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Cerium Trifluoride
Cerium(III) fluoride (or cerium trifluoride), CeF3, is an ionic compound of the rare earth metal cerium and fluorine. It appears as a mineral in the form of fluocerite-(Ce) - a very rare mineral species related mainly to pegmatites and rarely to oxidation zones of some polymetallic ore deposits. CeF3 may be used as a Faraday rotator material in the visible, near-infrared and mid-infrared spectral range. Structure The crystal structure of cerium(III) fluoride is described as the or tysonite structure. It contains 9-coordinate cerium ions that adopt an approximately tricapped trigonal prismatic coordination geometry, although it can be considered 11-coordinate if two more distant fluorides are considered part of the cerium coordination environment. The three crystallographically independent fluoride ions are 3-coordinate and range in geometry from trigonal planar to pyramidal A pyramid (from el, πυραμίς ') is a structure whose outer surfaces are triangular an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lanthanum Trifluoride
Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The LaF3 structure Bonding is ionic with lanthanum highly coordinated. The cation sits at the center of a trigonal prism. Nine fluorine atoms are close: three at the bottom corners of the trigonal prism, three in the faces of the trigonal prism, and three at top corners of the trigonal prism. There are also two fluorides a little further away above and below the prism. The cation can be considered 9-coordinate or 11-coordinate. At 300 K, the structure allows the formation of Schottky defects with an activation energy of 0.07 eV, and free flow of fluoride ions with an activation energy of 0.45 eV, making the crystal unusually electrically conductive. The larger sized rare earth elements (lanthanides), which are those with smaller atomic number, also form trifluorides with the LaF3 structure. Some actinides do as well. Applications This white salt is sometimes used as the "high-ind ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coordination Geometry
The term coordination geometry is used in a number of related fields of chemistry and solid state chemistry/physics. Molecules The coordination geometry of an atom is the geometrical pattern formed by atoms around the central atom. Inorganic coordination complexes In the field of inorganic coordination complexes it is the geometrical pattern formed by the atoms in the ligands that are bonded to the central atom in a molecule or a coordination complex. The geometrical arrangement will vary according to the number and type of ligands bonded to the metal centre, and to the coordination preference of the central atom, typically a metal in a coordination complex. The number of atoms bonded, (i.e. the number of σ-bonds between central atom and ligands) is termed the coordination number. The geometrical pattern can be described as a polyhedron where the vertices of the polyhedron are the centres of the coordinating atoms in the ligands. The coordination preference of a metal often va ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III) Compounds
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the E ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III)-fluoride-xtal-F3-coord-3D-bs-17
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the Ear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III)-fluoride-xtal-F2-coord-3D-bs-17
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the Ear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III)-fluoride-xtal-F1-coord-3D-bs-17
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the Ear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium(III)-fluoride-xtal-Ce-coord-3D-bs-17
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the Ear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acta Crystallographica
''Acta Crystallographica'' is a series of peer-reviewed scientific journals, with articles centred on crystallography, published by the International Union of Crystallography (IUCr). Originally established in 1948 as a single journal called ''Acta Crystallographica'', there are now six independent ''Acta Crystallographica'' titles: *'' Acta Crystallographica Section A: Foundations and Advances'' *'' Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials'' *'' Acta Crystallographica Section C: Structural Chemistry'' *'' Acta Crystallographica Section D: Structural Biology'' *'' Acta Crystallographica Section E: Crystallographic Communications'' *'' Acta Crystallographica Section F: Structural Biology Communications'' ''Acta Crystallographica'' has been noted for the high quality of the papers that it produces, as well as the large impact that its papers have had on the field of crystallography. The current six journals form part of the journal portf ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trigonal Pyramidal Molecular Geometry
In chemistry, a trigonal pyramid is a molecular geometry with one atom at the apex and three atoms at the corners of a trigonal base, resembling a tetrahedron (not to be confused with the tetrahedral geometry). When all three atoms at the corners are identical, the molecule belongs to point group ''C3v''. Some molecules and ions with trigonal pyramidal geometry are the pnictogen hydrides (XH3), xenon trioxide (XeO3), the chlorate ion, , and the sulfite ion, . In organic chemistry, molecules which have a trigonal pyramidal geometry are sometimes described as sp3 hybridized. The AXE method for VSEPR theory states that the classification is AX3E1. Trigonal pyramidal geometry in ammonia The nitrogen in ammonia has 5 valence electrons and bonds with three hydrogen atoms to complete the octet. This would result in the geometry of a regular tetrahedron with each bond angle equal to cos−1(−) ≈ 109.5°. However, the three hydrogen atoms are repelled by the electron l ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trigonal Planar Molecular Geometry
In chemistry, trigonal planar is a molecular geometry model with one atom at the center and three atoms at the corners of an equilateral triangle, called peripheral atoms, all in one plane. In an ideal trigonal planar species, all three ligands are identical and all bond angles are 120°. Such species belong to the point group D3h. Molecules where the three ligands are not identical, such as H2CO, deviate from this idealized geometry. Examples of molecules with trigonal planar geometry include boron trifluoride (BF3), formaldehyde (H2CO), phosgene (COCl2), and sulfur trioxide (SO3). Some ions with trigonal planar geometry include nitrate (), carbonate (), and guanidinium (). In organic chemistry, planar, three-connected carbon centers that are trigonal planar are often described as having sp2 hybridization. Nitrogen inversion is the distortion of pyramidal amines through a transition state that is trigonal planar. Pyramidalization is a distortion of this molecular shape t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tricapped Trigonal Prismatic Molecular Geometry
In chemistry, the tricapped trigonal prismatic molecular geometry describes the shape of compounds where nine atoms, groups of atoms, or ligands are arranged around a central atom, defining the vertices of a triaugmented triangular prism (a trigonal prism In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The oc ... with an extra atom attached to each of its three rectangular faces). It is very similar to the capped square antiprismatic molecular geometry, and there is some dispute over the specific geometry exhibited by certain molecules. Examples * is usually considered to have a tricapped trigonal prismatic geometry, although its geometry is sometimes described as capped square antiprismatic instead. * (Ln = La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy) * {{MolecularGeometry Ste ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cerium
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 oxidation state characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure. Despite always occurring in combination with the other rare-earth elements in minerals such as those of the monazite and bastnäsite groups, cerium is easy to extract from its ores, as it can be distinguished among the lanthanides by its unique ability to be oxidized to the +4 state in aqueous solution. It is the most common of the lanthanides, followed by neodymium, lanthanum, and praseodymium. It is the 25th-most abundant element, making up 66 ppm of the Ear ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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