an alloy of iron and titanium with between 10–20% iron and 45–75% titanium and sometimes a small amount of carbon. It is used in steelmaking as a cleansing agent for iron and steel; the titanium is highly reactive with sulfur, carbon, oxygen, and nitrogen, forming insoluble compounds and sequestering them in slag, and is therefore used for deoxidizing, and sometimes for desulfurization and denitrogenation. In steelmaking the addition of titanium yields metal with finer grain structure. Ferrotitanium can be manufactured by mixing titanium sponge and scrap with iron and melting them together in an induction furnace. Ferrotitanium powder can be also used as a fuel in some pyrotechnic compositions. References External links *{{cite web , url = http://minerals.usgs.gov/minerals/pubs/commodity/ferroalloys/myb1-2006-feall.pdf , title =Minerals Yearbook 2006: Ferroalloys , publisher = United States Geological Survey The United States Geologica ...
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Ferrosilicon Magnesium
Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerated in the presenc ...
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Ferrosilicon
Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in the presence of iron. Typical sources of iron are scrap iron or millscale. Ferrosilicons with silicon content up to about 15% are made in blast furnaces lined with acid fire bricks. Ferrosilicons with higher silicon content are made in electric arc furnaces. The usual formulations on the market are ferrosilicons with 15%, 45%, 75%, and 90% silicon. The remainder is iron, with about 2% consisting of other elements like aluminium and calcium. An overabundance of silica is used to prevent formation of silicon carbide. Microsilica is a useful byproduct. A mineral perryite is similar to ferrosilicon, with its composition Fe5Si2. In contact with water, ferrosilicon may slowly produce hydrogen. The reaction, which is accelerated in the presenc ...
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Ferrophosphorus
Ferrophosphorus is a ferroalloy, an alloy of iron and phosphorus. It contains high proportion of iron phosphides, Fe2P and Fe3P. Its CAS number is 8049-19-2. The usual grades contain either 18 or 25% of phosphorus. It is a gray solid material with melting point between 1050-1100 °C. It may liberate phosphine in contact with water. Very fine powder can be combustible. Ferrophosphorus is used in metallurgy as a source of phosphorus for alloying, for deoxidizing the melt and for removal of unwanted compounds into slag. Ferrophosphorus is a byproduct of Submerged-arc furnace for phosphorus production, phosphorus production in submerged-arc furnaces from apatites, by their reduction with carbon. It is formed from the iron oxide impurities. Addition of ferrophosphorus is used to produce powder metallurgy (P/M) steels with favorable magnetic properties, e.g. high saturation (magnetic), saturation induction. Iron phosphide acts here as a solid solution hardener and a sintering aid. U ...
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Nickel Pig Iron
lang=en, upright=1.5, World production of nickel pig iron, and proportion of that in the primary nickel production., alt=graphique, link=File:Nickel_pig_iron_production.svg%3Flang=en Nickel pig iron (NPI) is a low grade ferronickel invented in China as a cheaper alternative to pure nickel for the production of stainless steel. The production process of nickel pig iron utilizes lateritic nickel ores instead of pure nickel sold on the world market. The alternative was developed as a response to the high price of pure nickel. The estimated cost of a ton of nickel pig iron ranged between US$16,500 and $18,000 in 2012, and this cheaper substitute for pure nickel influences the price of nickel on the world market by lowering the demand in certain applications, the most important being the production of stainless steel, representing about two-thirds of nickel use. Nickel pig iron is made of low-grade nickel ore, coking coal, and a mixture of gravel and sand as an aggregate. This mixtu ...
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Ferronickel
Ferroalloy refers to various alloys of iron with a high proportion of one or more other elements such as manganese (Mn), aluminium (Al), or silicon (Si). They are used in the production of steels and alloys. The alloys impart distinctive qualities to steel and cast iron or serve important functions during production and are, therefore, closely associated with the iron and steel industry, the leading consumer of ferroalloys. The leading producers of ferroalloys in 2014 were China, South Africa, India, Russia and Kazakhstan, which accounted for 84% of the world production. World production of ferroalloys was estimated as 52.8 million tonnes in 2015. Compounds The main ferroalloys are: *FeAl – ferroaluminum *FeB – ferroboron – 12–20% of boron, max. 3% of silicon, max. 2% aluminium, max. 1% of carbon *FeCe – ferrocerium *FeCr – ferrochromium *FeMg – ferromagnesium *FeMn – ferromanganese *FeMo – ferromolybdenum – min. 60% Mo, max. 1% Si, max. 0.5% Cu *FeNb – ...
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Ferroniobium
Ferroniobium is an important iron-niobium alloy, with a niobium content of 60-70%. It is the main source for niobium alloying of HSLA steel and covers more than 80% of the worldwide niobium production. The niobium is mined from pyrochlore deposits and is subsequently transformed into the niobium pentoxide Nb2O5. This oxide is mixed with iron oxide and aluminium and is reduced in an aluminothermic reaction to niobium and iron. The component metals can be purified in an electron beam furnace or the alloy can be used as it is. For alloying with steel the ferroniobium is added to molten steel before casting. The largest producers of ferroniobium are the same as for niobium and are located in Brazil and Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot .... External links * *ISO 545 ...
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Ferromolybdenum
Ferro molybdenum is an important iron-molybdenum metal alloy, with a molybdenum content of 60-75% It is the main source for molybdenum alloying of HSLA steel. Production The alloy is produced by heating a mixture of molybdenum(VI) oxide MoO3, aluminium, and iron. The oxide and the aluminium combine via an aluminothermic reaction to give molybdenum in situ. The ferromolybdenum can be purified by electron beam melting Electron-beam additive manufacturing, or electron-beam melting (EBM) is a type of additive manufacturing, or 3D printing, for metal parts. The raw material (metal powder or wire) is placed under a vacuum and fused together from heating by an e ... or used as it is. For alloying with steel the ferromolybdenum is added to molten steel before casting. Among the biggest suppliers of ferromolybdenum in Europe are the English trading house Derek Raphael and Co Ltd and the English Trading House MTALX LTD in London. A large ferromolybdenum producer in the US is Langeloth ...
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