Colloidal Probe Technique
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Colloidal Probe Technique
The colloidal probe technique is commonly used to measure interaction forces acting between colloid, colloidal particles and/or planar surfaces in air or in solution. This technique relies on the use of an atomic force microscope (AFM). However, instead of a cantilever with a sharp AFM tip, one uses the ''colloidal probe''. The colloidal probe consists of a colloidal particle of few micrometers in diameter that is attached to an AFM cantilever. The colloidal probe technique can be used in the ''sphere-plane'' or ''sphere-sphere'' geometries (''see figure''). One typically achieves a force resolution between 1 and 100 pN and a distance resolution between 0.5 and 2 nanometers, nm. The colloidal probe technique has been developed in 1991 independently by Ducker and Butt. Since its development this tool has gained wide popularity in numerous research laboratories, and numerous reviews are available in the scientific literature. Alternative techniques to measure force between surfaces i ...
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Colloidal Probe Geometries
A colloid is a mixture in which one substance consisting of microscopically dispersed Solubility, insoluble particles is suspension (chemistry), suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word ''suspension (chemistry), suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be Opacity (optics), opaque or have a slight color. Colloidal suspensions are the subject of interfa ...
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Double Layer Forces
Double layer forces occur between charged objects across liquids, typically water. This force acts over distances that are comparable to the Debye length, which is on the order of one to a few tenths of Nanometre, nanometers. The strength of these forces increases with the magnitude of the surface charge density (or the electrical surface potential). For two similarly charged objects, this force is repulsive and decays exponentially at larger distances, see figure. For unequally charged objects and eventually at shorted distances, these forces may also be attractive. The theory due to DLVO theory, Derjaguin, Landau, Verwey, and Overbeek (DLVO) combines such double layer forces together with Van der Waals forces in order to estimate the actual interaction potential between colloidal particles.W. B. Russel, D. A. Saville, W. R. Schowalter, Colloidal Dispersions. Cambridge University Press: Cambridge, 1989. An Double layer (interfacial), electrical double layer develops near charged su ...
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Thermal Fluctuations
In statistical mechanics, thermal fluctuations are random deviations of a system from its average state, that occur in a system at equilibrium.In statistical mechanics they are often simply referred to as fluctuations. All thermal fluctuations become larger and more frequent as the temperature increases, and likewise they decrease as temperature approaches absolute zero. Thermal fluctuations are a basic manifestation of the temperature of systems: A system at nonzero temperature does not stay in its equilibrium microscopic state, but instead randomly samples all possible states, with probabilities given by the Boltzmann distribution. Thermal fluctuations generally affect all the degrees of freedom of a system: There can be random vibrations (phonons), random rotations ( rotons), random electronic excitations, and so forth. Thermodynamic variables, such as pressure, temperature, or entropy, likewise undergo thermal fluctuations. For example, for a system that has an equilibriu ...
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Derjaguin Approximation
The Derjaguin approximation (or sometimes also referred to as the proximity approximation), named after the Russian scientist Boris Derjaguin, expresses the force profile acting between finite size bodies in terms of the force profile between two planar semi-infinite walls. This approximation is widely used to estimate forces between colloidal particles, as forces between two planar bodies are often much easier to calculate. The Derjaguin approximation expresses the force ''F''(''h'') between two bodies as a function of the surface separation as : F(h) = 2 \pi R_ W(h), where ''W''(''h'') is the interaction energy per unit area between the two planar walls and ''R''eff the effective radius. When the two bodies are two spheres of radii ''R''1 and ''R''2, respectively, the effective radius is given by : R_^ = R_1^+R_2^. Experimental force profiles between macroscopic bodies as measured with the surface forces apparatus (SFA) or colloidal probe technique are often reported as the r ...
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Surface Modification
Surface modification is the act of modifying the surface of a material by bringing physical, chemical or biological characteristics different from the ones originally found on the surface of a material. This modification is usually made to solid materials, but it is possible to find examples of the modification to the surface of specific liquids. The modification can be done by different methods with a view to altering a wide range of characteristics of the surface, such as: roughness,is available). hydrophilicity,is available). surface charge, surface energy, biocompatibility and reactivity. Surface engineering Surface engineering is the sub-discipline of materials science which deals with the surface of solid matter. It has applications to chemistry, mechanical engineering, and electrical engineering (particularly in relation to semiconductor manufacturing). Solids are composed of a bulk material covered by a surface. The surface which bounds the bulk material is called ...
