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Depletion Gilding
Depletion gilding is a method for producing a layer of nearly pure gold on an object made of gold alloy by removing the other metals from its surface. It is sometimes referred to as a "surface enrichment" process. Process Most gilding methods are additive: they deposit gold that was not there before onto the surface of an object. By contrast, depletion gilding is a subtractive process whereby material is removed to increase the purity of gold that is already present on an object's surface. In depletion gilding, other metals are etched away from the surface of an object composed of a gold alloy by the use of acids or salts, often in combination with heat. Since no gold is added, only an object made of an alloy that already contains gold can be depletion gilded. Depletion gilding relies on the fact that gold is highly resistant to oxidation or corrosion by most common chemicals, whereas many other metals are not. Depletion gilding is most often used to treat alloys of gold with coppe ...
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Gold
Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile metal in a pure form. Chemically, gold is a transition metal and a group 11 element. It is one of the least reactive chemical elements and is solid under standard conditions. Gold often occurs in free elemental ( native state), as nuggets or grains, in rocks, veins, and alluvial deposits. It occurs in a solid solution series with the native element silver (as electrum), naturally alloyed with other metals like copper and palladium, and mineral inclusions such as within pyrite. Less commonly, it occurs in minerals as gold compounds, often with tellurium (gold tellurides). Gold is resistant to most acids, though it does dissolve in aqua regia (a mixture of nitric acid and hydrochloric acid), forming a soluble tetrachloroaurate anion. Gold is ...
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Sterling Silver
Sterling silver is an alloy of silver containing 92.5% by weight of silver and 7.5% by weight of other metals, usually copper. The sterling silver standard has a minimum millesimal fineness of 925. ''Fine silver'', which is 99.9% pure silver, is relatively soft, so silver is usually alloyed with copper to increase its hardness and strength. Sterling silver is prone to tarnishing, and elements other than copper can be used in alloys to reduce tarnishing, as well as casting porosity and firescale. Such elements include germanium, zinc, platinum, silicon, and boron. Recent examples of these alloys include ''argentium'', ''sterlium'' and ''silvadium''. Etymology One of the earliest attestations of the term is in Old French form , in a charter of the abbey of Les Préaux, dating to either 1085 or 1104. The English chronicler Orderic Vitalis (1075 – 1142) uses the Latin forms and . The word in origin refers to the newly introduced Norman silver penny. According to the Oxford Eng ...
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Anglo-Saxons
The Anglo-Saxons were a Cultural identity, cultural group who inhabited England in the Early Middle Ages. They traced their origins to settlers who came to Britain from mainland Europe in the 5th century. However, the ethnogenesis of the Anglo-Saxons happened within Britain, and the identity was not merely imported. Anglo-Saxon identity arose from interaction between incoming groups from several Germanic peoples, Germanic tribes, both amongst themselves, and with Celtic Britons, indigenous Britons. Many of the natives, over time, adopted Anglo-Saxon culture and language and were assimilated. The Anglo-Saxons established the concept, and the Kingdom of England, Kingdom, of England, and though the modern English language owes somewhat less than 26% of its words to their language, this includes the vast majority of words used in everyday speech. Historically, the Anglo-Saxon period denotes the period in Britain between about 450 and 1066, after Anglo-Saxon settlement of Britain, th ...
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Tumbaga
''Tumbaga'' is the name for a non-specific alloy of gold and copper given by Spanish Conquistadors to metals composed of these elements found in widespread use in pre-Columbian Mesoamerica in North America and South America. The term is believed to be a borrowing from Malay , meaning 'copper' or 'brass'. It has also been spelled ''tumbago'' in literature. Composition and properties Tumbaga is an alloy composed mostly of gold and copper. It has a significantly lower melting point than gold or copper alone. It is harder than copper, but maintains malleability after being pounded. Tumbaga can be treated with a simple acid, like citric acid, to dissolve copper off the surface. What remains is a shiny layer of nearly pure gold on top of a harder, more durable copper-gold alloy sheet. This process is referred to as depletion gilding. Use and function Tumbaga was widely used by the pre-Columbian cultures of South and Central America to make religious objects. Like most gold alloys, t ...
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Sican Culture
The Sican (also Sicán) culture is the name that archaeologist Izumi Shimada gave to the culture that inhabited what is now the north coast of Peru between about 750 and 1375. According to Shimada, ''Sican'' means "temple of the Moon". The Sican culture is also referred to as Lambayeque culture, after the name of the region in Peru. It succeeded the Moche culture. There is still controversy among archeologists and anthropologists over whether the two are separate cultures. The Sican culture is divided into three major periods based on cultural changes as evidenced in archeological artifacts."Research Settings: The Sican Culture"
, ''Sican Archaeological Project (SAP)'', 2007, Retrieved 5 October 2008.


