Ytterbium(III) Iodide
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Ytterbium(III) Iodide
Ytterbium(III) iodide is one of ytterbium's iodides, with the chemical formula of YbI3. Preparation Ytterbium(III) iodide can be prepared by reacting metallic ytterbium with iodine at 500°C with a 30 atm pressure: : 2 Yb + 3 I2 → 2 YbI3 Ytterbium(III) oxide, ytterbium(III) hydroxide or ytterbium(III) carbonate can react with hydroiodic acid to obtain ytterbium(III) iodide in aqueous solution: : Yb2O3 + 6 HI → 2 YbI3 + 3 H2O : Yb(OH)3 + 3 HI → YbI3 + 3 H2O : Yb2(CO3)3 + 6 HI → 2 YbI3 + 3 H2O + 3 CO2 The ytterbium(III) iodide hydrate crystallized from the solution can be heated with ammonium iodide to obtain the anhydrous form. Reactions Ytterbium(III) iodide decomposes to ytterbium(II) iodide Ytterbium(II) iodide is an iodide of ytterbium, with the chemical formula of YbI2. It is a yellow solid. Preparation Ytterbium(II) iodide can be prepared by heating ytterbium(III) iodide: :\mathrm It can also be prepared by reacting metalli ... upon heating: :2 YbI ...
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Ytterbium
Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides. In 1878, the Swiss chemist Jean Charles Galissard de Marignac separated from the rare earth "erbia" another independent component, which he called " ytterbia", for Ytterby, the village in Sweden near where he found the new component of erbium. He suspected that ytterbia was a compound of a new element that he called "ytterbium" (in total, four elements were ...
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Iodide
An iodide ion is the ion I−. Compounds with iodine in formal oxidation state −1 are called iodides. In everyday life, iodide is most commonly encountered as a component of iodized salt, which many governments mandate. Worldwide, iodine deficiency affects two billion people and is the leading preventable cause of intellectual disability. Structure and characteristics of inorganic iodides Iodide is one of the largest monatomic anions. It is assigned a radius of around 206 picometers. For comparison, the lighter halides are considerably smaller: bromide (196 pm), chloride (181 pm), and fluoride (133 pm). In part because of its size, iodide forms relatively weak bonds with most elements. Most iodide salts are soluble in water, but often less so than the related chlorides and bromides. Iodide, being large, is less hydrophilic compared to the smaller anions. One consequence of this is that sodium iodide is highly soluble in acetone, whereas sodium chloride is not. T ...
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Chemical Formula
In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and ''plus'' (+) and ''minus'' (−) signs. These are limited to a single typographic line of symbols, which may include Subscript and superscript, subscripts and superscripts. A chemical formula is not a chemical nomenclature, chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae. The simplest types of chemical formulae are called ''empirical formulae'', which use letters and numbers ind ...
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Iodine
Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a violet gas at . The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek 'violet-coloured'. Iodine occurs in many oxidation states, including iodide (I−), iodate (), and the various periodate anions. It is the least abundant of the stable halogens, being the sixty-first most abundant element. As the heaviest essential mineral nutrient, iodine is required for the synthesis of thyroid hormones. Iodine deficiency affects about two billion people and is the leading preventable cause of intellectual disabilities. The dominant producers of iodine today are Chile and Japan. Due to its high atomic number and ease of attachment to organic compound ...
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Ytterbium(III) Oxide
Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It has the "rare-earth C-type sesquioxide" structure which is related to the fluorite structure with one quarter of the anions removed, leading to ytterbium atoms in two different six coordinate (non-octahedral) environments. Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford Science Publications Uses * Colorant for glasses and enamels * Dopant for garnet crystals in lasers * Optical fibers See also * Active laser medium The active laser medium (also called gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a h ... References External links Information at WebElements Ytterbium compounds Sesquioxides {{inorganic-compound-stub ...
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Ytterbium(III) Hydroxide
Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides. In 1878, the Swiss chemist Jean Charles Galissard de Marignac separated from the rare earth "erbia" another independent component, which he called " ytterbia", for Ytterby, the village in Sweden near where he found the new component of erbium. He suspected that ytterbia was a compound of a new element that he called "ytterbium" (in total, four elements ...
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Ytterbium(III) Carbonate
Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides. In 1878, the Swiss chemist Jean Charles Galissard de Marignac separated from the rare earth "erbia" another independent component, which he called "ytterbia", for Ytterby, the village in Sweden near where he found the new component of erbium. He suspected that ytterbia was a compound of a new element that he called "ytterbium" (in total, four elements were na ...
