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Borates
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refers to certain functional groups in molecules consisting of boron and oxygen, and esters with such groups, such as triethyl orthoborate . Natural occurrence Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. Borates also occur in plants, including almost all fruits. Anions The main borate anions are: * tetrahydroxyborate , found in sodium tetrahydroxyborate . * orthoborate , found in trisodium orthoborate * perborate , as in sodium perborate * metaborate or , found in sodium metaborate * diborate , f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borate Mineral
The borate minerals are minerals which contain a borate anion group. The borate (BO3) units may be polymerised similar to the SiO4 unit of the silicate mineral class. This results in B2O5, B3O6, B2O4 anions as well as more complex structures which include hydroxide or halogen anions.Klein, Cornelis and Cornelius Hurlbut, Jr., ''Manual of Mineralogy'', Wiley, 20th ed., 1985 pp. 343 - 347 The (O,OH)4sup>− anion exists as well. Many borate minerals, such as borax, colemanite, and ulexite, are salts: soft, readily soluble, and found in evaporite contexts. However, some, such as boracite, are hard and resistant to weathering, more similar to the silicates. There are over 100 different borate minerals. Vanadates), 09 Silicates: * ''neso-'': insular (from Greek , "island") * ''soro-'': grouped (from Greek , "heap, pile, mound") * ''cyclo-'': rings of (from Greek , "circle") * ''ino-'': chained (from Greek , "fibre", rom Ancient Greek * ''phyllo-'': sheets of (from Greek , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has three valence electrons for forming covalent bonds, resulting in many compounds such as boric acid, the mineral borax, sodium borate, and the ultra-hard crystals of boron carbide and boron nitride. Boron is synthesized entirely by cosmic ray spallation and supernovae and not by stellar nucleosynthesis, so it is a low-abundance element in the Solar System and in the Crust (geology), Earth's crust. It constitutes about 0.001 percent by weight of Earth's crust. It is concentrated on Earth by the water-solubility of its more common naturally occurring compounds, the borate minerals. These are mined industrially as evaporites, such as borax and kernite. The largest known deposits are in Turkey, the largest producer of boron minerals. Elemental b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ulexite
Ulexite (NaCaB5O6(OH)6·5H2O, hydrated sodium calcium borate hydroxide), sometimes known as TV rock or Television stone, is a mineral occurring in silky white rounded crystalline masses or in parallel fibers. The natural fibers of ulexite conduct light along their long axes, by internal reflection. Ulexite was named for the German chemist Georg Ludwig Ulex (1811–1883) who first discovered it. Ulexite is a structurally complex mineral, with a basic structure containing chains of sodium, water and hydroxide octahedra. The chains are linked together by calcium, water, hydroxide and oxygen polyhedra and massive boron units. The boron units have a formula of 5O6(OH)6sup>3– and a charge of −3. They are composed of three borate tetrahedra and two borate triangular groups. Ulexite is found in evaporite deposits and the precipitated ulexite commonly forms a "cotton ball" tuft of acicular crystals. Ulexite is frequently found associated with colemanite, borax, meyerhofferite, hydro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Perborate
Sodium perborate is chemical compound whose chemical formula may be written , , or, more properly, ·. Its name is sometimes abbreviated as PBS (not to be confused with phosphate-buffered saline). The compound is commonly encountered in anhydrous form or as a hexahydrate (commonly called "monohydrate" or PBS-1 and "tetrahydrate" or PBS-4, after the early assumption that would be the anhydrous form).Alexander McKillop and William R Sanderson (1995): "Sodium perborate and sodium percarbonate: Cheap, safe and versatile oxidising agents for organic synthesis". ''Tetrahedron'', volume 51, issue 22, pages 6145-6166. They are both white, odorless, water-soluble solids.B.J. Brotherton "Boron: Inorganic Chemistry" in ''Encyclopedia of Inorganic Chemistry'' (1994) Ed. R. Bruce King, John Wiley & Sons This salt is widely used in laundry detergents, as one of the peroxide-based bleaches. Structure Unlike sodium percarbonate and sodium perphosphate, the compound is not simply an adduct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Borax
Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, and has many industrial and household uses, including as a pesticide, as a metal soldering flux, as a component of glass, enamel, and pottery glazes, for tanning of skins and hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffering agent. The compound is often called sodium tetraborate decahydrate, but that name is not consistent with its structure. The anion is not tetraborate but tetrahydroxy tetraborate , so the more correct formula should be . Informally, the product is often called sodium borate decahydrate or just sodium borate. The terms tincal "tinkle" and tincar "tinker" refer to native borax, historically mined from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disodium Tetraborate
