Dry Jet-wet Spinning
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Dry Jet-wet Spinning
Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments.. Melt Spinning If the polymer is a thermoplastic then it can undergo melt spinning. The molten polymer is extruded through a spinneret composed of capillaries where the resulting filament is solidified by cooling. Nylon, olefin, polyester, saran, and sulfar are produced via this process. Extrusion spinning Pellets or granules of the solid polymer are fed into an extruder. The pellets are compressed, heated and melted by an extrusion screw, then fed to a spinning pump and into the spinneret. Direct spinning The direct spinning process avoids the stage of solid polymer pellets. The polymer melt is produced from the raw materials, and then from the polymer finisher directly pumped to the spinning mill. Direct spinning is mainly applied during production of polyester fibers and filaments and is dedicated to high producti ...
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Polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'' ...
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Aramid
Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated body armor fabric and ballistic composites, in marine cordage, marine hull reinforcement, and as an asbestos substitute. The chain molecules in the fibers are highly oriented along the fiber axis. As a result, a higher proportion of the chemical bond contributes more to fiber strength than in many other synthetic fibers. Aramids have a very high melting point (>500 °C). Common aramid brand names include Kevlar, Nomex, and Twaron. Terminology and chemical structure ''Aramid'' is a shortened form of aromatic polyamide. The term was introduced in 1972, accepted in 1974 by the Federal Trade Commission of the USA as the name of a generic category of fiber distinct from nylon, and adopted by the International Standards Organisation in 1977. Aromatic in the name refers to the presence of aromatic rings ...
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Spinneret (polymers)
A spinneret is a device used to extrude a polymer solution or polymer melt to form fibers. Streams of viscous polymer exit via the spinneret into air or liquid leading to a phase inversion which allows the polymer to solidify. The individual polymer chains tend to align in the fiber because of viscous flow. This airstream liquid-to-fiber formation process is similar to the production process for cotton candy. The fiber production process is generally referred to as "spinning". Depending on the type of spinneret used, either solid or hollow fibers can be formed. Spinnerets are also used for electrospinning and electrospraying applications. They are sometimes called ''coaxial needles,'' or ''coaxial emitters.'' Spinnerets are usually made of metals with melting points too low to withstand the heating processes employed in industrial metallurgy, and thus are generally not used to form metallic fibers. See also * Electrospinning * Hollow fiber membrane * Spinning (polymers) * Tex ...
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Melt Electrospinning
Melt electrospinning is a processing technique to produce fibrous structures from polymer melts for applications that include tissue engineering, textiles and filtration. In general, electrospinning can be performed using either polymer melts or polymer solutions. However, melt electrospinning is distinct in that the collection of the fiber can very focused; combined with moving collectors, melt electrospinning writing is a way to perform 3D printing. Since volatile solvents are not used, there are benefits for some applications where solvent toxicity and accumulation during manufacturing are a concern. History The first description of melt electrospinning was by Charles Norton in a patent approved in 1936. After this first discovery, it wasn't until 1981 that melt electrospinning was described as part of a three-paper series. A meeting abstract on melt electrospinning in a vacuum was published by Reneker and Rangkupan 20 years later in 2001. Since this scientific publication i ...
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Electrospray
The name electrospray is used for an apparatus that employs electricity to disperse a liquid or for the fine aerosol resulting from this process. High voltage is applied to a liquid supplied through an emitter (usually a glass or metallic capillary). Ideally the liquid reaching the emitter tip forms a Taylor cone, which emits a liquid jet through its apex. Varicose waves on the surface of the jet lead to the formation of small and highly charged liquid droplets, which are radially dispersed due to Coulomb repulsion. History In the late 16th century William GilbertGilbert, W. (1628) De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (On the Magnet and Magnetic Bodies, and on That Great Magnet the Earth), London, Peter Short set out to describe the behaviour of magnetic and electrostatic phenomena. He observed that, in the presence of a charged piece of amber, a drop of water deformed into a cone. This effect is clearly related to electrosprays, even though Gilbert ...
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Microfiber
Microfiber (or microfibre) is synthetic fiber finer than one denier or decitex/thread, having a diameter of less than ten micrometers. A strand of silk is about one denier and about a fifth of the diameter of a human hair. The most common types of microfiber are made variously of polyesters; polyamides (e.g., nylon, Kevlar, Nomex); and combinations of polyester, polyamide, and polypropylene. Microfiber is used to make mats, knits, and weaves, for apparel, upholstery, industrial filters, and cleaning products. The shape, size, and combinations of synthetic fibers are chosen for specific characteristics, including softness, toughness, absorption, water repellence, electrostatics, and filtering ability. History Production of ultra-fine fibers (finer than 0.7 denier) dates to the late 1950s, using melt-blown spinning and flash spinning techniques. Initially, only fine staples of random length could be manufactured and very few applications were found. Then came experiments to p ...
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Polyacrylonitrile
Polyacrylonitrile (PAN), also known as polyvinyl cyanide and Creslan 61, is a synthetic, semicrystalline organic polymer resin, with the linear formula (C3H3N)n. Though it is thermoplastic, it does not melt under normal conditions. It degrades before melting. It melts above 300 °C if the heating rates are 50 degrees per minute or above. Almost all PAN resins are copolymers made from mixtures of monomers with acrylonitrile as the main monomer. It is a versatile polymer used to produce large variety of products including ultra filtration membranes, hollow fibers for reverse osmosis, fibers for textiles, and oxidized PAN fibers. PAN fibers are the chemical precursor of very high-quality carbon fiber. PAN is first thermally oxidized in air at 230 °C to form an oxidized PAN fiber and then carbonized above 1000 °C in inert atmosphere to make carbon fibers found in a variety of both high-tech and common daily applications such as civil and military aircraft primary and ...
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Polyethylene
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging ( plastic bags, plastic films, geomembranes and containers including bottles, etc.). , over 100 million tonnes of polyethylene resins are being produced annually, accounting for 34% of the total plastics market. Many kinds of polyethylene are known, with most having the chemical formula (C2H4)''n''. PE is usually a mixture of similar polymers of ethylene, with various values of ''n''. It can be ''low-density'' or ''high-density'': low-density polyethylene is extruded using high pressure () and high temperature (), while high-density polyethylene is extruded using low pressure () and low temperature (). Polyethylene is usually thermoplastic, but it can be modified to become thermosetting instead, for example, in cross-linked polyethylene. History Polyethylene was first synthesized by the German chemist Hans ...
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