|
Copper Azide
Copper(II) azide is a medium density explosive with the molecular formula . Uses Copper azide is very explosive and is too sensitive for any practical use unless handled in solution. Preparation Copper azide can be prepared by a metathesis reaction between water-soluble sources of and azide ions. (Spectator ions A spectator ion is an ion that exists as a reactant and a product in a chemical equation. A spectator ion can, therefore, be observed in the reaction of aqueous solutions of sodium carbonate and copper(II) sulfate but does not affect the equilibr ... omitted in reaction below). : It can be destroyed by concentrated nitric acid to form non-explosive products, these being nitrogen, nitrogen oxides and copper(II) nitrate. References Azides Copper(II) compounds Explosive chemicals {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lead(II) Azide
Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. Lead(II) acetate can also be used. Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product. In fact, it is normally shipped in a dextrinated solution that lowers its sensitivity. Production history Lead azide in its pure form was first prepared by Theodor Curtius in 1891. Due to sensitivity and stability concerns, the dextrinated form of lead azide (MIL-L-3055) was developed in the 1920s and 1930s with large scale production by DuPont Co beginning in 1932. Detonator development during World War II resulted in the need for a form of lead azide with a more brisant output. RD-1333 lead azide (MI ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Azide
Silver azide is the chemical compound with the formula . It is a silver(I) salt of hydrazoic acid. It forms a colorless crystals. It is a well-known explosive. Structure and chemistry Silver azide can be prepared by treating an aqueous solution of silver nitrate with sodium azide. The silver azide precipitates as a white solid, leaving sodium nitrate in solution. : X-ray crystallography shows that is a coordination polymer with square planar coordinated by four azide ligands. Correspondingly, each end of each azide ligand is connected to a pair of centers. The structure consists of two-dimensional layers stacked one on top of the other, with weaker Ag–N bonds between layers. The coordination of can alternatively be described as highly distorted 4 + 2 octahedral, the two more distant nitrogen atoms being part of the layers above and below. In its most characteristic reaction, the solid decomposes explosively, releasing nitrogen gas: : The first step in this decomposi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explosives may al ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of atoms o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids (and thus proteins), in the nucleic acids ( DNA and RNA) and in the energy transfer molecule adenosine triphosphate. The human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes the movement of the element from the air, into the biosphere and organic compounds, then back into the atmosphere. Many indus ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solution (chemistry)
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Salt Metathesis Reaction
A salt metathesis reaction, sometimes called a double displacement reaction, is a chemical process involving the exchange of bonds between two reacting chemical species which results in the creation of products with similar or identical bonding affiliations. This reaction is represented by the general scheme: :AB + CD -> AD + CB The bond between the reacting species can be either ionic or covalent. Classically, these reactions result in the precipitation of one product. In older literature, the term double decomposition is frequently encountered. The term double decomposition is more specifically used when at least one of the substances does not dissolve in the solvent, as the ligand or ion exchange takes place in the solid state of the reactant. For example: :AX(aq) + BY(s) → AY(aq) + BX(s). Types of reactions Counterion exchange Salt metathesis is a common technique for exchanging counterions. The choice of reactants is guided by a solubility chart or lattice energy. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Azide
In chemistry, azide is a linear, polyatomic anion with the formula and structure . It is the conjugate base of hydrazoic acid . Organic azides are organic compounds with the formula , containing the azide functional group. The dominant application of azides is as a propellant in air bags. Preparation Sodium azide is made industrially by the reaction of nitrous oxide, with sodium amide in liquid ammonia as solvent: : Many inorganic azides can be prepared directly or indirectly from sodium azide. For example, lead azide, used in detonators, may be prepared from the metathesis reaction between lead nitrate and sodium azide. An alternative route is direct reaction of the metal with silver azide dissolved in liquid ammonia. Some azides are produced by treating the carbonate salts with hydrazoic acid. Bonding Azide is isoelectronic with carbon dioxide , cyanate , nitrous oxide , nitronium ion and cyanogen fluoride NCF. Per valence bond theory, azide can be described ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spectator Ions
A spectator ion is an ion that exists as a reactant and a product in a chemical equation. A spectator ion can, therefore, be observed in the reaction of aqueous solutions of sodium carbonate and copper(II) sulfate but does not affect the equilibrium: :2 ( aq) + (aq) + (aq) + (aq) → 2 (aq) + (aq) + ( s) The and ions are spectator ions since they remain unchanged on both sides of the equation. They simply "watch" the other ions react, hence the name. They are present in total ionic equations to balance the charges of the ions. Whereas the and ions combine to form a precipitate of solid . In reaction stoichiometry, spectator ions are removed from a complete ionic equation to form a net ionic equation. For the above example this yields: So: 2 (aq) + (aq) + (aq) + (aq) → 2 (aq) + (aq) + (s) (where x = spectator ion) :⇒ (aq) + (aq) → (s) Spectator ion concentration only affects the Debye length. In contrast, potential determining ions, whose concentrat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
