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Zirconium(IV) Fluoride
Zirconium(IV) fluoride ( Zr F4) is an inorganic chemical compound. It is a component of ZBLAN fluoride glass. It is insoluble in water. It is the main component of fluorozirconate glasses. Three crystalline phases of ZrF4 have been reported, α (monoclinic), β (tetragonal, Pearson symbol tP40, space group P42/m, No 84) and γ (unknown structure). β and γ phases are unstable and irreversibly transform into the α phase at 400 °C. Zirconium fluoride is used as a zirconium source in oxygen-sensitive applications, e.g. metal production. Zirconium fluoride can be purified by distillation or sublimation. Conditions/substances to avoid are: moisture, active metals, acids and oxidizing agents. Zirconium fluoride in a mixture with other fluorides is a coolant for molten salt reactors. In the mixture with sodium fluoride it is a candidate coolant for the Advanced High-Temperature Reactor. Together with uranium salt, zirconium fluoride can be a component of fuel-coolant in molt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below org ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list was complete was only ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aircraft Reactor Experiment
The Aircraft Reactor Experiment (ARE) was an experimental nuclear reactor designed to test the feasibility of fluid-fuel, high-temperature, high-power-density reactors for the propulsion of supersonic aircraft. It operated between November 8-12, 1954 at the Oak Ridge National Laboratory (ORNL) with a maximum sustained power of 2.5 megawatts (MW), and generated a total of 96 MW-hours of energy. The ARE was the first reactor to use circulating molten salt fuel. The hundreds of engineers and scientists working on ARE provided technical data, facilities, equipment, and experience that enabled the broader development of molten salt reactors as well as liquid metal cooled reactors. Background The concept of nuclear-powered aircraft was first formally studied in May 1946 by the US Army Air Forces. It was supposed that the unique characteristics of nuclear power could be applied to long-range supersonic flight, which was considered highly valuable in terms of military strategy. Challe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranium Tetrafluoride
Uranium tetrafluoride is the inorganic compound with the formula UF4. It is a green solid with an insignificant vapor pressure and low solubility in water. Uranium in its tetravalent (uranous) state is important in various technological processes. In the uranium refining industry it is known as green salt. Production UF4 is prepared from UO2 in a fluidized bed by reaction with HF. The UO2 is derived from mining operations. Around 60,000 tonnes per year are prepared in this way annually. A common impurity is UO2F2. UF4 is susceptible to hydrolysis as well. UF4 is formed by the reaction of UF6 with hydrogen gas in a vertical tube-type reactor. UF4 is less stable than the uranium oxides and reacts slowly with moisture at ambient temperature, forming UO2 and HF, the latter of which is very corrosive and toxic; it is thus less favourable for long-term disposal. The bulk density of UF4 varies from about 2.0 g/cm3 to about 4.5 g/cm3 depending on the production process and the prop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Advanced High-Temperature Reactor
A high-temperature gas-cooled reactor (HTGR), is a nuclear reactor that uses a graphite moderator with a once-through uranium fuel cycle. The HTGR is a type of high-temperature reactor (HTR) that can conceptually have an outlet temperature of . The reactor core can be either a "prismatic block" (reminiscent of a conventional reactor core) or a " pebble-bed" core. The high temperatures enable applications such as process heat or hydrogen production via the thermochemical sulfur–iodine cycle. The HTR is the predecessor of the Very-high-temperature reactor (VHTR), one of the future Generation IV reactor-models, which initially would work with temperatures of 750 to 950 °C. Overview The HTGR is a type of high-temperature reactor that conceptually can reach high outlet temperatures (up to 750 °C). There are two main types of HTGRs: pebble bed reactors (PBR) and prismatic block reactors (PMR).The prismatic block reactor refers to a prismatic block core configuration ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Fluoride
Sodium fluoride (NaF) is an inorganic compound with the formula . It is used in trace amounts in the fluoridation of drinking water, in toothpaste, in metallurgy, and as a flux. It is a colorless or white solid that is readily soluble in water. It is a common source of fluoride in the production of pharmaceuticals and is used to prevent dental cavities. In 2020, it was the 265th most commonly prescribed medication in the United States, with more than 1million prescriptions. Uses Dental caries Fluoride salts are often added to municipal drinking water (as well as to certain food products in some countries) for the purpose of maintaining dental health. The fluoride enhances the strength of teeth by the formation of fluorapatite, a naturally occurring component of tooth enamel. Although sodium fluoride is used to fluoridate water and is the standard by which other water-fluoridation compounds are gauged, hexafluorosilicic acid (H2SiF6) and its salt sodium hexafluorosilica ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molten Salt Reactor
