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Dynamical Heterogeneity
Dynamical heterogeneity describes the behavior of glass-forming materials when undergoing a phase transition from the liquid state to the glassy state. In dynamical heterogeneity, the dynamics of cooling to a glassy state show variation within the material. Polymers Polymer properties include viscoelasticity and may be synthetic or natural. When a polymeric liquid is cooled below its freezing temperature without crystallizing, it becomes a supercooled liquid. When the supercooled liquid is further cooled, it becomes a glass. The temperature at which a polymer becomes a glass by fast cooling is called the glass transition temperature Tg. At this temperature, viscosity reaches up to 1013 poise depending upon cooling-rate. Phase transitions It is possible for a phase transition from polymer to glassy state to take place. Polymer glass transitions have many determinants including relaxation time, viscosity and cage size. At low temperatures the dynamics become very slow (sluggish) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Relaxation (physics)
In the physical sciences, relaxation usually means the return of a perturbed system into equilibrium. Each relaxation process can be categorized by a relaxation time τ. The simplest theoretical description of relaxation as function of time ''t'' is an exponential law (exponential decay A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation, where is the quantity and (lambda) is a positive rate ...). In simple linear systems Mechanics: Damped unforced oscillator Let the homogeneous differential equation: :m\frac+\gamma\frac+ky=0 model damped harmonic oscillator, damped unforced oscillations of a weight on a spring. The displacement will then be of the form y(t) = A e^ \cos(\mu t - \delta). The constant T (=2m/\gamma) is called the relaxation time of the system and the constant μ is the quasi-frequency. Electronics: RC circuit In an RC ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Time
Time is the continued sequence of existence and events that occurs in an apparently irreversible succession from the past, through the present, into the future. It is a component quantity of various measurements used to sequence events, to compare the duration of events or the intervals between them, and to quantify rates of change of quantities in material reality or in the conscious experience. Time is often referred to as a fourth dimension, along with three spatial dimensions. Time has long been an important subject of study in religion, philosophy, and science, but defining it in a manner applicable to all fields without circularity has consistently eluded scholars. Nevertheless, diverse fields such as business, industry, sports, the sciences, and the performing arts all incorporate some notion of time into their respective measuring systems. 108 pages. Time in physics is operationally defined as "what a clock reads". The physical nature of time is addre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Measurement
Measurement is the quantification of attributes of an object or event, which can be used to compare with other objects or events. In other words, measurement is a process of determining how large or small a physical quantity is as compared to a basic reference quantity of the same kind. The scope and application of measurement are dependent on the context and discipline. In natural sciences and engineering, measurements do not apply to nominal properties of objects or events, which is consistent with the guidelines of the ''International vocabulary of metrology'' published by the International Bureau of Weights and Measures. However, in other fields such as statistics as well as the social and behavioural sciences, measurements can have multiple levels, which would include nominal, ordinal, interval and ratio scales. Measurement is a cornerstone of trade, science, technology and quantitative research in many disciplines. Historically, many measurement systems existed fo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of heat and light. Energy is a conserved quantity—the law of conservation of energy states that energy can be converted in form, but not created or destroyed. The unit of measurement for energy in the International System of Units (SI) is the joule (J). Common forms of energy include the kinetic energy of a moving object, the potential energy stored by an object (for instance due to its position in a field), the elastic energy stored in a solid object, chemical energy associated with chemical reactions, the radiant energy carried by electromagnetic radiation, and the internal energy contained within a thermodynamic system. All living organisms constantly take in and release energy. Due to mass–energy equivalence, any object that has mass whe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Correlation Functions
