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Femtosecond
A femtosecond is a unit of time in the International System of Units (SI) equal to 10 or of a second; that is, one quadrillionth, or one millionth of one billionth, of a second. For context, a femtosecond is to a second as a second is to about 31.71 million years; a ray of light travels approximately 0.3  μm (micrometers) in 1 femtosecond, a distance comparable to the diameter of a virus.Compared with overview in: Page 3 The word ''femtosecond'' is formed by the SI prefix ''femto'' and the SI unit ''second''. Its symbol is fs. A femtosecond is equal to 1000 attoseconds, or 1/1000 picosecond. Because the next higher SI unit is 1000 times larger, times of 10−14 and 10−13 seconds are typically expressed as tens or hundreds of femtoseconds. * Typical time steps for molecular dynamics simulations are on the order of 1 fs. * The periods of the waves of visible light have a duration of about 2 femtoseconds. = = 2.0 \times 10^~ The precise duration depends on the ...
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Ultrafast Laser Spectroscopy
Ultrafast laser spectroscopy is a spectroscopic technique that uses ultrashort pulse lasers for the study of dynamics on extremely short time scales ( attoseconds to nanoseconds). Different methods are used to examine the dynamics of charge carriers, atoms, and molecules. Many different procedures have been developed spanning different time scales and photon energy ranges; some common methods are listed below. Attosecond-to-picosecond spectroscopy Dynamics on the as to fs time scale are in general too fast to be measured electronically. Most measurements are done by employing a sequence of ultrashort light pulses to initiate a process and record its dynamics. The temporal width (duration) of the light pulses has to be on the same scale as the dynamics that are to be measured or even shorter. Light sources Titanium-sapphire laser Ti-sapphire lasers are tunable lasers that emit red and near-infrared light (700 nm- 1100 nm). Ti-sapphire laser oscillators use Ti doped-s ...
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Femtosecond Pulse Shaping
In optics, femtosecond pulse shaping refers to manipulations with temporal profile of an ultrashort laser pulse. Pulse shaping can be used to shorten/elongate the duration of optical pulse, or to generate complex pulses. Introduction Generation of sequences of ultrashort optical pulses is key in realizing ultra high speed optical networks, Optical Code Division Multiple Access (OCDMA) systems, chemical and biological reaction triggering and monitoring etc. Based on the requirement, pulse shapers may be designed to stretch, compress or produce a train of pulses from a single input pulse. The ability to produce trains of pulses with femtosecond or picosecond separation implies transmission of optical information at very high speeds. In ultrafast laser science pulse shapers are often used as a complement to pulse compressors in order to fine-tune high-order dispersion compensation and achieve transform-limited few-cycle optical pulses. Techniques A pulse shaper may be visualized ...
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Femtochemistry
Femtochemistry is the area of physical chemistry that studies chemical reactions on extremely short timescales (approximately 10−15 seconds or one femtosecond, hence the name) in order to study the very act of atoms within molecules (reactants) rearranging themselves to form new molecules (products). In a 1988 issue of the journal ''Science'', Ahmed Hassan Zewail published an article using this term for the first time, stating "Real-time femtochemistry, that is, chemistry on the femtosecond timescale...". Later in 1999, Zewail received the Nobel Prize in Chemistry for his pioneering work in this field showing that it is possible to see how atoms in a molecule move during a chemical reaction with flashes of laser light. Application of femtochemistry in biological studies has also helped to elucidate the conformational dynamics of stem-loop RNA structures. Many publications have discussed the possibility of controlling chemical reactions by this method, but this remains contr ...
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Attosecond
An attosecond (symbol as) is a unit of time in the International System of Units (SI) equal to 1×10−18 of a second (one quintillionth of a second). For comparison, an attosecond is to a second what a second is to about 31.71 billion years.Electron Motion Filmed
28 February 2008
The word "attosecond" is formed by the ''atto'' and the unit ''second''. ''Atto-'' was derived from the Danish word for eighteen (''atten''). Its symbol is as. An attosecond is equal to 1000
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Chemical Reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur. The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course ...
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Molecular Dynamics
Molecular dynamics (MD) is a computer simulation method for analyzing the physical movements of atoms and molecules. The atoms and molecules are allowed to interact for a fixed period of time, giving a view of the dynamic "evolution" of the system. In the most common version, the trajectories of atoms and molecules are determined by numerically solving Newton's equations of motion for a system of interacting particles, where forces between the particles and their potential energies are often calculated using interatomic potentials or molecular mechanical force fields. The method is applied mostly in chemical physics, materials science, and biophysics. Because molecular systems typically consist of a vast number of particles, it is impossible to determine the properties of such complex systems analytically; MD simulation circumvents this problem by using numerical methods. However, long MD simulations are mathematically ill-conditioned, generating cumulative erro ...
