Amperostat
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Amperostat
A galvanostat (also known as amperostat) is a control and measuring device capable of keeping the current through an electrolytic cell in coulometric titrations constant, disregarding changes in the load itself. Its main feature is its ''nearly'' "''infinite''" (i.e. extremely high in respect to common loads) internal resistance. The designation "''galvanostat''" is mainly used in electrochemistry: this device differs from common constant current sources by its ability to supply ''and measure'' a wide range of currents (from picoamperes to amperes) of both polarities. The galvanostat responds to changes in the resistance of the cell by varying its output potential: as Ohm's law shows, : = the variable system resistance and the controlled voltage are directly proportional, i.e. : U_c = where *''I_o'' is the electric current that is kept constant *''U_c'' is the output control voltage of the amperostat *''R_v'' is the electrical resistance that varies; thus, an increase ...
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Coulometric
Coulometry determines the amount of matter transformed during an electrolysis reaction by measuring the amount of electricity (in coulombs) consumed or produced. It can be used for precision measurements of charge, and the amperes even used to have a coulometric definition. However, today coulometry is mainly used for analytical applications. Coulometry is a group of techniques in analytical chemistry. It is named after Charles-Augustin de Coulomb. There are two basic categories of coulometric techniques. ''Potentiostatic coulometry'' involves holding the electric potential constant during the reaction using a potentiostat. The other, called ''coulometric titration'' or ''amperostatic coulometry'', keeps the current (measured in amperes) constant using an amperostat. Potentiostatic coulometry Potentiostatic coulometry is a technique most commonly referred to as "bulk electrolysis". The working electrode is kept at a constant potential and the current that flows through th ...
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Control System
A control system manages, commands, directs, or regulates the behavior of other devices or systems using control loops. It can range from a single home heating controller using a thermostat controlling a domestic boiler to large industrial control systems which are used for controlling processes or machines. The control systems are designed via control engineering process. For continuously modulated control, a feedback controller is used to automatically control a process or operation. The control system compares the value or status of the process variable (PV) being controlled with the desired value or setpoint (SP), and applies the difference as a control signal to bring the process variable output of the plant to the same value as the setpoint. For sequential and combinational logic, software logic, such as in a programmable logic controller, is used. Open-loop and closed-loop control There are two common classes of control action: open loop and closed loop. In an ...
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Electrical Polarity
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving particles are called charge carriers, which may be one of several types of particles, depending on the conductor. In electric circuits the charge carriers are often electrons moving through a wire. In semiconductors they can be electrons or Electron hole, holes. In an Electrolyte#Electrochemistry, electrolyte the charge carriers are ions, while in Plasma (physics), plasma, an ionized gas, they are ions and electrons. The International System of Units, SI unit of electric current is the ampere, or ''amp'', which is the flow of electric charge across a surface at the rate of one coulomb per second. The ampere (symbol: A) is an SI base unit. Electric current is measured using a device called an ammeter. Electric currents create magnetic fields ...
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Current Source
A current source is an electronic circuit that delivers or absorbs an electric current which is independent of the voltage across it. A current source is the dual of a voltage source. The term ''current sink'' is sometimes used for sources fed from a negative voltage supply. Figure 1 shows the schematic symbol for an ideal current source driving a resistive load. There are two types. An ''independent current source'' (or sink) delivers a constant current. A ''dependent current source'' delivers a current which is proportional to some other voltage or current in the circuit. Background , - align="center" , style="padding: 1em 2em 0;", , style="padding: 1em 2em 0;", , - align="center" , Voltage source , Current source , - align="center" , style="padding: 1em 2em 0;", , style="padding: 1em 2em 0;", , - align="center" , Controlled voltage source , Controlled current source , - align="center" , style="padding: 1em 2em 0;", , style="padding: 1em 2em 0;", , - align ...
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Operational Amplifier
An operational amplifier (often op amp or opamp) is a DC-coupled high-gain electronic voltage amplifier with a differential input and, usually, a single-ended output. In this configuration, an op amp produces an output potential (relative to circuit ground) that is typically 100,000 times larger than the potential difference between its input terminals. The operational amplifier traces its origin and name to analog computers, where they were used to perform mathematical operations in linear, non-linear, and frequency-dependent circuits. The popularity of the op amp as a building block in analog circuits is due to its versatility. By using negative feedback, the characteristics of an op-amp circuit, its gain, input and output impedance, bandwidth etc. are determined by external components and have little dependence on temperature coefficients or engineering tolerance in the op amp itself. Op amps are used widely in electronic devices today, including a vast array of consumer, ...
