Biomimetic Antifouling Coating
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Biomimetic Antifouling Coating
A biomimetic antifouling coating is a treatment that prevents the accumulation of marine organisms on a surface. Typical antifouling coatings are not biomimetic but are based on synthetic chemical compounds that can have deleterious effects on the environment. Prime examples are tributyltin compounds, which are components in paints to prevent biofouling of ship hulls. Although highly effective at combatting the accumulation of barnacles and other problematic organisms, organotin-containing paints are damaging to many organisms and have been shown to interrupt marine food chains.1. Gittens, J. E., Smith, T. J., Suleiman, R., Akid, R., "Current and emerging environmentally-friendly systems for fouling control in the marine environment", Biotechnol. Adv. 2013, 31, 1738. Biomimetic antifouling coatings are highly lucrative because of their low environmental impact and demonstrated success. Some properties of a biomimetic antifouling coating can be predicted from the contact angles ...
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Biomimicry
Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from grc, βίος (''bios''), life, and μίμησις ('' mīmēsis''), imitation, from μιμεῖσθαι (''mīmeisthai''), to imitate, from μῖμος (''mimos''), actor. A closely related field is bionics. Living organisms have evolved well-adapted structures and materials over geological time through natural selection. Biomimetics has given rise to new technologies inspired by biological solutions at macro and nanoscales. Humans have looked at nature for answers to problems throughout their existence. Nature has solved engineering problems such as self-healing abilities, environmental exposure tolerance and resistance, hydrophobicity, self-assembly, and harnessing solar energy. History One of the early examples of biomimicry was the study of birds to enable human flight. Al ...
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Ligand
In coordination chemistry, a ligand is an ion or molecule ( functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's electron pairs, often through Lewis bases. The nature of metal–ligand bonding can range from covalent to ionic. Furthermore, the metal–ligand bond order can range from one to three. Ligands are viewed as Lewis bases, although rare cases are known to involve Lewis acidic "ligands". Metals and metalloids are bound to ligands in almost all circumstances, although gaseous "naked" metal ions can be generated in a high vacuum. Ligands in a complex dictate the reactivity of the central atom, including ligand substitution rates, the reactivity of the ligands themselves, and redox. Ligand selection requires critical consideration in many practical areas, including bioinorganic and medicinal chemistry, homogeneous catalysis, and environment ...
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Sharklet (material)
Sharklet, manufactured by Sharklet Technologies, is a bio-inspired plastic sheet product structured to impede microorganism growth, particularly bacterial growth. It is marketed for use in hospitals and other places with a relatively high potential for bacteria to spread and cause infections. Coating surfaces with Sharklet work due to the nano-scale texture of the product's surface. The inspiration for Sharklet's texture came through analysis of the texture of shark skin, which does not attract barnacles or other biofouling, unlike ship hulls and other smooth surfaces. The texture was later found to also repel microbial activity. History Sharklet material is bio-inspired and was developed by Dr. Anthony Brennan, materials science and engineering professor at University of Florida, while trying to improve antifouling technology for ships and submarines at Pearl Harbor. Brennan realized that sharks do not experience fouling. He observed that shark's skin denticles are arra ...
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Tributyltin
Tributyltin (TBT) is an umbrella term for a class of organotin compounds which contain the (C4H9)3 Sn group, with a prominent example being tributyltin oxide. For 40 years TBT was used as a biocide in anti-fouling paint, commonly known as bottom paint, applied to the hulls of oceangoing vessels. Bottom paint improves ship performance and durability as it reduces the rate of biofouling, the growth of organisms on the ship's hull. The TBT slowly leaches out into the marine environment where it is highly toxic toward nontarget organisms. TBT toxicity can lead to biomagnification or bioaccumulation within such nontarget organisms like invertebrates, vertebrates, and a variety of mammals. TBT is also an obesogen. After it led to collapse of local populations of organisms, TBT was banned. Chemical properties TBT, or tributyltin, tributylstannyl or tributyl stannic hydride compounds are organotin compounds. They have three butyl groups covalently bonded to a tin(IV) centre.Davies, ...
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Bionics
Bionics or biologically inspired engineering is the application of biological methods and systems found in nature to the study and design of engineering systems and modern technology. The word ''bionic'', coined by Jack E. Steele in August 1958, is a portmanteau from ''biology'' and ''electronics'' that was popularized by the 1970s U.S. television series ''The Six Million Dollar Man'' and '' The Bionic Woman'', both based upon the novel '' Cyborg'' by Martin Caidin. All three stories feature humans given various superhuman powers by their electromechanical implants. According to proponents of bionic technology, the transfer of technology between lifeforms and manufactured objects is desirable because evolutionary pressure typically forces living organisms – fauna and flora – to become optimized and efficient. For example, dirt- and water-repellent paint (coating) developed from the observation that practically nothing sticks to the surface of the lotus flower plant (the ...
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Anti-fouling
Biofouling or biological fouling is the accumulation of microorganisms, plants, algae, or small animals where it is not wanted on surfaces such as ship and submarine hulls, devices such as water inlets, pipework, grates, ponds, and rivers that cause degradation to the primary purpose of that item. Such accumulation is referred to as '' epibiosis'' when the host surface is another organism and the relationship is not parasitic. Since biofouling can occur almost anywhere water is present, biofouling poses risks to a wide variety of objects such as boat hulls and equipment, medical devices and membranes, as well as to entire industries, such as paper manufacturing, food processing, underwater construction, and desalination plants. Anti-fouling is the ability of specifically designed materials (such as toxic biocide paints, or non-toxic paints) to remove or prevent biofouling. The buildup of biofouling on marine vessels poses a significant problem. In some instances, the hull stru ...