A molten salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a molten salt mixture. Only two MSRs have ever operated, both research reactors in the United States. The 1950's Aircraft Reactor Experiment was primarily motivated by the compact size that the technique offers, while the 1960's Molten-Salt Reactor Experiment aimed to prove the concept of a nuclear power plant which implements a thorium fuel cycle in a breeder reactor. Increased research into Generation IV reactor designs began to renew interest in the technology, with multiple nations having projects, and , China is on the verge of starting its TMSR-LF1 thorium MSR. MSRs are considered safer than conventional reactors because they operate with fuel already in a molten state, and in some designs in the event of an emergency, the fuel mixture is designed to drain from the core to a containment vessel where it will solidify in fuel drain tanks. This pre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coolant
A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosion of the cooling system. Some applications also require the coolant to be an electrical insulator. While the term "coolant" is commonly used in automotive and HVAC applications, in industrial processing heat-transfer fluid is one technical term more often used in high temperature as well as low-temperature manufacturing applications. The term also covers cutting fluids. Industrial cutting fluid has broadly been classified as water-soluble coolant and neat cutting fluid. Water-soluble coolant is oil in water emulsion. It has varying oil content from nil oil (synthetic coolant). This coolant can either keep its phase and stay liquid or gaseous, or can undergo a phase transition, with the latent heat adding to the cooling efficiency. The lat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluoride
Fluoride (). According to this source, is a possible pronunciation in British English. is an inorganic, monatomic anion of fluorine, with the chemical formula (also written ), whose salts are typically white or colorless. Fluoride salts typically have distinctive bitter tastes, and are odorless. Its salts and minerals are important chemical reagents and industrial chemicals, mainly used in the production of hydrogen fluoride for fluorocarbons. Fluoride is classified as a weak base since it only partially associates in solution, but concentrated fluoride is corrosive and can attack the skin. Fluoride is the simplest fluorine anion. In terms of charge and size, the fluoride ion resembles the hydroxide ion. Fluoride ions occur on Earth in several minerals, particularly fluorite, but are present only in trace quantities in bodies of water in nature. Nomenclature Fluorides include compounds that contain ionic fluoride and those in which fluoride does not dissociate. The nom ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizing Agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an Redox, oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequence of database operations that satisfies the ACID properties (which can be perceived as a single logical operation on the data) is called a ''transaction''. For example, a transfer of funds from one bank account to another, even involving multiple changes such as debiting one account and crediting another, is a single transaction. In 1983, Andreas Reuter and Theo Härder coined the acronym ''ACID'', building on earlier work by Jim Gray who named atomicity, consistency, and durability, but not isolation, when characterizing the transaction concept. These four properties are the major guarantees of the transaction paradigm, which has influenced many aspects of development in database systems. According to Gray and Reuter, the IBM Informa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Moisture
Moisture is the presence of a liquid, especially water, often in trace amounts. Small amounts of water may be found, for example, in the air (humidity), in foods, and in some commercial products. Moisture also refers to the amount of water vapor present in the air. Moisture control in products Control of moisture in products can be a vital part of the process of the product. There is a substantial amount of moisture in what seems to be dry matter. Ranging in products from cornflake cereals to washing powders, moisture can play an important role in the final quality of the product. There are two main aspects of concern in moisture control in products: allowing too much moisture or too little of it. For example, adding some water to cornflake cereal, which is sold by weight, reduces costs and prevents it from tasting too dry, but adding too much water can affect the crunchiness of the cereal and the freshness because water content contributes to bacteria growth. Water content o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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