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Aluminium(I) Chloride
Aluminium monochloride, or chloridoaluminium is the metal halide with the formula AlCl. Aluminum monochloride as a molecule is thermodynamically stable at high temperature and low pressure only. This compound is produced as a step in the Alcan process to smelt aluminium from an aluminium-rich alloy. When the alloy is placed in a reactor that is heated to 1,300 °C and mixed with aluminium trichloride, a gas of aluminium monochloride is produced. : It then disproportionates into aluminium melt and aluminium trichloride upon cooling to 900 °C. This molecule has been detected in the interstellar medium, where molecules are so dilute that intermolecular collisions are unimportant. See also *Aluminium monofluoride *Aluminium monobromide *Aluminium monoiodide Aluminium monoiodide is an aluminium(I) compound with the chemical formula AlI. It is unstable at room temperature due to dismutation: :6AlI -> + 4Al It forms a cyclic adduct Al4I4(NEt3)4 with triethylamine. See ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium Monofluoride
Aluminium monofluoride, also known as fluoridoaluminium, is the chemical compound with the formula AlF. This elusive species is formed by the reaction between aluminium trifluoride and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled. Clusters derived from related aluminium(I) halides can be stabilized using specialized ligands. This molecule has been detected in the interstellar medium, where molecules are so dilute that intermolecular collisions are unimportant. See also *Aluminium monobromide *Aluminium monochloride *Aluminium monoiodide Aluminium monoiodide is an aluminium(I) compound with the chemical formula AlI. It is unstable at room temperature due to dismutation: :6AlI -> + 4Al It forms a cyclic adduct Al4I4(NEt3)4 with triethylamine. See also *Aluminium monofluoride * A ... References Aluminium(I) compounds Fluorides Metal halides {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gallium Monofluoride
Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in group 13 of the periodic table and is similar to the other metals of the group (aluminium, indium, and thallium). Elemental gallium is a soft, silvery metal in standard temperature and pressure. In its liquid state, it becomes silvery white. If too much force is applied, the gallium may fracture conchoidally. Since its discovery in 1875, gallium has widely been used to make alloys with low melting points. It is also used in semiconductors, as a dopant in semiconductor substrates. The melting point of gallium is used as a temperature reference point. Gallium alloys are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. An even lower melting point of , well below the freezing point of water, is claimed for the alloy galinstan (62–95 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 and 170 thousand times atmospheric pressure. Equally, some materials regarded as metals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halide
In chemistry, a halide (rarely halogenide) is a binary chemical compound, of which one part is a halogen atom and the other part is an element or radical that is less electronegative (or more electropositive) than the halogen, to make a fluoride, chloride, bromide, iodide, astatide, or theoretically tennesside compound. The alkali metals combine directly with halogens under appropriate conditions forming halides of the general formula, MX (X = F, Cl, Br or I). Many salts are halides; the ''hal-'' syllable in ''halide'' and ''halite'' reflects this correlation. All Group 1 metals form halides that are white solids at room temperature. A halide ion is a halogen atom bearing a negative charge. The halide anions are fluoride (), chloride (), bromide (), iodide () and astatide (). Such ions are present in all ionic halide salts. Halide minerals contain halides. All these halides are colourless, high melting crystalline solids having high negative enthalpies of formation. Test ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alcan
Alcan was a Canadian mining company and aluminum manufacturer. It was founded in 1902 as the Northern Aluminum Company, renamed Aluminum Company of Canada in 1925, and Alcan Aluminum in 1966. It took the name Alcan Incorporated in 2001. During that time, it grew to become one of the world's largest aluminum manufacturers. Alcan was purchased by Australian-British multinational Rio Tinto for $38 billion in 2007, becoming Rio Tinto Alcan Inc. in 2008. It was headquartered in Montreal, in its Maison Alcan complex. History The Northern Aluminum Company Limited was founded in 1902, in Shawinigan, Quebec, as part of the Pittsburgh Reduction Company. In 1913, the company opened a kitchen utensil production plant and foundry in Toronto. It opened a rolling mill in the plant a few years later. During World War I (1914–18), aluminum production increased to 131,000 tonnes from 69,000. In 1925, the company was renamed the Aluminum Company of Canada. The Aluminum Company of Canada was ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium Chloride
Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula . It forms hexahydrate with the formula , containing six water molecules of hydration. Both are colourless crystals, but samples are often contaminated with iron(III) chloride, giving a yellow color. The anhydrous material is important commercially. It has a low melting and boiling point. It is mainly produced and consumed in the production of aluminium metal, but large amounts are also used in other areas of the chemical industry. The compound is often cited as a Lewis acid. It is an example of an inorganic compound that reversibly changes from a polymer to a monomer at mild temperature. Structure Anhydrous adopts three structures, depending on the temperature and the state (solid, liquid, gas). Solid has a sheet-like layered structure with cubic close-packed chloride ions. In this framework, the Al centres exhibit octahedral coordination geometry. In contrast, has a more mol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Disproportionation
In chemistry, disproportionation, sometimes called dismutation, is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation states. More generally, the term can be applied to any desymmetrizing reaction of the following type, regardless of whether it is a redox or some other type of process: :2A -> A' + A'' Examples *Mercury(I) chloride disproportionates upon UV-irradiation: :Hg2Cl2 → Hg + HgCl2 *Phosphorous acid disproportionates upon heating to give phosphoric acid and phosphine: :4 → 3 H3PO4 + PH3 *Desymmetrizing reactions are sometimes referred to as disproportionation, as illustrated by the thermal degradation of bicarbonate: :2 → + H2CO3 :The oxidation numbers remain constant in this acid-base reaction. This process is also called autoionization. *Another variant on disproportionation is radical disproportionation, in which two radicals form an alkene and an alkane. : Reverse r ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Interstellar Medium
In astronomy, the interstellar medium is the matter and radiation that exist in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as dust and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic space. The energy that occupies the same volume, in the form of electromagnetic radiation, is the interstellar radiation field. The interstellar medium is composed of multiple phases distinguished by whether matter is ionic, atomic, or molecular, and the temperature and density of the matter. The interstellar medium is composed, primarily, of hydrogen, followed by helium with trace amounts of carbon, oxygen, and nitrogen. The thermal pressures of these phases are in rough equilibrium with one another. Magnetic fields and turbulent motions also provide pressure in the ISM, and are typically more important, dynamically, than the thermal pressure is. In the interstellar medium, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Astronomy And Astrophysics
''Astronomy & Astrophysics'' is a monthly peer-reviewed scientific journal covering theoretical, observational, and instrumental astronomy and astrophysics. The journal is run by a Board of Directors representing 27 sponsoring countries plus a representative of the European Southern Observatory. The journal is published by EDP Sciences and the editor-in-chief is . History Origins ''Astronomy and Astrophysics'' (A&A) was created as an answer to the publishing scenario found in Europe in the 1960s. At that time, multiple journals were being published in several countries around the continent. These journals usually had a limited number of subscribers, and published articles in languages other than English, resulting in a small number of citations compared to American and British journals. Starting in 1963, conversations between astronomers from European countries assessed the need for a common astronomical journal. On 8 April 1968, leading astronomers from Belgium, Denmark, Fran ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aluminium Monofluoride
Aluminium monofluoride, also known as fluoridoaluminium, is the chemical compound with the formula AlF. This elusive species is formed by the reaction between aluminium trifluoride and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled. Clusters derived from related aluminium(I) halides can be stabilized using specialized ligands. This molecule has been detected in the interstellar medium, where molecules are so dilute that intermolecular collisions are unimportant. See also *Aluminium monobromide *Aluminium monochloride *Aluminium monoiodide Aluminium monoiodide is an aluminium(I) compound with the chemical formula AlI. It is unstable at room temperature due to dismutation: :6AlI -> + 4Al It forms a cyclic adduct Al4I4(NEt3)4 with triethylamine. See also *Aluminium monofluoride * A ... References Aluminium(I) compounds Fluorides Metal halides {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
