Butyne
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Butyne
Butyne is an alkyne that contains 4 carbon and 6 hydrogen. It contains one triple bond and has two isomeric organic chemical compounds: *1-Butyne (ethylacetylene) *2-Butyne (dimethylacetylene) See also * Butane (C4H10) * Butene Butene, also known as butylene, is an alkene with the formula . The word ''butene'' may refer to any of the individual compounds. They are colourless gases that are present in crude oil as a minor constituent in quantities that are too small for ... (C4H8) {{Chemistry index ...
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Alkyne
\ce \ce Acetylene \ce \ce \ce Propyne \ce \ce \ce \ce 1-Butyne In organic chemistry, an alkyne is an unsaturated hydrocarbon containing at least one carbon—carbon triple bond. The simplest acyclic alkynes with only one triple bond and no other functional groups form a homologous series with the general chemical formula . Alkynes are traditionally known as acetylenes, although the name ''acetylene'' also refers specifically to , known formally as ethyne using IUPAC nomenclature. Like other hydrocarbons, alkynes are generally hydrophobic. Structure and bonding In acetylene, the H–C≡C bond angles are 180°. By virtue of this bond angle, alkynes are rod-like. Correspondingly, cyclic alkynes are rare. Benzyne cannot be isolated. The C≡C bond distance of 121 picometers is much shorter than the C=C distance in alkenes (134 pm) or the C–C bond in alkanes (153 pm). : The triple bond is very strong with a bond strength of 839 kJ/mol. The sigma bond contri ...
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1-Butyne
1-Butyne is an organic compound with the chemical formula HC2CH2CH3. It is a colorless combustable gas. 1-Butyne participates in reactions typical for terminal alkynes, such as alkyne metathesis, hydrogenation, condensation with formaldehyde. Based on its heat of combustion, it is slightly less stable than its isomer 2-butyne. See also * 2-Butyne * Butadiene * Cyclobutene Cyclobutene is a cycloalkene. It is of interest in research but currently has no practical applications. It is a colorless easily condensed gas. A modern synthesis involves the 2-step dehydration of cyclobutanol. The compound was first prepared ... References External links NIST Chemistry WebBook page for 1-butyne Alkynes {{hydrocarbon-stub ...
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2-Butyne
2-Butyne (dimethylacetylene, crotonylene or but-2-yne) is an alkyne with chemical formula CH3C≡CCH3. Produced artificially, it is a colorless, volatile, pungent liquid at standard temperature and pressure. 2-Butyne is of interest to physical chemists because of its very low torsional barrier and the problem of determining that barrier using high-resolution infrared spectroscopy. Analysis of its spectrum leads to a determination that the torsional barrier is only 6 cm−1 (1.2 J or 72 J mol−1). However, it has not been determined whether the equilibrium structure is eclipsed (D3h) or staggered (D3d). Symmetry analysis using the Molecular Symmetry Group G36 shows that one would need to analyse its high resolution rotation-vibration Raman spectrum to determine its equilibrium structure. 2-Butyne (''dimethylethyne'') forms with 5-decyne (''dibutylethyne''), 4-octyne (''dipropylethyne'') and 3-hexyne (''diethylethyne'') a group of symmetric alkynes. Synthesis 2-Butyne can b ...
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Butane
Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name butane comes from the root but- (from butyric acid, named after the Greek word for butter) and the suffix -ane. It was discovered by the chemist Dr. Walter Snelling in 1912. It was found dissolved in crude petroleum in 1864 by Edmund Ronalds, who was the first to describe its properties. Butane is one of a group of liquefied petroleum gases (LP gases). The others include propane, propylene, butadiene, butylene, isobutylene, and mixtures thereof. Butane burns more cleanly than gasoline and coal. Density The density of butane is highly dependent on temperature and pressure in the reservoir. For example, the density of liquid phase is 571.8±1 kg/m3 (for pressures up to 2MPa and temperature 27±0.2 °C), while the density of l ...
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