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Enthalpy–entropy Chart
An enthalpy–entropy chart, also known as the ''H''–''S'' chart or Mollier diagram, plots the total heat against entropy, describing the enthalpy of a thermodynamic system. A typical chart covers a pressure range of 0.01–1000 Bar (unit), bar, and temperatures up to 800 degrees Celsius. It shows enthalpy H in terms of internal energy U, pressure p and volume V using the relationship H = U + pV \,\! (or, in terms of specific enthalpy, specific entropy and specific volume, h = u + pv \! ). History The diagram was created in 1904, when Richard Mollier plotted the total heat against entropy . At the 1923 Thermodynamics Conference held in Los Angeles it was decided to name, in his honor, as a "Mollier diagram" any thermodynamic diagram using the enthalpy as one of its axes. Details On the diagram, lines of constant pressure, constant temperature and volume are plotted, so in a two-phase region, the lines of constant pressure and temperature coincide. Thus, coordinates on t ...
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Isobaric Process
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the Thermodynamic system, system stays constant: Δ''P'' = 0. The heat transferred to the system does work (thermodynamics), work, but also changes the internal energy (''U'') of the system. This article uses the physics sign convention for work, where positive work is work (thermodynamics)#Sign convention, work done by the system. Using this convention, by the first law of thermodynamics, : Q = \Delta U + W\, where ''W'' is work, ''U'' is internal energy, and ''Q'' is heat. Pressure-volume work by the closed system is defined as: :W = \int \! p \,dV \, where Δ means change over the whole process, whereas ''d'' denotes a differential. Since pressure is constant, this means that : W = p \Delta V\, . Applying the ideal gas law, this becomes : W = n\,R\,\Delta T with ''R'' representing the gas constant, and ''n'' representing the amount of substance, which is ass ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, Work (thermodynamics), work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantity, physical quantities but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to various topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering, and mechanical engineering, as well as other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the thermodynamic efficiency, efficiency of early steam engines, particularly through the work of French physicist Nicolas Léonard Sadi Carnot, Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win ...
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Contour Line
A contour line (also isoline, isopleth, isoquant or isarithm) of a Function of several real variables, function of two variables is a curve along which the function has a constant value, so that the curve joins points of equal value. It is a cross-section (geometry)#Definition, plane section of the graph of a function of two variables, three-dimensional graph of the function f(x,y) parallel to the (x,y)-plane. More generally, a contour line for a function of two variables is a curve connecting points where the function has the same particular value. In cartography, a contour line (often just called a "contour") joins points of equal elevation (height) above a given level, such as mean sea level. A contour map is a map illustrated with contour lines, for example a topographic map, which thus shows valleys and hills, and the steepness or gentleness of slopes. The contour interval of a contour map is the difference in elevation between successive contour lines. The gradient of t ...
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Thermodynamic Diagrams
Thermodynamic diagrams are diagrams used to represent the thermodynamic states of a material (typically fluid) and the consequences of manipulating this material. For instance, a temperature–entropy diagram (Temperature–entropy diagram, T–s diagram) may be used to demonstrate the behavior of a fluid as it is changed by a compressor. Overview Especially in meteorology, they are used to analyze the actual state of the atmosphere derived from the measurements of radiosondes, usually obtained with weather balloons. In such diagrams, temperature and humidity values (represented by the dew point) are displayed with respect to atmospheric pressure, pressure. Thus the diagram gives at a first glance the actual atmospheric stratification and vertical water vapor distribution. Further analysis gives the actual base and top height of cumulus cloud, convective clouds or possible instabilities in the stratification. By assuming the energy amount due to solar radiation it is possibl ...
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Psychrometric Chart
Psychrometrics (or psychrometry, ; also called hygrometry) is the field of engineering concerned with the physical and thermodynamic properties of gas-vapor mixtures. History With the inventions of the hygrometer and thermometer, the theories of combining the two began to emerge during the sixteenth and seventeenth centuries. In 1818, a German inventor, Ernst Ferdinand August (1795-1870), patented the term “psychrometer”, from the Greek language meaning “cold measure”. The psychrometer is a hygrometric instrument based on the principle that dry air enhances evaporation, unlike wet air, which slows it. Common applications Although the principles of psychrometry apply to any physical system consisting of gas-vapor mixtures, the most common system of interest is the mixture of water vapor and air, because of its application in heating, ventilation, and air-conditioning and meteorology. In human terms, our thermal comfort is in large part a consequence of not just th ...
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Malt
Malt is any cereal grain that has been made to germinate by soaking in water and then stopped from germinating further by drying with hot air, a process known as "malting". Malted grain is used to make beer, whisky, malted milk, malt vinegar, confections such as Maltesers and Whoppers, flavored drinks such as Horlicks, Ovaltine, and Milo (drink), Milo, and some baked goods, such as malt loaf, bagels, and Rich Tea biscuits. Malted grain that has been ground into a coarse meal is known as "sweet meal". Malting grain develops the enzymes (α-amylase, β-amylase) required for modifying the grains' starches into various types of sugar, including monosaccharide glucose, disaccharide maltose, trisaccharide maltotriose, and higher sugars called maltodextrines. It also develops other enzymes, such as proteases, that break down the proteins in the grain into forms that can be used by yeast. The point at which the malting process is stopped affects the starch-to-enzyme ratio, and partly ...
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Thermal Power Station
A thermal power station, also known as a thermal power plant, is a type of power station in which the heat energy generated from various fuel sources (e.g., coal, natural gas, nuclear fuel, etc.) is converted to electrical energy. The heat from the source is converted into mechanical energy using a thermodynamic power cycle (such as a Diesel cycle, Rankine cycle, Brayton cycle, etc.). The most common cycle involves a working fluid (often water) heated and boiled under high pressure in a pressure vessel to produce high-pressure steam. This high pressure-steam is then directed to a turbine, where it rotates the turbine's blades. The rotating turbine is mechanically connected to an electric generator which converts rotary motion into electricity. Fuels such as natural gas or oil can also be burnt directly in gas turbines ( internal combustion), skipping the steam generation step. These plants can be of the open cycle or the more efficient combined cycle type. The majorit ...
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Colloid
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word '' suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study began in 1845 by Franc ...
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Steam Turbine
A steam turbine or steam turbine engine is a machine or heat engine that extracts thermal energy from pressurized steam and uses it to do mechanical work utilising a rotating output shaft. Its modern manifestation was invented by Sir Charles Parsons in 1884. It revolutionized marine propulsion and navigation to a significant extent. Fabrication of a modern steam turbine involves advanced metalwork to form high-grade steel alloys into precision parts using technologies that first became available in the 20th century; continued advances in durability and efficiency of steam turbines remains central to the energy economics of the 21st century. The largest steam turbine ever built is the 1,770 MW Arabelle steam turbine built by Arabelle Solutions (previously GE Steam Power), two units of which will be installed at Hinkley Point C Nuclear Power Station, England. The steam turbine is a form of heat engine that derives much of its improvement in thermodynamic efficiency from the u ...
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Rankine Cycle
The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University. Heat energy is supplied to the system via a boiler where the working fluid (typically water) is converted to a high-pressure gaseous state (steam) in order to turn a turbine. After passing over the turbine the fluid is allowed to condense back into a liquid state as waste heat energy is rejected before being returned to boiler, completing the cycle. Friction losses throughout the system are often neglected for the purpose of simplifying calculations as such losses are usually much less significant than thermodynamic losses, especially in larger systems. Description The Rankine cycle closely describes ...
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