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Ampere
The ampere (, ; symbol: A), often shortened to amp,SI supports only the use of symbols and deprecates the use of abbreviations for units. is the unit of electric current in the International System of Units (SI). One ampere is equal to electrons worth of charge moving past a point in a second. It is named after French mathematician and physicist André-Marie Ampère (1775–1836), considered the father of electromagnetism along with Danish physicist Hans Christian Ørsted. As of the 2019 redefinition of the SI base units, the ampere is defined by fixing the elementary charge to be exactly C ( coulomb), which means an ampere is an electrical current equivalent to elementary charges moving every seconds or elementary charges moving in a second. Prior to the redefinition the ampere was defined as the current that would need to be passed through 2 parallel wires 1 metre apart to produce a magnetic force of newtons per metre. The earlier CGS system had two definitio ...
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Electronic Feedback Loops
Feedback occurs when outputs of a system are routed back as inputs as part of a chain of cause-and-effect that forms a circuit or loop. The system can then be said to ''feed back'' into itself. The notion of cause-and-effect has to be handled carefully when applied to feedback systems: History Self-regulating mechanisms have existed since antiquity, and the idea of feedback had started to enter economic theory in Britain by the 18th century, but it was not at that time recognized as a universal abstraction and so did not have a name. The first ever known artificial feedback device was a float valve, for maintaining water at a constant level, invented in 270 BC in Alexandria, Egypt. This device illustrated the principle of feedback: a low water level opens the valve, the rising water then provides feedback into the system, closing the valve when the required level is reached. This then reoccurs in a circular fashion as the water level fluctuates. Centrifugal governors were ...
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Directly Proportional
In mathematics, two sequences of numbers, often experimental data, are proportional or directly proportional if their corresponding elements have a constant ratio, which is called the coefficient of proportionality or proportionality constant. Two sequences are inversely proportional if corresponding elements have a constant product, also called the coefficient of proportionality. This definition is commonly extended to related varying quantities, which are often called ''variables''. This meaning of ''variable'' is not the common meaning of the term in mathematics (see variable (mathematics)); these two different concepts share the same name for historical reasons. Two functions f(x) and g(x) are ''proportional'' if their ratio \frac is a constant function. If several pairs of variables share the same direct proportionality constant, the equation expressing the equality of these ratios is called a proportion, e.g., (for details see Ratio). Proportionality is closely rela ...
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Voltage
Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to move a test charge between the two points. In the International System of Units, the derived unit for voltage is named ''volt''. The voltage between points can be caused by the build-up of electric charge (e.g., a capacitor), and from an electromotive force (e.g., electromagnetic induction in generator, inductors, and transformers). On a macroscopic scale, a potential difference can be caused by electrochemical processes (e.g., cells and batteries), the pressure-induced piezoelectric effect, and the thermoelectric effect. A voltmeter can be used to measure the voltage between two points in a system. Often a common reference potential such as the ground of the system is used as one of the points. A voltage can represent either a source ...
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Ohm's Law
Ohm's law states that the current through a conductor between two points is directly proportional to the voltage across the two points. Introducing the constant of proportionality, the resistance, one arrives at the usual mathematical equation that describes this relationship: :I = \frac, where is the current through the conductor, ''V'' is the voltage measured ''across'' the conductor and ''R'' is the resistance of the conductor. More specifically, Ohm's law states that the ''R'' in this relation is constant, independent of the current. If the resistance is not constant, the previous equation cannot be called ''Ohm's law'', but it can still be used as a definition of static/DC resistance. Ohm's law is an empirical relation which accurately describes the conductivity of the vast majority of electrically conductive materials over many orders of magnitude of current. However some materials do not obey Ohm's law; these are called non-ohmic. The law was named after t ...
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Electrical Resistance
The electrical resistance of an object is a measure of its opposition to the flow of electric current. Its reciprocal quantity is , measuring the ease with which an electric current passes. Electrical resistance shares some conceptual parallels with mechanical friction. The SI unit of electrical resistance is the ohm (), while electrical conductance is measured in siemens (S) (formerly called the 'mho' and then represented by ). The resistance of an object depends in large part on the material it is made of. Objects made of electrical insulators like rubber tend to have very high resistance and low conductance, while objects made of electrical conductors like metals tend to have very low resistance and high conductance. This relationship is quantified by resistivity or conductivity. The nature of a material is not the only factor in resistance and conductance, however; it also depends on the size and shape of an object because these properties are extensive rather than intens ...
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Amperes
The ampere (, ; symbol: A), often shortened to amp,SI supports only the use of symbols and deprecates the use of abbreviations for units. is the unit of electric current in the International System of Units (SI). One ampere is equal to electrons worth of charge moving past a point in a second. It is named after French mathematician and physicist André-Marie Ampère (1775–1836), considered the father of electromagnetism along with Danish physicist Hans Christian Ørsted. As of the 2019 redefinition of the SI base units, the ampere is defined by fixing the elementary charge to be exactly C (coulomb), which means an ampere is an electrical current equivalent to elementary charges moving every seconds or elementary charges moving in a second. Prior to the redefinition the ampere was defined as the current that would need to be passed through 2 parallel wires 1 metre apart to produce a magnetic force of newtons per metre. The earlier CGS system had two definitions of ...
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