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Creation Operators
Creation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually denoted \hat) lowers the number of particles in a given state by one. A creation operator (usually denoted \hat^\dagger) increases the number of particles in a given state by one, and it is the adjoint of the annihilation operator. In many subfields of physics and chemistry, the use of these operators instead of wavefunctions is known as second quantization. They were introduced by Paul Dirac. Creation and annihilation operators can act on states of various types of particles. For example, in quantum chemistry and many-body theory the creation and annihilation operators often act on electron states. They can also refer specifically to the ladder operators for the quantum harmonic oscillator. In the latter case, the raising operator is in ...
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Operator (mathematics)
In mathematics, an operator is generally a mapping or function that acts on elements of a space to produce elements of another space (possibly and sometimes required to be the same space). There is no general definition of an ''operator'', but the term is often used in place of ''function'' when the domain is a set of functions or other structured objects. Also, the domain of an operator is often difficult to be explicitly characterized (for example in the case of an integral operator), and may be extended to related objects (an operator that acts on functions may act also on differential equations whose solutions are functions that satisfy the equation). See Operator (physics) for other examples. The most basic operators are linear maps, which act on vector spaces. Linear operators refer to linear maps whose domain and range are the same space, for example \R^n to \R^n. Such operators often preserve properties, such as continuity. For example, differentiation and indef ...
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Fermions
In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and leptons and all composite particles made of an odd number of these, such as all baryons and many atoms and nuclei. Fermions differ from bosons, which obey Bose–Einstein statistics. Some fermions are elementary particles (such as electrons), and some are composite particles (such as protons). For example, according to the spin-statistics theorem in relativistic quantum field theory, particles with integer spin are bosons. In contrast, particles with half-integer spin are fermions. In addition to the spin characteristic, fermions have another specific property: they possess conserved baryon or lepton quantum numbers. Therefore, what is usually referred to as the spin-statistics relation is, in fact, a spin statistics-quantum number ...
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Gaussian Integral
The Gaussian integral, also known as the Euler–Poisson integral, is the integral of the Gaussian function f(x) = e^ over the entire real line. Named after the German mathematician Carl Friedrich Gauss, the integral is \int_^\infty e^\,dx = \sqrt. Abraham de Moivre originally discovered this type of integral in 1733, while Gauss published the precise integral in 1809. The integral has a wide range of applications. For example, with a slight change of variables it is used to compute the normalizing constant of the normal distribution. The same integral with finite limits is closely related to both the error function and the cumulative distribution function of the normal distribution. In physics this type of integral appears frequently, for example, in quantum mechanics, to find the probability density of the ground state of the harmonic oscillator. This integral is also used in the path integral formulation, to find the propagator of the harmonic oscillator, and in statistical ...
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Propagator
In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. In Feynman diagrams, which serve to calculate the rate of collisions in quantum field theory, virtual particles contribute their propagator to the rate of the scattering event described by the respective diagram. These may also be viewed as the inverse of the wave operator appropriate to the particle, and are, therefore, often called ''(causal) Green's functions'' (called "''causal''" to distinguish it from the elliptic Laplacian Green's function). Non-relativistic propagators In non-relativistic quantum mechanics, the propagator gives the probability amplitude for a particle to travel from one spatial point (x') at one time (t') to another spatial point (x) at a later time (t). Consider a system with Hamiltonian . The Green's function (fu ...
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Commutative Property
In mathematics, a binary operation is commutative if changing the order of the operands does not change the result. It is a fundamental property of many binary operations, and many mathematical proofs depend on it. Most familiar as the name of the property that says something like or , the property can also be used in more advanced settings. The name is needed because there are operations, such as division and subtraction, that do not have it (for example, ); such operations are ''not'' commutative, and so are referred to as ''noncommutative operations''. The idea that simple operations, such as the multiplication and addition of numbers, are commutative was for many years implicitly assumed. Thus, this property was not named until the 19th century, when mathematics started to become formalized. A similar property exists for binary relations; a binary relation is said to be symmetric if the relation applies regardless of the order of its operands; for example, equality is symme ...