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Micromanipulator
A micromanipulator is a device which is used to physically interact with a sample under a microscope, where a level of precision of movement is necessary that cannot be achieved by the unaided human hand. It may typically consist of an input joystick, a mechanism for reducing the range of movement and an output section with the means of holding a microtool to hold, inject, cut or otherwise manipulate the object as required. The mechanism for reducing the movement usually requires the movement to be free of backlash. This is achieved by the use of kinematic constraints to allow each part of the mechanism to move only in one or more chosen degrees of freedom, which achieves a high precision and repeatability of movement, usually at the expense of some absolute accuracy. Movement Movement reduction can be performed by mechanical levers, hydraulically using pistons of different diameters connected by tubing containing non-compressible fluid, electronically using stepper motors or lin ...
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Hysteresis
Hysteresis is the dependence of the state of a system on its history. For example, a magnet may have more than one possible magnetic moment in a given magnetic field, depending on how the field changed in the past. Plots of a single component of the moment often form a loop or hysteresis curve, where there are different values of one variable depending on the direction of change of another variable. This history dependence is the basis of memory in a hard disk drive and the remanence that retains a record of the Earth's magnetic field magnitude in the past. Hysteresis occurs in ferromagnetic and ferroelectric materials, as well as in the deformation of rubber bands and shape-memory alloys and many other natural phenomena. In natural systems it is often associated with irreversible thermodynamic change such as phase transitions and with internal friction; and dissipation is a common side effect. Hysteresis can be found in physics, chemistry, engineering, biology, and economics. I ...
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Instability
In numerous fields of study, the component of instability within a system is generally characterized by some of the outputs or internal states growing without bounds. Not all systems that are not stable are unstable; systems can also be marginally stable or exhibit limit cycle behavior. In structural engineering, a structure can become unstable when excessive load is applied. Beyond a certain threshold, structural deflections magnify stresses, which in turn increases deflections. This can take the form of buckling or crippling. The general field of study is called structural stability. Atmospheric instability is a major component of all weather systems on Earth. Instability in control systems In the theory of dynamical systems, a state variable in a system is said to be unstable if it evolves without bounds. A system itself is said to be unstable if at least one of its state variables is unstable. In continuous time control theory, a system is unstable if any of the ro ...
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Hooke's Law
In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring (device), spring by some distance () Proportionality (mathematics)#Direct_proportionality, scales linearly with respect to that distance—that is, where is a constant factor characteristic of the spring (i.e., its stiffness), and is small compared to the total possible deformation of the spring. The law is named after 17th-century British physicist Robert Hooke. He first stated the law in 1676 as a Latin anagram. He published the solution of his anagram in 1678 as: ("as the extension, so the force" or "the extension is proportional to the force"). Hooke states in the 1678 work that he was aware of the law since 1660. Hooke's equation holds (to some extent) in many other situations where an elasticity (physics), elastic body is Deformation (physics), deformed, such as wind blowing on a tall building, and a musician plucking a string (music), string of a guitar ...
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Colloidal Probe Response Forces
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word ''suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Italian ...
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Photodiode
A photodiode is a light-sensitive semiconductor diode. It produces current when it absorbs photons. The package of a photodiode allows light (or infrared or ultraviolet radiation, or X-rays) to reach the sensitive part of the device. The package may include lenses or optical filters. Devices designed for use specially as a photodiode use a PIN junction rather than a p–n junction, to increase the speed of response. Photodiodes usually have a slower response time as their surface area increases. A photodiode is designed to operate in reverse bias. A solar cell used to generate electric solar power is a large area photodiode. Photodiodes are used in scientific and industrial instruments to measure light intensity, either for its own sake or as a measure of some other property (density of smoke, for example). A photodiode can be used as the receiver of data encoded on an infrared beam, as in household remote controls. Photodiodes can be used to form an optocoupler, allowing tra ...
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Piezoelectricity
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The word ''piezoelectricity'' means electricity resulting from pressure and latent heat. It is derived from the Greek word ; ''piezein'', which means to squeeze or press, and ''ēlektron'', which means amber, an ancient source of electric charge. The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no inversion symmetry. The piezoelectric effect is a reversible process: materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an applied electrical field. For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their ...
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