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Borate Flint
A borate is any of several boron oxyanions, anion, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt (chemistry), salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate mineral, borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral borax, sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Crust (geology), Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borax
Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, and has many industrial and household uses, including as a pesticide, as a metal soldering flux, as a component of glass, enamel, and pottery glazes, for tanning of skins and hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffering agent. The compound is often called sodium tetraborate decahydrate, but that name is not consistent with its structure. The anion is not tetraborate but tetrahydroxy tetraborate , so the more correct formula should be . Informally, the product is often called sodium borate decahydrate or just sodium borate. The terms tincal "tinkle" and tincar "tinker" refer to native borax, historically mined from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Suanite
Suanite is a magnesium borate mineral with formula Mg2B2O5. It was first described in 1953 by Japanese scientist Takeo Watanabe from the University of Tokyo. His first contact with the mineral was during analysis of gold- and copper- bearing skarn minerals from the Hol Kol mine, located in North Korea North Korea, officially the Democratic People's Republic of Korea (DPRK), is a country in East Asia. It constitutes the northern half of the Korea, Korean Peninsula and shares borders with China and Russia to the north, at the Yalu River, Y ... obtained in 1939. Due to the small sample size available to him, he was only able to determine the unknown substance's optical properties under a microscope. Watanabe was able to return to the site in 1943 and obtain further samples that permitted him to perform chemical analysis on the material. References Nesoborates Magnesium minerals Monoclinic minerals Minerals in space group 14 {{mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnesium Diborate
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table) it occurs naturally only in combination with other elements and it almost always has an oxidation state of +2. It reacts readily with air to form a thin passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Perborate
Sodium perborate is chemical compound whose chemical formula may be written , , or, more properly, ·. Its name is sometimes abbreviated as PBS (not to be confused with phosphate-buffered saline). The compound is commonly encountered in anhydrous form or as a hexahydrate (commonly called "monohydrate" or PBS-1 and "tetrahydrate" or PBS-4, after the early assumption that would be the anhydrous form).Alexander McKillop and William R Sanderson (1995): "Sodium perborate and sodium percarbonate: Cheap, safe and versatile oxidising agents for organic synthesis". ''Tetrahedron'', volume 51, issue 22, pages 6145-6166. They are both white, odorless, water-soluble solids.B.J. Brotherton "Boron: Inorganic Chemistry" in ''Encyclopedia of Inorganic Chemistry'' (1994) Ed. R. Bruce King, John Wiley & Sons This salt is widely used in laundry detergents, as one of the peroxide-based bleaches. Structure Unlike sodium percarbonate and sodium perphosphate, the compound is not simply an adduct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trisodium Orthoborate
Trisodium borate is a chemical compound of sodium, boron, and oxygen, with formula , or . It is a salt with the orthoborate anion . The compound is also called trisodium orthoborate, sodium orthoborate, or just sodium borate. However, "sodium orthoborate" has been used also for a compound with formula , which would correspond to an equimolar mixture of sodium metaborate and trisodium borate proper. and "sodium borate" is sometimes used in the generic sense, for a sodium salt with any of several other borate anions. Preparation Sodium carbonate will react with sodium metaborate or boric oxide to form the orthoborate and carbon dioxide when heated between 600 and 850 °C: : + → + Difficult to obtain in pure form from melts. Properties Reactions When dissolved in water, the orthoborate anion partially hydrolyzes into metaborate and hydroxide : : + + 3 Electrolysis of a solution of sodium orthoborate generates sodium perborate at the anode An a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Tetrahydroxyborate
Sodium tetrahydroxyborate is a salt (ionic compound) of with chemical formula or . It is one of several sodium borates. At room temperature it is a colorless transparent crystalline solid. The element ratio corresponds to the oxide mixture , but the structure of the solid is quite different from that suggested by this formula. Structure Sodium tetrahydroxyborate has been crystallized from aqueous solutions in two anhydrous forms. Both contain the tetrahedral tetrahydroxyborate anion, which is formed from (ortho)boric acid in water solutions by binding an hydroxide anion instead of loss of a proton . These anions lie in layers perpendicular to the (010) plane, and form a tridimensional lattice held together by hydrogen bonds between the hydrogen atoms in each anion and the oxygen atoms in adjacent anions. Monoclinic form The first form, described in 1993, crystallizes in the monoclinic crystal system with symmetry group ''P''21/''a'' and parameters ''a'' = 588.6 pm, ''b'' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrahydroxyborate
Tetrahydroxyborate is an inorganic anion with the chemical formula or . It contributes no colour to tetrahydroxyborate salts. It is found in the mineral hexahydroborite, , originally formulated . It is one of the boron oxoanions, and acts as a weak base. The systematic names are tetrahydroxyboranuide (substitutive) and tetrahydroxidoborate(1−) (additive). It can be viewed as the conjugate base of boric acid. Structure Tetrahydroxyborate has a symmetric tetrahedral geometry, isoelectronic with the hypothetical compound orthocarbonic acid . Chemical properties Basicity Tetrahydroxyborate act as a weak Brønsted–Lowry base because it can assimilate a proton (), yielding boric acid with release of water: : + + It can also release a hydroxy anion , thus acting as a classical Arrhenius base: : + (pK = 9.14 to the left) Thus, when boric acid is dissolved in pure (neutral) water, most of it will exist as tetrahydroxyborate ions. With diols In aqueous solution, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
