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Carbon Mineralization
Enhanced weathering is a process that aims to accelerate the natural weathering by spreading finely ground silicate rock, such as basalt, onto surfaces which speeds up chemical reactions between rocks, water, and air. It also removes carbon dioxide () from the atmosphere, permanently storing it in solid carbonate minerals or ocean alkalinity. The latter also slows ocean acidification. Although existing mine tailings or alkaline industrial silicate minerals (such as steel slags, construction & demolition waste, or ash from biomass incineration) may be used at first, mining more basalt might eventually be required to limit climate change. History Enhanced weathering has been proposed for both terrestrial and ocean-based carbon sequestration. Ocean methods are being tested by the non-profit organization Project Vesta to see if they are environmentally and economically viable. In July 2020, a group of scientists assessed that the geo-engineering technique of enhanced rock weathe ...
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Weathering
Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity. Weathering processes are divided into ''physical'' and ''chemical weathering''. Physical weathering involves the breakdown of rocks and soils through the mechanical effects of heat, water, ice, or other agents. Chemical weathering involves the chemical reaction of water, atmospheric gases, and biologically produced chemicals with rocks and soils. Water is the principal agent behind both physical and chemical weathering, though atmospheric oxygen and carbon dioxide and the activities of biological organisms are also important. Chemical weathering by biological action is also known as biological wea ...
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Solution (chemistry)
In chemistry, a solution is a special type of homogeneous mixture composed of two or more substances. In such a mixture, a solute is a substance dissolved in another substance, known as a solvent. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. These surrounded solute particles then move away from the solid solute and out into the solution. The mixing process of a solution happens at a scale where the effects of chemical polarity are involved, resulting in interactions that are specific to solvation. The solution usually has the state of the solvent when the solvent is the larger fraction of the mixture, as is commonly the case. One important parameter of a solution is the concentration, which is a measure of the amount of solute in a given amount of solution or solvent. The term "aqueous solution" is used when ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ...
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Aqueous Solution
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word ''aqueous'' (which comes from ''aqua'') means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. A ''non-aqueous solution'' is a solution in which the solvent is a liquid, but is not water. (See also Solvent and Inorganic nonaqueous solvent.) Characteristics Substances that are ''hydrophobic'' ('water-fearing') do not dissolve well in water, whereas those that are ''hydrophilic'' ('water-friendly') do. An example of a hydrophilic substance is sodium chlo ...
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Solid
Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice (crystal, crystalline solids, which include metals and ordinary ice), or irregularly (an amorphous solid such as common window glass). Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed. The branch of physics that deals with solids is called solid-state physics, and is the main branch of condens ...
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Forsterite
Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group ''Pbnm'') with cell parameters ''a'' 4.75 Å (0.475 nm), ''b'' 10.20 Å (1.020 nm) and ''c'' 5.98 Å (0.598 nm). Forsterite is associated with igneous and metamorphic rocks and has also been found in meteorites. In 2005 it was also found in cometary dust returned by the Stardust probe. In 2011 it was observed as tiny crystals in the dusty clouds of gas around a forming star. Two polymorphs of forsterite are known: wadsleyite (also orthorhombic) and ringwoodite ( isometric, Cubic crystal system). Both are mainly known from meteorites. Peridot is the gemstone variety of forsterite olivine. Composition Pure forsterite is composed of magnesium, oxygen and silicon. The chemical formula is Mg2SiO4. ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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Water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water co ...
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Silicate Mineral
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphism (materials science), polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this carbonate–silicate cycle, geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous e ...
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Carbonate Mineral
Carbonate minerals are those minerals containing the carbonate ion, . Carbonate divisions Anhydrous carbonates *Calcite group: trigonal **Calcite CaCO3 **Gaspéite (Ni,Mg,Fe2+)CO3 **Magnesite MgCO3 **Otavite CdCO3 **Rhodochrosite MnCO3 **Siderite FeCO3 **Smithsonite ZnCO3 **Spherocobaltite CoCO3 *Aragonite group: orthorhombic **Aragonite CaCO3 **Cerussite PbCO3 **Strontianite SrCO3 **Witherite BaCO3 **Rutherfordine UO2CO3 **Natrite Na2CO3 Anhydrous carbonates with compound formulas *Dolomite group: trigonal **Ankerite CaFe(CO3)2 **Dolomite (mineral), Dolomite CaMg(CO3)2 **Huntite Mg3Ca(CO3)4 **Minrecordite CaZn(CO3)2 **Barytocalcite BaCa(CO3)2 Carbonates with hydroxyl or halogen *Carbonate with hydroxide: monoclinic **Azurite Cu3(CO3)2(OH)2 **Hydrocerussite Pb3(CO3)2(OH)2 **Malachite Cu2CO3(OH)2 **Rosasite (Cu,Zn)2CO3(OH)2 **Phosgenite Pb2(CO3)Cl2 **Hydrozincite Zn5(CO3)2(OH)6 **Aurichalcite (Zn,Cu)5(CO3)2(OH)6 Hydrated carbonates *Hydromagnesite Mg5(CO3)4(OH)2.4H2O *Ikaite ...
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Carbonation
Carbonation is the chemical reaction of carbon dioxide to give carbonates, bicarbonates, and carbonic acid. In chemistry, the term is sometimes used in place of carboxylation, which refers to the formation of carboxylic acids. In inorganic chemistry and geology, carbonation is common. Metal hydroxides (MOH) and metal oxides (M'O) react with CO2 to give bicarbonates and carbonates: :MOH + CO2 → M(HCO3) :M'O + CO2 → M'CO3 In reinforced concrete, the chemical reaction between carbon dioxide in the air and calcium hydroxide and hydrated calcium silicate in the concrete is known as neutralisation. The similar reaction in which calcium hydroxide from cement reacts with carbon dioxide and forms insoluble calcium carbonate is carbonatation. Henry's law Henry's law states that P=KBx where P is the partial pressure of gas above the solution. KB is Henry's law constant. KB increases as temperature increases. x is the mole fraction In chemistry, the mole fraction or mol ...
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