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Electroplating
Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the reduction of cations of that metal by means of a direct electric current. The part to be coated acts as the cathode (negative electrode) of an electrolytic cell; the electrolyte is a solution of a salt of the metal to be coated; and the anode (positive electrode) is usually either a block of that metal, or of some inert conductive material. The current is provided by an external power supply. Electroplating is widely used in industry and decorative arts to improve the surface qualities of objects—such as resistance to abrasion and corrosion, lubricity, reflectivity, electrical conductivity, or appearance. It is used to build up thickness on undersized or worn-out parts, or to manufacture metal plates with complex shape, a process called electroforming. It is used to deposit copper and other conductors in forming printe ...
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Fine Silver
The fineness of a precious metal object (coin, bar, jewelry, etc.) represents the weight of ''fine metal'' therein, in proportion to the total weight which includes alloying base metals and any impurities. Alloy metals are added to increase hardness and durability of coins and jewelry, alter colors, decrease the cost per weight, or avoid the cost of high-purity refinement. For example, copper is added to the precious metal silver to make a more durable alloy for use in coins, housewares and jewelry. Coin silver, which was used for making silver coins in the past, contains 90% silver and 10% copper, by mass. Sterling silver contains 92.5% silver and 7.5% of other metals, usually copper, by mass. Various ways of expressing fineness have been used and two remain in common use: ''millesimal fineness'' expressed in units of parts per 1,000 and '' karats'' or ''carats'' used only for gold. Karats measure the parts per 24, so that 18 karat = = 75% and 24 karat gold is considered 100% g ...
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Oxalic Acid
Oxalic acid is an organic acid with the systematic name ethanedioic acid and formula . It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus ''Oxalis'', commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous. Oxalic acid has much greater acid strength than acetic acid. It is a reducing agent and its conjugate base, known as oxalate (), is a chelating agent for metal cations. Typically, oxalic acid occurs as the dihydrate with the formula . History The preparation of salts of oxalic acid (crab acid) from plants had been known, at least since 1745, when the Dutch botanist and physician Herman Boerhaave isolated a salt from wood sorrel. By 1773, François Pierre Savary of Fribourg, Switzerland had isolated oxalic acid from i ...
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Gilding
Gilding is a decorative technique for applying a very thin coating of gold over solid surfaces such as metal (most common), wood, porcelain, or stone. A gilded object is also described as "gilt". Where metal is gilded, the metal below was traditionally silver in the West, to make silver-gilt (or ''vermeil'') objects, but gilt-bronze is commonly used in China, and also called ormolu if it is Western. Methods of gilding include hand application and gluing, typically of gold leaf, chemical gilding, and electroplating, the last also called gold plating. Parcel-gilt (partial gilt) objects are only gilded over part of their surfaces. This may mean that all of the inside, and none of the outside, of a chalice or similar vessel is gilded, or that patterns or images are made up by using a combination of gilt and ungilted areas. Gilding gives an object a gold appearance at a fraction of the cost of creating a solid gold object. In addition, a solid gold piece would often be too soft or ...
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Electrum
Electrum is a naturally occurring alloy of gold and silver, with trace amounts of copper and other metals. Its color ranges from pale to bright yellow, depending on the proportions of gold and silver. It has been produced artificially, and is also known as "green gold".Emsley, John (2003Nature's building blocks: an A–Z guide to the elements Oxford University Press. . p. 168 Electrum was used as early as the third millennium BC in Old Kingdom of Egypt, sometimes as an exterior coating to the pyramidions atop ancient Egyptian pyramids and obelisks. It was also used in the making of ancient drinking vessels. The first known metal coins made were of electrum, dating back to the end of the 7th century or the beginning of the 6th century BC. For several decades, the medals awarded with the Nobel Prize have been made of gold-plated green gold. Etymology The name "electrum" is the Latinized form of the Greek word ἤλεκτρον (''ḗlektron''), mentioned in the ''Odyssey' ...
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Keum-boo
''Keum-boo'' (also ''Geumbu'', ''Kum-Boo'' or ''Kum-bu''—Korean "attached gold") is an ancient Korean gilding technique used to apply thin sheets of gold to silver, to make silver-gilt. Traditionally, this technique is accomplished by first depleting a surface of sterling silver to bring up a thin layer of fine silver. Then 24 carat gold foil is applied with heat and pressure— mechanical gilding—to produce a permanent diffusion bond. Pure precious metals such as gold and silver have a very similar atomic structure and therefore have a good potential for bonding. Heating these metals to a temperature between 260–370°C increases the movement of the atoms. When pressure is added, this causes an electron exchange at the surface between the two metals, creating a permanent diffusion bond. This diffusion bond occurs far below the soldering temperature for either metal (Dhein, 2004). Examples of this technique have probably been observed, but not positively identified on piece ...
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