The cross-correlation matrix of two random vectors is a matrix containing as elements the cross-correlations of all pairs of elements of the random vectors. The cross-correlation matrix is used in various digital signal processing algorithms. Definition For two random vectors \mathbf = (X_1,\ldots,X_m)^ and \mathbf = (Y_1,\ldots,Y_n)^, each containing random elements whose expected value and variance exist, the cross-correlation matrix of \mathbf and \mathbf is defined by and has dimensions m \times n. Written component-wise: :\operatorname_ = \begin \operatorname _1 Y_1& \operatorname _1 Y_2& \cdots & \operatorname _1 Y_n\\ \\ \operatorname _2 Y_1& \operatorname _2 Y_2& \cdots & \operatorname _2 Y_n\\ \\ \vdots & \vdots & \ddots & \vdots \\ \\ \operatorname_m Y_1& \operatorname _m Y_2& \cdots & \operatorname _m Y_n\\ \\ \end The random vectors \mathbf and \mathbf need not have the same dimension, and either might be a scalar value. Example For example, if \mathbf = \left ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microscopic
The microscopic scale () is the scale of objects and events smaller than those that can easily be seen by the naked eye, requiring a lens (optics), lens or microscope to see them clearly. In physics, the microscopic scale is sometimes regarded as the scale between the macroscopic scale and the quantum realm, quantum scale. Microscopic units and measurements are used to classify and describe very small objects. One common microscopic length scale unit is the micrometre (also called a ''micron'') (symbol: μm), which is one millionth of a metre. History Whilst compound microscopes were first developed in the 1590s, the significance of the microscopic scale was only truly established in the 1600s when Marcello Malpighi, Marcello Malphigi and Antonie van Leeuwenhoek microscopically observed frog lungs and microorganisms. As microbiology was established, the significance of making scientific observations at a microscopic level increased. Published in 1665, Robert Hooke’s book Mi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ballistic
Ballistics may refer to: Science * Ballistics, the science that deals with the motion, behavior, and effects of projectiles ** Forensic ballistics, the science of analyzing firearm usage in crimes ** Internal ballistics, the study of the processes accelerating a projectile ** Transition ballistics, the study of the projectile's behavior when it leaves the barrel ** External ballistics, the study of the passage of the projectile through space or the air ** Terminal ballistics, the study of the interaction of a projectile with its target * Ballistic conduction, conduction of electricity with negligible charge scattering * Ballistic movement of muscles in an animal Combat * Ballistic missile, a missile that follows a sub-orbital flightpath * Ballistic knife, a specialized combat knife with a detachable, self-propelled blade * Ballistic shield, a shield meant to protect the user from bullets Arts and media Comics * Ballistic (Image Comics), a comic character of Top Cow Product ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dynamics (mechanics)
Dynamics is the branch of classical mechanics that is concerned with the study of forces and their effects on motion. Isaac Newton was the first to formulate the fundamental physical laws that govern dynamics in classical non-relativistic physics, especially his second law of motion. Principles Generally speaking, researchers involved in dynamics study how a physical system might develop or alter over time and study the causes of those changes. In addition, Newton established the fundamental physical laws which govern dynamics in physics. By studying his system of mechanics, dynamics can be understood. In particular, dynamics is mostly related to Newton's second law of motion. However, all three laws of motion are taken into account because these are interrelated in any given observation or experiment. Linear and rotational dynamics The study of dynamics falls under two categories: linear and rotational. Linear dynamics pertains to objects moving in a line and involves such ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phase Transition
In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states of matter: solid, liquid, and gas, and in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium, certain properties of the medium change as a result of the change of external conditions, such as temperature or pressure. This can be a discontinuous change; for example, a liquid may become gas upon heating to its boiling point, resulting in an abrupt change in volume. The identification of the external conditions at which a transformation occurs defines the phase transition point. Types of phase transition At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Viscoelasticity
In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed. Viscoelastic materials have elements of both of these properties and, as such, exhibit time-dependent strain. Whereas elasticity is usually the result of bond stretching along crystallographic planes in an ordered solid, viscosity is the result of the diffusion of atoms or molecules inside an amorphous material.Meyers and Chawla (1999): "Mechanical Behavior of Materials", 98-103. Background In the nineteenth century, physicists such as Maxwell, Boltzmann, and Kelvin researched and experimented with creep and recovery of glasses, metals, and rubbers. Viscoelasticity was further examined in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