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Hydroiodic Acid
Hydroiodic acid (or hydriodic acid) is an aqueous solution of hydrogen iodide (HI). It is a strong acid, one that is ionized completely in an aqueous solution. It is colorless. Concentrated solutions are usually 48% to 57% HI. Reactions Hydroiodic acid reacts with oxygen in air to give iodine: :4 HI + O2 → 2 + 2 I2 Like other hydrogen halides, hydroiodic acid adds to alkenes to give alkyl iodides. It can also be used as a reducing agent, for example in the reduction of aromatic nitro compounds to anilines. Cativa process The Cativa process is a major end use of hydroiodic acid, which serves as a co-catalyst for the production of acetic acid by the carbonylation of methanol. Illicit uses Hydroiodic acid is listed as a U.S. Federal DEA List I Chemical, owing to its use as a reducing agent related to the production of methamphetamine from ephedrine Ephedrine is a central nervous system (CNS) stimulant that is often used to prevent low blood pressure during anesthe ...
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Aqueous Solution
An aqueous solution is a solution in which the solvent is water. It is mostly shown in chemical equations by appending (aq) to the relevant chemical formula. For example, a solution of table salt, or sodium chloride (NaCl), in water would be represented as . The word ''aqueous'' (which comes from ''aqua'') means pertaining to, related to, similar to, or dissolved in, water. As water is an excellent solvent and is also naturally abundant, it is a ubiquitous solvent in chemistry. Since water is frequently used as the solvent in experiments, the word solution refers to an aqueous solution, unless the solvent is specified. A ''non-aqueous solution'' is a solution in which the solvent is a liquid, but is not water. (See also Solvent and Inorganic nonaqueous solvent.) Characteristics Substances that are ''hydrophobic'' ('water-fearing') do not dissolve well in water, whereas those that are ''hydrophilic'' ('water-friendly') do. An example of a hydrophilic substance is sodium chlo ...
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Ammonium Iodide
Ammonium iodide is the chemical compound NH4I. It is used in photographic chemicals and some medications.Holleman, A. F.; Wiberg, E. ''Inorganic Chemistry'' Academic Press: San Diego, 2001. . It can be prepared by the action of hydroiodic acid on ammonia. It is easily soluble in water, from which it crystallizes in cubes. It is also soluble in ethanol. It gradually turns yellow on standing in moist air, owing to decomposition with liberation of iodine. Preparation Ammonium iodide can be made in lab by reacting ammonia or ammonium hydroxide with hydroiodic acid or hydrogen iodide gas: : NH3 + HI → NH4I : NH4OH + HI → NH4I + H2O It is also formed by the decomposition of ammoniated nitrogen triiodide Nitrogen triiodide is an inorganic compound with the formula N I3. It is an extremely sensitive contact explosive: small quantities explode with a loud, sharp snap when touched even lightly, releasing a purple cloud of iodine vapor; it can even b ... (an explosive). Referenc ...
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Ytterbium(II) Iodide
Ytterbium(II) iodide is an iodide of ytterbium, with the chemical formula of YbI2. It is a yellow solid. Preparation Ytterbium(II) iodide can be prepared by heating ytterbium(III) iodide: :\mathrm It can also be prepared by reacting metallic ytterbium with 1,2-diiodoethane in tetrahydrofuran: :\mathrm Although the reaction takes place at room temperature, due to the sensitivity of the reagents it is necessary to work anhydrous and under inert gas. Otherwise, if oxygen is present, rapid oxidation to ytterbium(III) takes place. This can be visually recognized by the color change from green to yellow solution. Properties and uses Ytterbium(II) iodide is a yellow solid that is very sensitive to air and moisture and is rapidly oxidized to ytterbium(III). It reacts with water to produce hydrogen gas and basic iodides, and reacts violently with acids. Ytterbium(II) iodide sinters at 0.01 Torr from about 780 °C and gives a viscous melt at about 920 °C. It begin ...
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Ytterbium(III) Compounds
Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides. In 1878, the Swiss chemist Jean Charles Galissard de Marignac separated from the rare earth "erbia" another independent component, which he called "ytterbia", for Ytterby, the village in Sweden near where he found the new component of erbium. He suspected that ytterbia was a compound of a new element that he called "ytterbium" (in total, four elements were na ...
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