Borax is a salt (ionic compound), a hydrated borate of sodium, with chemical formula often written . It is a colorless crystalline solid, that dissolves in water to make a basic solution. It is commonly available in powder or granular form, and has many industrial and household uses, including as a pesticide, as a metal soldering flux, as a component of glass, enamel, and pottery glazes, for tanning of skins and hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffering agent. The compound is often called sodium tetraborate decahydrate, but that name is not consistent with its structure. The anion is not tetraborate but tetrahydroxy tetraborate , so the more correct formula should be . Informally, the product is often called sodium borate decahydrate or just sodium borate. The terms tincal "tinkle" and tincar "tinker" refer to native borax, historically mined from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Colemanite
Colemanite (Ca2B6O11·5H2O) or (CaB3O4(OH)3·H2O) is a borate mineral found in evaporite deposits of alkaline lacustrine environments. Colemanite is a secondary mineral that forms by alteration of borax and ulexite. It was first described in 1884 for an occurrence near Furnace Creek in Death Valley and was named after William Tell Coleman (1824–1893), owner of the mine "Harmony Borax Works" where it was first found. At the time, Coleman had alternatively proposed the name "smithite" instead after his business associate Francis Marion Smith. Uses Colemanite is an important ore of boron, and was the most important boron ore until the discovery of kernite in 1926. It has many industrial uses, like the manufacturing of heat resistant glass. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A * Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–20 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boracite
Boracite is a magnesium borate mineral with formula: Mg3 B7 O13 Cl. It occurs as blue green, colorless, gray, yellow to white crystals in the orthorhombic - pyramidal crystal system. Boracite also shows pseudo-isometric cubical and octahedral forms. These are thought to be the result of transition from an unstable high temperature isometric form on cooling. Penetration twins are not unusual. It occurs as well formed crystals and dispersed grains often embedded within gypsum and anhydrite crystals. It has a Mohs hardness of 7 to 7.5 and a specific gravity of 2.9. Refractive index values are nα = 1.658 - 1.662, nβ = 1.662 - 1.667 and nγ = 1.668 - 1.673. It has a conchoidal fracture and does not show cleavage. It is insoluble in water (not to be confused with borax, which is soluble in water). Boracite is typically found in evaporite sequences associated with gypsum, anhydrite, halite, sylvite, carnallite, kainite and hilgardite. It was first described in 1789 for specimens fro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Suanite
Suanite is a magnesium borate mineral with formula Mg2B2O5. It was first described in 1953 by Japanese scientist Takeo Watanabe from the University of Tokyo. His first contact with the mineral was during analysis of gold- and copper- bearing skarn minerals from the Hol Kol mine, located in North Korea North Korea, officially the Democratic People's Republic of Korea (DPRK), is a country in East Asia. It constitutes the northern half of the Korea, Korean Peninsula and shares borders with China and Russia to the north, at the Yalu River, Y ... obtained in 1939. Due to the small sample size available to him, he was only able to determine the unknown substance's optical properties under a microscope. Watanabe was able to return to the site in 1943 and obtain further samples that permitted him to perform chemical analysis on the material. References Nesoborates Magnesium minerals Monoclinic minerals Minerals in space group 14 {{mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tetrahydroxyborate
Tetrahydroxyborate is an inorganic anion with the chemical formula or . It contributes no colour to tetrahydroxyborate salts. It is found in the mineral hexahydroborite, , originally formulated . It is one of the boron oxoanions, and acts as a weak base. The systematic names are tetrahydroxyboranuide (substitutive) and tetrahydroxidoborate(1−) (additive). It can be viewed as the conjugate base of boric acid. Structure Tetrahydroxyborate has a symmetric tetrahedral geometry, isoelectronic with the hypothetical compound orthocarbonic acid . Chemical properties Basicity Tetrahydroxyborate act as a weak Brønsted–Lowry base because it can assimilate a proton (), yielding boric acid with release of water: : + + It can also release a hydroxy anion , thus acting as a classical Arrhenius base: : + (pK = 9.14 to the left) Thus, when boric acid is dissolved in pure (neutral) water, most of it will exist as tetrahydroxyborate ions. With diols In aqueous solution, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Metaborate
Sodium metaborate is a chemical compound of sodium, boron, and oxygen with formula . However, the metaborate ion is trimeric in the anhydrous solid, therefore a more correct formula is or . The formula can be written also as · to highlight the relation to the main oxides of sodium and boron. The name is also applied to several hydrates whose formulas can be written for various values of ''n''. The anhydrous and hydrates are colorless crystalline solids. The anhydrous form is hygroscopic. Hydrates and solubility The following hydrates crystallize from solutions of the proper composition in various temperature ranges: * tetrahydrate ·4 from −6 to 53.6 °C * dihydrate ·2 from 53.6 °C to 105 °C * hemihydrate ·0.5 from 105 °C to the boiling point. Early reports of a monohydrate · have not been confirmed. Structure Anhydrous Solid anhydrous sodium metaborate has the hexagonal crystal system with space group R\bar3 c. It actually contains the trimeric ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
