Buserite
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Buserite
Buserite is a hydrated layered Mn-oxide mineral with nominal chemical formula MnO2.''n''H2O. It was named after Swiss chemist professor W. Buser, who first identified it in 1952 in deep-sea manganese nodules. Buser named it 10 Å manganate because the periodicity in the layer stacking direction was 10 Å. It was renamed buserite in 1970 by the nomenclature commission of the International Mineralogical Association (IMA). More recent crystallographic studies have shown that buserite is not a distinct mineral species, but a two-water layer form of the one-water layer phyllomanganate birnessite, which has a characteristic periodicity of 7 Å perpendicularly to the MnO2 layers. When taken out of water, buserite may lose one layer of water and transform into birnessite. Some buserite minerals are resistant to dehydratation to various degrees, however, depending on the structure of the interlayer. Buserite of marine ferromangnanese nodules transforms into birnessite upon heating to ...
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Birnessite
Birnessite (nominally MnO2.''n''H2O) is a hydrous manganese dioxide mineral with a chemical formula of Na0.7Ca0.3Mn7O14·2.8H2O. It is the main manganese mineral species at the Earth's surface, and commonly occurs as fine-grained, poorly crystallized aggregates in soils, sediments, grain and rock coatings (e.g., desert varnish), and marine ferromanganese nodules and crusts. It was discovered at Birness, Aberdeenshire, Scotland. Formation Its precipitation from the oxidation of Mn(II) in oxygenated aqueous solutions is kinetically hindered and slow on mineral surfaces. Biological Mn(II) oxidation is generally fast relative to abiotic Mn(II) oxidation processes, and for this reason the majority of natural birnessites is believed to be produced by microorganisms, especially bacteria but also fungi. Composition and structure Birnessite is a non-stoichiometric compound, in which variable amounts of Mn4+ ions in the nominal MnO2·''n''H2O formula either are missing, or are r ...
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Manganese Nodule
Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. Nodules vary in size from tiny particles visible only under a microscope to large pellets more than across. However, most nodules are between in diameter, about the size of hen's eggs or potatoes. Their surface textures vary from smooth to rough. They frequently have botryoidal (mammillated or knobby) texture and vary from spherical in shape to typically oblate (flying saucer), sometimes prolate (Rugby ball), or are otherwise irregular. The bottom surface, buried in sediment, is generally rougher than the top due to a different type of growth. Occurrence Nodules lie on the seabed sediment, often partly or completely buried. They vary greatly in abundance, in some cases ...
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Ferromanganese Nodules
Ferromanganese nodules form in the oxidizing environment of the abyssal pelagic zone. They are the result of ion exchange reactions that precipitate ore components from the water (sedimentary) or out of the interstitial water of the sediments layers (diagenetic). The composition of Manganese-bearing minerals is dependent on how the nodules are formed; sedimentary nodules, which have a lower Mn2+ content than diagenetic, are dominated by Fe- vernadite, Mn-feroxyhyte, and asbolane-buserite while diagenetic nodules are dominated by buserite I, birnessite, todorokite Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula . It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but ..., and asbolane-buserite. References * {{cite journal, last=Novikov, first=C.V., author2=Murdmaa, I.O., year=2007, title=Ion exchange properties of oceanic ferromanganese n ...
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Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite *** Cassiterite ** Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite *** Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to mod ...
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Swiss People
The Swiss people (german: die Schweizer, french: les Suisses, it, gli Svizzeri, rm, ils Svizzers) are the citizens of Switzerland or people of Swiss abroad, Swiss ancestry. The number of Swiss nationality law, Swiss nationals has grown from 1.7 million in 1815 to 8.7 million in 2020. More than 1.5 million Swiss citizens hold multiple citizenship. About 11% of citizens Swiss abroad, live abroad (0.8 million, of whom 0.6 million hold multiple citizenship). About 60% of those living abroad reside in the European Union (0.46 million). The largest groups of Swiss descendants and nationals outside Europe are found in the Swiss Americans, United States, Brazil and Swiss Canadian, Canada. Although the Switzerland as a federal state, modern state of Switzerland originated in 1848, the period of romantic nationalism, it is not a nation-state, and the Swiss are not a single ethnic group, but rather are a Confederation, confederacy (') or ' ("nation of will", "nation by choice", tha ...
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Angstrom
The angstromEntry "angstrom" in the Oxford online dictionary. Retrieved on 2019-03-02 from https://en.oxforddictionaries.com/definition/angstrom.Entry "angstrom" in the Merriam-Webster online dictionary. Retrieved on 2019-03-02 from https://www.merriam-webster.com/dictionary/angstrom. (, ; , ) or ångström is a metric unit of length equal to m; that is, one ten-billionth ( US) of a metre, a hundred-millionth of a centimetre,Entry "angstrom" in the Oxford English Dictionary, 2nd edition (1986). Retrieved on 2021-11-22 from https://www.oed.com/oed2/00008552. 0.1 nanometre, or 100 picometres. Its symbol is Å, a letter of the Swedish alphabet. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals,Arturas Vailionis (2015):Geometry of Crystals Lect ...
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Manganate
In inorganic nomenclature, a manganate is any negatively charged molecular entity with manganese as the central atom.. However, the name is usually used to refer to the tetraoxidomanganate(2−) anion, MnO, also known as manganate(VI) because it contains manganese in the +6 oxidation state. Manganates are the only known manganese(VI) compounds.. Other manganates include hypomanganate or manganate(V), , permanganate or manganate(VII), , and the dimanganate or dimanganate(III) . A manganate(IV) anion has been prepared by radiolysis of dilute solutions of permanganate.. It is mononuclear in dilute solution, and shows a strong absorption in the ultraviolet and a weaker absorption at 650 nm. Structure The manganate(VI) ion is tetrahedral, similar to sulfate or chromate: indeed, manganates are often isostructural with sulfates and chromates, a fact first noted by Eilhard Mitscherlich in 1831.. The manganese–oxygen distance is 165.9 pm, about 3 pm longer than in p ...
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International Mineralogical Association
Founded in 1958, the International Mineralogical Association (IMA) is an international group of 40 national societies. The goal is to promote the science of mineralogy and to standardize the nomenclature of the 5000 plus known mineral species. The IMA is affiliated with the International Union of Geological Sciences (IUGS). The Association supports the activities of Commissions and Working Groups involved on certain aspects of mineralogical practice and facilitates interactions among mineralogists by sponsoring and organising meetings. In particular, the IMA holds its general meeting every four years. The next meeting is scheduled in 2022 in Lyon, France. Presidents The presidents of the IMA have been: * since 2021: Anhuai Lu ** Peking University *2018–2020: Patrick Cordier (born 1961) ** Université de Lille *2016–2018: Peter C. Burns ** University of Notre Dame *2014–2016: Sergey V. Krivovichev (born 1972) ** Saint Petersburg State University *2012–2014: Walter ...
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Water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a solvent). It is vital for all known forms of life, despite not providing food, energy or organic micronutrients. Its chemical formula, H2O, indicates that each of its molecules contains one oxygen and two hydrogen atoms, connected by covalent bonds. The hydrogen atoms are attached to the oxygen atom at an angle of 104.45°. "Water" is also the name of the liquid state of H2O at standard temperature and pressure. A number of natural states of water exist. It forms precipitation in the form of rain and aerosols in the form of fog. Clouds consist of suspended droplets of water and ice, its solid state. When finely divided, crystalline ice may precipitate in the form of snow. The gaseous state of water is steam or water vapor. Water co ...
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Manganese Minerals
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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