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Normal Operators
In mathematics, especially functional analysis, a normal operator on a complex Hilbert space ''H'' is a continuous linear operator ''N'' : ''H'' → ''H'' that commutes with its hermitian adjoint ''N*'', that is: ''NN*'' = ''N*N''. Normal operators are important because the spectral theorem holds for them. The class of normal operators is well understood. Examples of normal operators are * unitary operators: ''N*'' = ''N−1'' * Hermitian operators (i.e., self-adjoint operators): ''N*'' = ''N'' * Skew-Hermitian operators: ''N*'' = −''N'' * positive operators: ''N'' = ''MM*'' for some ''M'' (so ''N'' is self-adjoint). A normal matrix is the matrix expression of a normal operator on the Hilbert space C''n''. Properties Normal operators are characterized by the spectral theorem. A compact normal operator (in particular, a normal operator on a finite-dimensional linear space) is unitarily diagonalizable. Let T be a bounded operator. The following are equivalent. * T is normal. ...
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Momentum Operator
In quantum mechanics, the momentum operator is the operator (physics), operator associated with the momentum (physics), linear momentum. The momentum operator is, in the position representation, an example of a differential operator. For the case of one particle in one spatial dimension, the definition is: \hat = - i \hbar \frac where is Planck's reduced constant, the imaginary unit, is the spatial coordinate, and a partial derivative (denoted by \partial/\partial x) is used instead of a total derivative () since the wave function is also a function of time. The "hat" indicates an operator. The "application" of the operator on a differentiable wave function is as follows: \hat\psi = - i \hbar \frac In a basis of Hilbert space consisting of momentum eigenstates expressed in the momentum representation, the action of the operator is simply multiplication by , i.e. it is a multiplication operator, just as the position operator is a multiplication operator in the position represen ...
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Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program, the economic policies advocated by Alexander Hamilton, the first United States Secretary of the Treasury See also * Alexander Hamilton (1755 or 1757–1804), American statesman and one of the Founding Fathers of the US * Hamilton (other) Hamilton may refer to: People * Hamilton (name), a common ...
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Nondimensionalization
Nondimensionalization is the partial or full removal of physical dimensions from an equation involving physical quantities by a suitable substitution of variables. This technique can simplify and parameterize problems where measured units are involved. It is closely related to dimensional analysis. In some physical systems, the term scaling is used interchangeably with ''nondimensionalization'', in order to suggest that certain quantities are better measured relative to some appropriate unit. These units refer to quantities intrinsic to the system, rather than units such as SI units. Nondimensionalization is not the same as converting extensive quantities in an equation to intensive quantities, since the latter procedure results in variables that still carry units. Nondimensionalization can also recover characteristic properties of a system. For example, if a system has an intrinsic resonance frequency, length, or time constant, nondimensionalization can recover these val ...
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Schrödinger Equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of the subject. The equation is named after Erwin Schrödinger, who postulated the equation in 1925, and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics. Given a set of known initial conditions, Newton's second law makes a mathematical prediction as to what path a given physical system will take over time. The Schrödinger equation gives the evolution over time of a wave function, the quantum-mechanical characterization of an isolated physical system. The equation can be derived from the fact that the time-evolution operator must be unitary, and must therefore be generated by t ...
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Identical Particles
In quantum mechanics, identical particles (also called indistinguishable or indiscernible particles) are particles that cannot be distinguished from one another, even in principle. Species of identical particles include, but are not limited to, elementary particles (such as electrons), composite subatomic particles (such as atomic nuclei), as well as atoms and molecules. Quasiparticles also behave in this way. Although all known indistinguishable particles only exist at the quantum scale, there is no exhaustive list of all possible sorts of particles nor a clear-cut limit of applicability, as explored in quantum statistics. There are two main categories of identical particles: bosons, which can share quantum states, and fermions, which cannot (as described by the Pauli exclusion principle). Examples of bosons are photons, gluons, phonons, helium-4 nuclei and all mesons. Examples of fermions are electrons, neutrinos, quarks, protons, neutrons, and helium-3 nuclei. The fact that ...
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Fermion
In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and leptons and all composite particles made of an odd number of these, such as all baryons and many atoms and nuclei. Fermions differ from bosons, which obey Bose–Einstein statistics. Some fermions are elementary particles (such as electrons), and some are composite particles (such as protons). For example, according to the spin-statistics theorem in relativistic quantum field theory, particles with integer spin are bosons. In contrast, particles with half-integer spin are fermions. In addition to the spin characteristic, fermions have another specific property: they possess conserved baryon or lepton quantum numbers. Therefore, what is usually referred to as the spin-statistics relation is, in fact, a spin statistics-quantum numb ...
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