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Arsenide Mineral
An arsenide mineral is a mineral that contains arsenide as its main anion. Arsenides are grouped with the sulfides in both the Dana and Strunz mineral classification systems. Examples * algodonite * domeykite * löllingite * nickeline * rammelsbergite * safflorite * skutterudite * sperrylite Sperrylite is a platinum arsenide mineral with the chemical formula and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in ... References {{mineral-stub ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ...
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Arsenide
In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides. Alkali metal and alkaline earth arsenides The group 1 alkali metals and the group 2, alkaline earth metals, form arsenides with isolated arsenic atoms. They form upon heating arsenic powder with excess sodium gives sodium arsenide (Na3As). The structure of Na3As is complex with unusually short Na–Na distances of 328–330 pm which are shorter than in sodium metal. This short distance indicates the complex bonding in these simple phases, i.e. they are not simply salts of As3− anion, for example. The compound LiAs, has a metallic lustre and electrical conductivity indicating some metallic bonding. These compounds are mainly of academic interest. For example, "sodium arsenide" is a structural mo ...
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Anion
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ...
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Algodonite
Algodonite is a copper arsenide mineral with formula: Cu6As. It is a gray white metallic mineral crystallizing in the hexagonal system. It has a Mohs hardness of 4 and a specific gravity of 8.38 - 8.72. It was first described in 1857 from the Algodones silver mine, Coquimbo, Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a .... References Copper minerals Arsenide minerals Hexagonal minerals Minerals in space group 194 {{Mineral-stub ...
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Domeykite
Domeykite is a copper arsenide mineral, Cu3As. It crystallizes in the isometric system, although crystals are very rare. It typically forms as irregular masses or botryoidal forms. It is an opaque, white to gray (weathers brassy) metallic mineral with a Mohs hardness of 3 to 3.5 and a specific gravity of 7.2 to 8.1 It was first described in 1845 in the Algodones mines, Coquimbo, Chile. It was named after Polish mineralogist Ignacy Domeyko (1802–1889) by Wilhelm Haidinger. Uses Domeykite, being a minor copper ore is used for obtaining copper. It can also be polished and used for ornamental purposes. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A * Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbachite: Cu2+Mn3+6O8SiO4 – German mineralogist I ... References Copper(I) minerals Arsenide minerals Cub ...
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Löllingite
Loellingite, also spelled löllingite, is an iron arsenide mineral with formula FeAs2. It is often found associated with arsenopyrite (FeAsS) from which it is hard to distinguish. Cobalt, nickel and sulfur substitute in the structure. The orthorhombic lollingite group includes the nickel iron arsenide rammelsbergite and the cobalt iron arsenide safflorite. Leucopyrite is an old synonym for loellingite. It forms opaque silvery white orthorhombic prismatic crystals often exhibiting crystal twinning. It also occurs in anhedral masses and tarnishes on exposure to air. It has a Mohs hardness of 5.5 to 6 and a quite high specific gravity of 7.1 to 7.5. It becomes magnetic after heating. Loellingite was first described in 1845 at the Lölling district in Carinthia, Austria, for which it was named. It occurs in mesothermal ore deposits associated with skutterudite, native bismuth, nickeline, nickel-skutterudite, siderite and calcite. It has also been reported from pegmatite A pegma ...
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Nickeline
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly. Small quantities of sulfur, iron and cobalt are usually present, and sometimes the arsenic is largely replaced by antimony. This last forms an isomorphous series with breithauptite (nickel antimonide). Etymology and history Medieval miners looking for copper in the German Erzgebirge ("Ore Mountains") would sometimes find a red mineral, superficially resembling copper ore. Upon attempting extraction, no copper was produced, and subsequently, the miners would be afflicted with mysterious illness. They blamed a mischievous sprite of German mythology, Nickel (similar to ''Old Nick'') for besetting the copper (German: Kupfer). This German equivalent of "copper-nickel" was used as early as 1694 (other old German synonyms are ''Rotnickelkies'' and ''Arsennickel' ...
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Rammelsbergite
Rammelsbergite is a nickel arsenide mineral with formula NiAs2. It forms metallic silvery to tin white to reddish orthorhombic prismatic crystals, and is usually massive in form. It has a Mohs hardness of 5.5 and a specific gravity of 7.1. It was first described in 1854 from its type locality in the Schneeberg District in Saxony, Germany. It was named after the German chemist and mineralogist, Karl Friedrich August Rammelsberg (1813–1899). It occurs as a hydrothermal mineral in medium temperature veins association with skutterudite, safflorite, lollingite, nickeline, native bismuth, native silver, algodonite, domeykite and uraninite. See also * List of minerals named after people This is a list of minerals named after people. The chemical composition follows name. A *Abelsonite: C31H32N4Ni – American physicist Philip Hauge Abelson (1913–2004)alfred *Abswurmbachite: Cu2+Mn3+6O8SiO4 – German mineralogist I ... References Mineral Galleries* Nickel miner ...
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Safflorite
Safflorite is a rare cobalt iron arsenide mineral with the chemical formula . ''Pure'' safflorite is , but iron is virtually always present. Safflorite is a member of the three-way substitution series of arsenides known as the loellingite or loellingite group. More than fifty percent iron makes the mineral loellingite whereas more than fifty percent nickel and the mineral is rammelsbergite. A parallel series of antimonide minerals exist. Safflorite along with the other minerals crystallize in the orthorhombic system forming opaque gray to white massive to radiating forms, Clinosafflorite has a monoclinic symmetry. It has a mohs hardness of 4.5 and a specific gravity of 6.9 to 7.3. Twinning is common and star shaped twins are frequently found. It was first described in 1835 from the Schneeberg District, Erzgebirge, Saxony, Germany. Safflorite occurs with other arsenide minerals as an accessory in silver mining districts. It alters to the arsenate erythrite Erythrite or red ...
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Skutterudite
Named after Skuterudåsen, a hill in Modum, Norway, skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula subscript of 2–3. High nickel varieties are referred to as nickel-skutterudite, previously chloanthite. It is a hydrothermal ore mineral found in moderate to high temperature veins with other Ni-Co minerals. Associated minerals are arsenopyrite, native silver, erythrite, annabergite, nickeline, cobaltite, silver sulfosalts, native bismuth, calcite, siderite, barite and quartz. It is mined as an ore of cobalt and nickel with a by-product of arsenic. The crystal structure of this mineral has been found to be exhibited by several compounds with important technological uses. The mineral has a bright metallic luster, and is tin white or light steel gray in color with a black streak. The specific gravity is 6.5 and the hardness is 5.5–6. I ...
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Sperrylite
Sperrylite is a platinum arsenide mineral with the chemical formula and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6 - 7 and a very high specific gravity of 10.6. It was discovered by Francis Louis Sperry, an American chemist, in 1889 at Sudbury. The most important occurrence of sperrylite is in the nickel ore deposit of Sudbury Basin in Ontario, Canada. It also occurs in the layered igneous complex of the Bushveld region of South Africa and the Oktyabr'skoye copper-nickel deposit of the Eastern-Siberian Region, Russia. Geologic occurrence Sperrylite is the most common platinum mineral, it generally occurs with a wide array of other unusual minerals, including cooperite [], laurite [], kotulskite [], merenskyite [], iridium-osmium (Ir-Os) alloys, sudburyite [], omeiite [], testibio ...
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