Deflagrates
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Deflagrates
Deflagration (Lat: ''de + flagrare'', "to burn down") is subsonic combustion in which a pre-mixed flame propagates through a mixture of fuel and oxidizer. Deflagrations can only occur in pre-mixed fuels. Most fires found in daily life are diffusion flames. Deflagrations with flame speeds in the range of 1 m/sec differ from detonations which propagate supersonically through shock waves with speeds in the range of 1 km/sec. Applications Deflagrations are often used in engineering applications when the goal is to move an object such as a bullet in a firearm, or a piston in an internal combustion engine with the force of the expanding gas. Deflagration systems and products can also be used in mining, demolition and stone quarrying via gas pressure blasting as a beneficial alternative to high explosives. Flame physics The underlying flame physics can be understood with the help of an idealized model consisting of a uniform one-dimensional tube of unburnt and burned gaseous fuel, ...
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Explosives
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may al ...
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Thermal Diffusivity
In heat transfer analysis, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It measures the rate of transfer of heat of a material from the hot end to the cold end. It has the SI derived unit of m2/s. Thermal diffusivity is usually denoted by lowercase alpha (), but , , ( kappa), , and are also used. The formula is: :\alpha = \frac where * is thermal conductivity (W/(m·K)) * is specific heat capacity (J/(kg·K)) * is density (kg/m3) Together, can be considered the volumetric heat capacity (J/(m3·K)). As seen in the heat equation, :\frac = \alpha \nabla^2 T, one way to view thermal diffusivity is as the ratio of the time derivative of temperature to its curvature, quantifying the rate at which temperature concavity is "smoothed out". In a sense, thermal diffusivity is a contrasting measure to thermal inertia. In a substance with high thermal diffusivity, heat moves rapidly through it because the substa ...
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Combustion
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While the activation energy must be overcome to initiate combustion (e.g., using a lit match to light a fire), the heat from a flame may provide enough energy to make the reaction self-sustaining. Combustion is often a complicated sequence of elementary radical reactions. Solid fuels, such as wood and coal, first undergo endothermic pyrolysis to produce gaseous fuels whose combustion then supplies the heat required to produce more of them. Combustion is often hot enough that incandescent light in the form of either glowing or a flame is produced. A ...
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Pressure Piling
Pressure piling describes phenomena related to combustion of gases in a tube or long vessel. When a flame front propagates along a tube, the unburned gases ahead of the front are compressed, and hence heated. The amount of compression varies depending on the geometry and can range from twice to eight times the initial pressure. Where multiple vessels are connected by piping, ignition of gases in one vessel and pressure piling may result in a deflagration to detonation transition and very large explosion pressure. In electrical equipment in hazardous areas, if two electrical enclosures are connected by a conduit, an explosion of a gas in one of the compartments travels through the conduit into the next enclosure.Ernest C. Magison, ''Electrical Innstruments in Hazardous Locations 4th edition'', International Society of Automation, 1998 , page 153 The pressure of the 'primary' explosion together with the pressure from the 'secondary' explosion in the other compartment produces one ...
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Deflagration To Detonation Transition
Deflagration to detonation transition (DDT) refers to a phenomenon in ignitable mixtures of a flammable gas and air (or oxygen) when a sudden transition takes place from a deflagration type of combustion to a detonation type of explosion. Description A deflagration is characterized by a subsonic flame propagation velocity, typically far below , and relatively modest overpressures, typically below . The main mechanism of combustion propagation is of a flame front that moves forward through the gas mixture - in technical terms the reaction zone (chemical combustion) progresses through the medium by processes of diffusion of heat and mass. In its most benign form, a deflagration may simply be a flash fire. In contrast, a detonation is characterized by supersonic flame propagation velocities, perhaps up to , and substantial overpressures, up to . The main mechanism of detonation propagation is of a powerful pressure wave that compresses the unburnt gas ahead of the wave to a temp ...
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Conflagration
A conflagration is a large fire. Conflagrations often damage human life, animal life, health, and/or property. A conflagration can begin accidentally, be naturally caused (wildfire), or intentionally created (arson). A very large fire can produce a firestorm, in which the central column of rising heated air induces strong inward winds, which supply oxygen to the fire. Conflagrations can cause casualties including deaths or injuries from burns, trauma due to collapse of structures and attempts to escape, and smoke inhalation. Firefighting is the practice of extinguishing a conflagration, protecting life and property and minimizing damage and injury. One of the goals of fire prevention is to avoid conflagrations. When a conflagration is extinguished, there is often a fire investigation to determine the cause of the fire. Causes and types During a conflagration a significant movement of air and combustion products occurs. Hot gaseous products of combustion move upward, causin ...
