Contact Angle
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Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of t ...
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Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the m ...
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Video Contact Angle
Video is an electronic medium for the recording, copying, playback, broadcasting, and display of moving visual media. Video was first developed for mechanical television systems, which were quickly replaced by cathode-ray tube (CRT) systems which, in turn, were replaced by flat panel displays of several types. Video systems vary in display resolution, aspect ratio, refresh rate, color capabilities and other qualities. Analog and digital variants exist and can be carried on a variety of media, including radio broadcast, magnetic tape, optical discs, computer files, and network streaming. History Analog video Video technology was first developed for mechanical television systems, which were quickly replaced by cathode-ray tube (CRT) television systems, but several new technologies for video display devices have since been invented. Video was originally exclusively a live technology. Charles Ginsburg led an Ampex research team developing one of the first practical video ...
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Elliptic Partial Differential Equation
Second-order linear partial differential equations (PDEs) are classified as either elliptic, hyperbolic, or parabolic. Any second-order linear PDE in two variables can be written in the form :Au_ + 2Bu_ + Cu_ + Du_x + Eu_y + Fu +G= 0,\, where , , , , , , and are functions of and and where u_x=\frac, u_=\frac and similarly for u_,u_y,u_. A PDE written in this form is elliptic if :B^2-AC, applying the chain rule once gives :u_=u_\xi \xi_x+u_\eta \eta_x and u_=u_\xi \xi_y+u_\eta \eta_y, a second application gives :u_=u_ _x+u_ _x+2u_\xi_x\eta_x+u_\xi_+u_\eta_, :u_=u_ _y+u_ _y+2u_\xi_y\eta_y+u_\xi_+u_\eta_, and :u_=u_ \xi_x\xi_y+u_ \eta_x\eta_y+u_(\xi_x\eta_y+\xi_y\eta_x)+u_\xi_+u_\eta_. We can replace our PDE in x and y with an equivalent equation in \xi and \eta :au_ + 2bu_ + cu_ \text= 0,\, where :a=A^2+2B\xi_x\xi_y+C^2, :b=2A\xi_x\eta_x+2B(\xi_x\eta_y+\xi_y\eta_x) +2C\xi_y\eta_y , and :c=A^2+2B\eta_x\eta_y+C^2. To transform our PDE into the desired canonical fo ...
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Mean Curvature
In mathematics, the mean curvature H of a surface S is an ''extrinsic'' measure of curvature that comes from differential geometry and that locally describes the curvature of an embedded surface in some ambient space such as Euclidean space. The concept was used by Sophie Germain in her work on elasticity theory. Jean Baptiste Marie Meusnier used it in 1776, in his studies of minimal surfaces. It is important in the analysis of minimal surfaces, which have mean curvature zero, and in the analysis of physical interfaces between fluids (such as soap films) which, for example, have constant mean curvature in static flows, by the Young-Laplace equation. Definition Let p be a point on the surface S inside the three dimensional Euclidean space . Each plane through p containing the normal line to S cuts S in a (plane) curve. Fixing a choice of unit normal gives a signed curvature to that curve. As the plane is rotated by an angle \theta (always containing the normal line) that curvatur ...
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Young–Laplace Equation
In physics, the Young–Laplace equation () is an algebraic equation that describes the capillary pressure difference sustained across the interface between two static fluids, such as water and air, due to the phenomenon of surface tension or wall tension, although use of the latter is only applicable if assuming that the wall is very thin. The Young–Laplace equation relates the pressure difference to the shape of the surface or wall and it is fundamentally important in the study of static capillary surfaces. It's a statement of normal stress balance for static fluids meeting at an interface, where the interface is treated as a surface (zero thickness): \begin \Delta p &= -\gamma \nabla \cdot \hat n \\ &= -2\gamma H_f \\ &= -\gamma \left(\frac + \frac\right) \end where \Delta p is the Laplace pressure, the pressure difference across the fluid interface (the exterior pressure minus the interior pressure), \gamma is the surface tension (or wall tension), \hat n is the unit norm ...