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Picosecond
A picosecond (abbreviated as ps) is a unit of time in the International System of Units (SI) equal to 10−12 or (one trillionth) of a second. That is one trillionth, or one millionth of one millionth of a second, or 0.000 000 000 001 seconds. A picosecond is to one second as one second is to approximately 31,689 years. Multiple technical approaches achieve imaging within single-digit picoseconds: for example, the streak camera or intensified CCD (ICCD) cameras are able to picture the motion of light. One picosecond is equal to 1000 femtoseconds, or 1/1000 nanoseconds. Because the next SI unit is 1000 times larger, measurements of 10−11 and 10−10 second are typically expressed as tens or hundreds of picoseconds. Some notable measurements in this range include: * 1.0 picoseconds (1.0 ps) – cycle time for electromagnetic frequency 1 terahertz (THz) (1 x 1012 hertz), an inverse unit. This corresponds to a wavelength of 0.3 mm, as can be calculated by ...
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Second
The second (symbol: s) is the unit of time in the International System of Units (SI), historically defined as of a day – this factor derived from the division of the day first into 24 hours, then to 60 minutes and finally to 60 seconds each (24 × 60 × 60 = 86400). The current and formal definition in the International System of Units ( SI) is more precise:The second ..is defined by taking the fixed numerical value of the caesium frequency, Δ''ν''Cs, the unperturbed ground-state hyperfine transition frequency of the caesium 133 atom, to be when expressed in the unit Hz, which is equal to s−1. This current definition was adopted in 1967 when it became feasible to define the second based on fundamental properties of nature with caesium clocks. Because the speed of Earth's rotation varies and is slowing ever so slightly, a leap second is added at irregular intervals to civil time to keep clocks in sync with Earth's rotation. Uses Analog clocks and watches often ...
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Pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compounds. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic, organic, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each year. Physical principles ...
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Green
Green is the color between cyan and yellow on the visible spectrum. It is evoked by light which has a dominant wavelength of roughly 495570 nm. In subtractive color systems, used in painting and color printing, it is created by a combination of yellow and cyan; in the RGB color model, used on television and computer screens, it is one of the additive primary colors, along with red and blue, which are mixed in different combinations to create all other colors. By far the largest contributor to green in nature is chlorophyll, the chemical by which plants photosynthesize and convert sunlight into chemical energy. Many creatures have adapted to their green environments by taking on a green hue themselves as camouflage. Several minerals have a green color, including the emerald, which is colored green by its chromium content. During post-classical and early modern Europe, green was the color commonly associated with wealth, merchants, bankers, and the gentry, while red was ...
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Human Eye
The human eye is a sensory organ, part of the sensory nervous system, that reacts to visible light and allows humans to use visual information for various purposes including seeing things, keeping balance, and maintaining circadian rhythm. The eye can be considered as a living optical device. It is approximately spherical in shape, with its outer layers, such as the outermost, white part of the eye (the sclera) and one of its inner layers (the pigmented choroid) keeping the eye essentially light tight except on the eye's optic axis. In order, along the optic axis, the optical components consist of a first lens (the cornea—the clear part of the eye) that accomplishes most of the focussing of light from the outside world; then an aperture (the pupil) in a diaphragm (the iris—the coloured part of the eye) that controls the amount of light entering the interior of the eye; then another lens (the crystalline lens) that accomplishes the remaining focussing of light i ...
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Hydronium
In chemistry, hydronium (hydroxonium in traditional British English) is the common name for the aqueous cation , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid is dissolved in water, as Arrhenius acid molecules in solution give up a proton (a positive hydrogen ion, ) to the surrounding water molecules (). In fact, acids must be surrounded by more than a single water molecule in order to ionize, yielding aqueous and conjugate base. Three main structures for the aqueous proton have garnered experimental support: The Eigen cation, which is a tetrahydrate, H3O+(H2O)3; the Zundel cation, which is a symmetric dihydrate, H+(H2O)2; and the Stoyanov cation, an expanded Zundel cation, which is a hexahydrate: H+(H2O)2(H2O)4. Spectroscopic evidence from well-defined IR spectra overwhelmingly supports the Stoyanov cation as the predominant form. For this reason, it has been suggested that wherever p ...
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