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Speed Of Sound
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elastic medium. At , the speed of sound in air is about , or one kilometre in or one mile in . It depends strongly on temperature as well as the medium through which a sound wave is propagating. At , the speed of sound in air is about . The speed of sound in an ideal gas depends only on its temperature and composition. The speed has a weak dependence on frequency and pressure in ordinary air, deviating slightly from ideal behavior. In colloquial speech, ''speed of sound'' refers to the speed of sound waves in air. However, the speed of sound varies from substance to substance: typically, sound travels most slowly in gases, faster in liquids, and fastest in solids. For example, while sound travels at in air, it travels at in water (almost 4.3 times as fast) and at in iron (almost 15 times as fast). In an exceptionally stiff material such as diamond, sound travels a ...
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Flash Fire
A flash fire is a sudden, intense fire caused by ignition of a mixture of air and a dispersed flammable substance such as a solid (including dust), flammable or combustible liquid (such as an aerosol or fine mist), or a flammable gas. It is characterized by high temperature, short duration, and a rapidly moving flame front. Definition A flash fire is defined by NFPA 2112 (Standard on Flame-Resistant Clothing for Protection of Industrial Personnel Against Short-Duration Thermal Exposures from Fire) as: :"A type of short-duration fire that spreads by means of a flame front rapidly through a diffuse fuel, such as dust, gas, or the vapors of an ignitable liquid, without the production of damaging pressure." Characterization Flash fires may occur in environments where fuel, typically flammable gas or dust, is mixed with air in concentrations suitable for combustion. In a flash fire, the flame spreads at subsonic velocity, so the overpressure damage is usually negligible and the bul ...
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Laminar Flame Speed
Laminar flame speed is an intrinsic characteristic of premixed combustible mixtures.http://www.clarke-energy.com/2013/laminar-flame-speed/ Laminar Flame Speed It is the speed at which an un-stretched laminar flame will propagate through a quiescent mixture of unburned reactants. Laminar flame speed is given the symbol ''s''L. According to the thermal flame theory of Mallard and Le Chatelier, the un-stretched laminar flame speed is dependent on only three properties of a chemical mixture: the thermal diffusivity of the mixture, the reaction rate of the mixture and the temperature through the flame zone: s_\mathrm^ = \sqrt \alpha is thermal diffusivity, \dot is reaction rate, and the temperature subscript u is for unburned, b is for burned and i is for ignition temperature. Laminar flame speed is a property of the mixture (fuel structure, stoichiometry) and thermodynamic conditions upon mixture ignition (pressure, temperature). Turbulent flame speed is a function of the a ...
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Turbulence
In fluid dynamics, turbulence or turbulent flow is fluid motion characterized by chaotic changes in pressure and flow velocity. It is in contrast to a laminar flow, which occurs when a fluid flows in parallel layers, with no disruption between those layers. Turbulence is commonly observed in everyday phenomena such as surf, fast flowing rivers, billowing storm clouds, or smoke from a chimney, and most fluid flows occurring in nature or created in engineering applications are turbulent. Turbulence is caused by excessive kinetic energy in parts of a fluid flow, which overcomes the damping effect of the fluid's viscosity. For this reason turbulence is commonly realized in low viscosity fluids. In general terms, in turbulent flow, unsteady vortices appear of many sizes which interact with each other, consequently drag due to friction effects increases. This increases the energy needed to pump fluid through a pipe. The onset of turbulence can be predicted by the dimensionless Rey ...
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Heat Transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, Convection (heat transfer), thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species (mass transfer in the form of advection), either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system. Heat conduction, also called diffusion, is the direct microscopic exchanges of kinetic energy of particles (such as molecules) or quasiparticles (such as lattice waves) through the boundary between two systems. When an object is at a different temperature from another body or its surroundings, heat flows so that the body and the surroundings reach the same temperature, ...
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Activation Energy
In chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (''E''a) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state. For a chemical reaction to proceed at a reasonable rate, the temperature of the system should be high enough such that there exists an appreciable number of molecules with translational energy equal to or greater than the activation energy. The term "activation energy" was introduced in 1889 by the Swedish scientist Svante Arrhenius. Other uses Although less commonly used, activation energy also applies to nuclear reactions and various other physical phenomena. Te ...
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