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Fouling
Fouling is the accumulation of unwanted material on solid surfaces. The fouling materials can consist of either living organisms ( biofouling) or a non-living substance (inorganic or organic). Fouling is usually distinguished from other surface-growth phenomena in that it occurs on a surface of a component, system, or plant performing a defined and useful function and that the fouling process impedes or interferes with this function. Other terms used in the literature to describe fouling include deposit formation, encrustation, crudding, deposition, scaling, scale formation, slagging, and sludge formation. The last six terms have a more narrow meaning than fouling within the scope of the fouling science and technology, and they also have meanings outside of this scope; therefore, they should be used with caution. Fouling phenomena are common and diverse, ranging from fouling of ship hulls, natural surfaces in the marine environment ( marine fouling), fouling of heat-transf ...
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Biofouling
Biofouling or biological fouling is the accumulation of microorganisms, plants, algae, or small animals where it is not wanted on surfaces such as ship and submarine hulls, devices such as water inlets, pipework, grates, ponds, and rivers that cause degradation to the primary purpose of that item. Such accumulation is referred to as '' epibiosis'' when the host surface is another organism and the relationship is not parasitic. Since biofouling can occur almost anywhere water is present, biofouling poses risks to a wide variety of objects such as boat hulls and equipment, medical devices and membranes, as well as to entire industries, such as paper manufacturing, food processing, underwater construction, and desalination plants. Anti-fouling is the ability of specifically designed materials (such as toxic biocide paints, or non-toxic paints) to remove or prevent biofouling. The buildup of biofouling on marine vessels poses a significant problem. In some instances, the hull stru ...
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Wenzel
Wenzel is a male given name (long version Wenzeslaus) as the German and Old English form of the Czech given name Václav or Venceslav, meaning "praised with glory". Variations are Вячеслав (Ukrainian and Russian), Vencel (Hungarian), Wacław, Więcław, Wiesław (Polish), Venceslas/Wenceslas (French), Venceslao (Italian), Venceslau (Portuguese), Wenceslao (Spanish). Given name * Wenzel Jamnitzer (ca. 1507–1585), Austrian-German etcher and goldsmith * Wenzel, Archduke of Austria (1561–1578), Austrian prince and Grand Prior of the Order of Malta * Wenzel Anton Graf Kaunitz (1711–1794), Austrian statesman * Wenzel Raimund Birck (1718–1763), Austrian composer * Wenzel Parler (1333–1399), German-Bohemian architect * Wenzel Pichl (1741–1805), Czech composer * Wenzel Thomas Matiegka (1773–1830), Bohemian composer * Prince Klemens Wenzel von Metternich (1773–1859), German-Austrian politician and statesman * Wolfgang Wenzel von Haffner (1806–1892), Norwegian ...
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Contact Angle
The contact angle is the angle, conventionally measured through the liquid, where a liquid–vapor interface meets a solid surface. It quantifies the wettability of a solid surface by a liquid via the Young equation. A given system of solid, liquid, and vapor at a given temperature and pressure has a unique equilibrium contact angle. However, in practice a dynamic phenomenon of contact angle hysteresis is often observed, ranging from the advancing (maximal) contact angle to the receding (minimal) contact angle. The equilibrium contact is within those values, and can be calculated from them. The equilibrium contact angle reflects the relative strength of the liquid, solid, and vapour molecular interaction. The contact angle depends upon the medium above the free surface of the liquid, and the nature of the liquid and solid in contact. It is independent of the inclination of solid to the liquid surface. It changes with surface tension and hence with the temperature and purity of ...
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Placoid Scales
A fish scale is a small rigid plate that grows out of the skin of a fish. The skin of most jawed fishes is covered with these protective scales, which can also provide effective camouflage through the use of reflection and colouration, as well as possible hydrodynamic advantages. The term ''scale'' derives from the Old French , meaning a shell pod or husk. Scales vary enormously in size, shape, structure, and extent, ranging from strong and rigid armour plates in fishes such as shrimpfishes and boxfishes, to microscopic or absent in fishes such as eels and anglerfishes. The morphology of a scale can be used to identify the species of fish it came from. Scales originated within the jawless ostracoderms, ancestors to all jawed fishes today. Most bony fishes are covered with the cycloid scales of salmon and carp, or the ctenoid scales of perch, or the ganoid scales of sturgeons and gars. Cartilaginous fishes (sharks and rays) are covered with placoid scales. Some species a ...
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Nicotinamide
Niacinamide or Nicotinamide (NAM) is a form of vitamin B3 found in food and used as a dietary supplement and medication. As a supplement, it is used by mouth to prevent and treat pellagra (niacin deficiency). While nicotinic acid (niacin) may be used for this purpose, niacinamide has the benefit of not causing skin flushing. As a cream, it is used to treat acne. It is a water-soluble vitamin. Niacinamide is the supplement name while Nicotinamide (NAM) is the scientific name. Side effects are minimal. At high doses liver problems may occur. Normal amounts are safe for use during pregnancy. Niacinamide is in the vitamin B family of medications, specifically the vitamin B3 complex. It is an amide of nicotinic acid. Foods that contain niacinamide include yeast, meat, milk, and green vegetables. Niacinamide was discovered between 1935 and 1937. It is on the World Health Organization's List of Essential Medicines. Niacinamide is available as a generic medication and over th ...
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