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Capillary Number
In fluid dynamics, the capillary number (Ca) is a dimensionless quantity representing the relative effect of viscous drag forces versus surface tension forces acting across an interface between a liquid and a gas, or between two immiscible liquids. Alongside the Bond number, commonly denoted Bo, this term is useful to describe the forces acting on a fluid front in porous or granular media, such as soil.Dynamics of viscous entrapped saturated zones in partially wetted porous media
Transport in Porous Media (2018), 125(2), 193-210
The capillary number is defined as: :\mathrm = \frac where \mu is the dynamic ...
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Annual Review Of Materials Research
The ''Annual Review of Materials Research'' is a peer-reviewed journal that publishes review articles about materials science. It has been published by the nonprofit Annual Reviews since 1971, when it was first released under the title the ''Annual Review of Materials Science''. Three people have served as editors, with the current editor David R. Clarke serving in the position since 2001. It has an impact factor of 13.972 as of 2022. History The ''Annual Review of Materials Science'' was first published in 1971 by the nonprofit publisher Annual Reviews, making it their sixteenth journal. Its first editor was Robert Huggins. In 2001, its name was changed to the current form, the ''Annual Review of Materials Research''. The name change was intended "to better reflect the broad appeal that materials research has for so many diverse groups of scientists and not simply those who identify themselves with the academic discipline of materials science." As of 2020, it was published bo ...
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Wilhelmy Plate
A Wilhelmy plate is a thin plate that is used to measure equilibrium surface or interfacial tension at an air–liquid or liquid–liquid interface. In this method, the plate is oriented perpendicular to the interface, and the force exerted on it is measured. Based on the work of Ludwig Wilhelmy, this method finds wide use in the preparation and monitoring of Langmuir films. Detailed description The Wilhelmy plate consists of a thin plate usually on the order of a few square centimeters in area. The plate is often made from filter paper, glass or platinum which may be roughened to ensure complete wetting. In fact, the results of the experiment do not depend on the material used, as long as the material is wetted by the liquid. The plate is cleaned thoroughly and attached to a balance with a thin metal wire. The force on the plate due to wetting is measured using a tensiometer or microbalance and used to calculate the surface tension (\gamma) using the Wilhelmy equation: :\ga ...
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Static Friction
Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. There are several types of friction: *Dry friction is a force that opposes the relative lateral motion of two solid surfaces in contact. Dry friction is subdivided into ''static friction'' ("stiction") between non-moving surfaces, and ''kinetic friction'' between moving surfaces. With the exception of atomic or molecular friction, dry friction generally arises from the interaction of surface features, known as asperities (see Figure 1). *Fluid friction describes the friction between layers of a viscous fluid that are moving relative to each other. *Lubricated friction is a case of fluid friction where a lubricant fluid separates two solid surfaces. *Skin friction is a component of drag, the force resisting the motion of a fluid across the surface of a body. *Internal friction is the force resisting motion between the elements making up a sol ...
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Confocal Microscopy
Confocal microscopy, most frequently confocal laser scanning microscopy (CLSM) or laser confocal scanning microscopy (LCSM), is an optical imaging technique for increasing optical resolution and contrast of a micrograph by means of using a spatial pinhole to block out-of-focus light in image formation. Capturing multiple two-dimensional images at different depths in a sample enables the reconstruction of three-dimensional structures (a process known as optical sectioning) within an object. This technique is used extensively in the scientific and industrial communities and typical applications are in life sciences, semiconductor inspection and materials science. Light travels through the sample under a conventional microscope as far into the specimen as it can penetrate, while a confocal microscope only focuses a smaller beam of light at one narrow depth level at a time. The CLSM achieves a controlled and highly limited depth of field. Basic concept The principle of co ...
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