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Caesium Cyanide
Caesium cyanide (chemical formula: CsCN) is the caesium salt of hydrogen cyanide. It is a white solid, easily soluble in water, with a smell reminiscent of bitter almonds, and with crystals similar in appearance to sugar. Caesium cyanide has chemical properties similar to potassium cyanide and is very toxic. Production Hydrogen cyanide reacts with caesium hydroxide giving caesium cyanide and water: :HCN + CsOH → CsCN + H2O. References [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lithium Cyanide
Lithium cyanide is an inorganic compound with the chemical formula LiCN. It is a toxic, white colored, hygroscopic, water-soluble salt that finds only niche uses. Preparation LiCN arises from the interaction of lithium hydroxide and hydrogen cyanide. A laboratory-scale preparation uses acetone cyanohydrin as a surrogate for HCN: :(CH3)2C(OH)CN + LiH → (CH3)2CO + LiCN + H2 Uses The compound decomposes to cyanamide and carbon when heated to a temperature close to but below 600 °C. Acids react to give hydrogen cyanide. Lithium cyanide can be used as a reagent for organic compound cyanation In organic synthesis, cyanation is the attachment or substitution of a cyanide group on various substrates. Such transformations are high-value because they generate C-C bond. Furthermore nitriles are versatile functional groups. Cyanation to fo .... :RX + LiCN → RCN + LiX References {{Cyanides Lithium salts Cyanides ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Cyanide
Sodium cyanide is a poisonous compound with the formula Na C N. It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt. Its main application, in gold mining, also exploits its high reactivity toward metals. It is a moderately strong base. Production and chemical properties Sodium cyanide is produced by treating hydrogen cyanide with sodium hydroxide: :HCN + NaOH → NaCN + H2O Worldwide production was estimated at 500,000 tons in the year 2006. Formerly it was prepared by the Castner process involving the reaction of sodium amide with carbon at elevated temperatures. : NaNH2 + C → NaCN + H2 The structure of solid NaCN is related to that of sodium chloride. The anions and cations are each six-coordinate. Potassium cyanide (KCN) adopts a similar structure. When treated with acid, it forms the toxic gas hydrogen cyanide: : NaCN + H+ → HCN + Na+ Because the salt is derived from a weak acid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Cyanide
Potassium cyanide is a compound with the formula KCN. This colorless crystalline salt, similar in appearance to sugar, is highly soluble in water. Most KCN is used in gold mining, organic synthesis, and electroplating. Smaller applications include jewellery for chemical gilding and buffing.Andreas Rubo, Raf Kellens, Jay Reddy, Joshua Wooten, Wolfgang Hasenpusch "Alkali Metal Cyanides" in Ullmann's Encyclopedia of Industrial Chemistry 2006 Wiley-VCH, Weinheim, Germany. Potassium cyanide is highly toxic. The moist solid emits small amounts of hydrogen cyanide due to hydrolysis, which may smell like bitter almonds. Not everyone, however, can smell cyanide; the ability to do so is a genetic trait. The taste of potassium cyanide has been described as acrid and bitter, with a burning sensation similar to lye. Production KCN is produced by treating hydrogen cyanide with an aqueous solution of potassium hydroxide, followed by evaporation of the solution in a vacuum: About 50,000 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rubidium Cyanide
Rubidium cyanide (chemical formula: RbCN) is the rubidium salt of hydrogen cyanide. It is a white solid, easily soluble in water, with a smell reminiscent of bitter almonds, and somewhat similar in appearance to sugar. Rubidium cyanide has chemical properties similar to potassium cyanide, and is similarly very toxic. Production Rubidium cyanide can be synthesized by the reaction of hydrogen cyanide and rubidium hydroxide Rubidium hydroxide is the inorganic compound with the formula RbOH. It consists of rubidium cations and an equal number of hydroxide anions. It is a colorless solid that is commercially available as aqueous solutions from a few suppliers. Like ot ... in alcohol or ether:Rubidium cyanide (in Chinese). ChemYQ. :HCN + RbOH → RbCN + H2O. References [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Cyanide
Ammonium cyanide is an unstable inorganic compound with the formula NH4CN. Uses Ammonium cyanide is generally used in organic synthesis. Being unstable, it is not shipped or sold commercially. Preparation Ammonium cyanide is prepared in solution by bubbling hydrogen cyanide into aqueous ammonia at a low temperature : HCN + NH3 (aq) → NH4CN (aq) It may be prepared by the reaction of calcium cyanide and ammonium carbonate: : Ca(CN)2 + (NH4)2CO3 → 2 NH4CN + CaCO3 In dry state, ammonium cyanide is made by heating a mixture of potassium cyanide or potassium ferrocyanide with ammonium chloride and condensing the vapours into ammonium cyanide crystals: : KCN + NH4Cl → NH4CN + KCl Reactions Ammonium cyanide decomposes to ammonia and hydrogen cyanide, often forming a black polymer of hydrogen cyanide: : NH4CN → NH3 + HCN It undergoes salt metathesis reaction in solution with a number of metal salts to form metal–cyanide complexes. Reaction with ketones and aldehydes yield ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers indicating the numerical ''proportions'' of ato ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Caesium
Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale. It has only one stable isotope, caesium-133. Caesium is mined mostly from pollucite. The element has 40 known isotopes, making it, along with barium and mercury, one of the elements with the most isotopes. Caesium-137, a fission product, is extracted from waste produced by nuclear reactors. The German chemist Robert Bunsen and physicist Gustav Kirchhoff discovered caesium in 1860 by the newly developed method of flame spectroscopy. The first small-scale applications for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Large-scale applications are for the production of potassium cyanide and adiponitrile, used in mining and plastics, respectively. It is more toxic than solid cyanide compounds due to its volatile nature. Structure and general properties Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen. The tautomer of HCN is HNC, hydrogen isocyanide. Hydrogen cyanide is weakly acidic with a p''K''a of 9.2. It partially ionizes in water solution to give the cyanide anion, CN−. A solution of hydrogen cyanide in water, represented as HCN, is called ''hydrocyanic acid''. The salts of the cyanid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Almonds
The almond (''Prunus amygdalus'', syn. ''Prunus dulcis'') is a species of tree native to Iran and surrounding countries, including the Levant. The almond is also the name of the edible and widely cultivated seed of this tree. Within the genus ''Prunus'', it is classified with the peach in the subgenus ''Amygdalus'', distinguished from the other subgenera by corrugations on the shell ( endocarp) surrounding the seed. The fruit of the almond is a drupe, consisting of an outer hull and a hard shell with the seed, which is not a true nut. ''Shelling'' almonds refers to removing the shell to reveal the seed. Almonds are sold shelled or unshelled. Blanched almonds are shelled almonds that have been treated with hot water to soften the seedcoat, which is then removed to reveal the white embryo. Once almonds are cleaned and processed, they can be stored over time. Almonds are used in many food cuisines, often featuring prominently in desserts, such as marzipan. The almond tree pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Cyanide
Potassium cyanide is a compound with the formula KCN. This colorless crystalline salt, similar in appearance to sugar, is highly soluble in water. Most KCN is used in gold mining, organic synthesis, and electroplating. Smaller applications include jewellery for chemical gilding and buffing.Andreas Rubo, Raf Kellens, Jay Reddy, Joshua Wooten, Wolfgang Hasenpusch "Alkali Metal Cyanides" in Ullmann's Encyclopedia of Industrial Chemistry 2006 Wiley-VCH, Weinheim, Germany. Potassium cyanide is highly toxic. The moist solid emits small amounts of hydrogen cyanide due to hydrolysis, which may smell like bitter almonds. Not everyone, however, can smell cyanide; the ability to do so is a genetic trait. The taste of potassium cyanide has been described as acrid and bitter, with a burning sensation similar to lye. Production KCN is produced by treating hydrogen cyanide with an aqueous solution of potassium hydroxide, followed by evaporation of the solution in a vacuum: About 50,000 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Cyanide
Hydrogen cyanide, sometimes called prussic acid, is a chemical compound with the formula HCN and structure . It is a colorless, extremely poisonous, and flammable liquid that boils slightly above room temperature, at . HCN is produced on an industrial scale and is a highly valued precursor to many chemical compounds ranging from polymers to pharmaceuticals. Large-scale applications are for the production of potassium cyanide and adiponitrile, used in mining and plastics, respectively. It is more toxic than solid cyanide compounds due to its volatile nature. Structure and general properties Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen. The tautomer of HCN is HNC, hydrogen isocyanide. Hydrogen cyanide is weakly acidic with a p''K''a of 9.2. It partially ionizes in water solution to give the cyanide anion, CN−. A solution of hydrogen cyanide in water, represented as HCN, is called ''hydrocyanic acid''. The salts of the cyanid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Caesium Hydroxide
Caesium hydroxide is a strong base (pKa= 15.76) containing the highly reactive alkali metal caesium, much like the other alkali metal hydroxides such as sodium hydroxide and potassium hydroxide. Caesium hydroxide is corrosive enough to quickly dissolve through glass. Due to its high reactivity, caesium hydroxide is extremely hygroscopic. Laboratory caesium hydroxide is typically a hydrate. It is an anisotropic etchant of silicon, exposing octahedral planes. This technique can form pyramids and regularly shaped etch pits for uses such as Microelectromechanical systems. It is known to have a higher selectivity to etch highly p-doped silicon than the more commonly used potassium hydroxide. This compound is not commonly used in experiments due to the high extraction cost of caesium and its reactive behaviour. It acts in similar fashion to the compounds rubidium hydroxide and potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is common ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
