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YLF
Neodymium-doped yttrium lithium fluoride (Nd:YLF) is a lasing medium for arc lamp- pumped and diode-pumped solid-state lasers. The YLF crystal (LiYF4) is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053 nm. It is used in Q-switched systems in part due to its relatively long fluorescence lifetime. As with Nd:YAG lasers, harmonic generation is frequently employed with Q-switched Nd:YLF to produce shorter wavelengths. A common application of frequency-doubled Nd:YLF pulses is to pump ultrafast Ti:Sapphire chirped-pulse amplifiers. Neodymium-doped YLF can provide higher pulse energies than Nd:YAG for repetition rates of a few kHz or less. Compared to Nd:YAG, the Nd:YLF crystal is very brittle and fractures easily. It is also slightly water-soluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of t ...
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Yttrium Lithium Fluoride
Yttrium lithium fluoride (LiYF4, sometimes abbreviated YLF) is a birefringent crystal, typically doped with neodymium or praseodymium and used as a gain medium in solid-state lasers. Yttrium is the substitutional element in LiYF4. The hardness of YLF is significantly lower than other commons crystalline laser media, i.e. yttrium aluminium garnet. References See also *Neodymium-doped yttrium lithium fluoride Neodymium-doped yttrium lithium fluoride (Nd:YLF) is a lasing medium for arc lamp- pumped and diode-pumped solid-state lasers. The YLF crystal (LiYF4) is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053&nbs ... Optical materials Crystals Yttrium compounds Lithium compounds Fluorides Metal halides {{crystal-stub ...
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Laser Gain Media
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The first laser was built in 1960 by Theodore H. Maiman at Hughes Research Laboratories, based on theoretical work by Charles Hard Townes and Arthur Leonard Schawlow. A laser differs from other sources of light in that it emits light which is ''coherent''. Spatial coherence allows a laser to be focused to a tight spot, enabling applications such as laser cutting and lithography. Spatial coherence also allows a laser beam to stay narrow over great distances (collimation), enabling applications such as laser pointers and lidar (light detection and ranging). Lasers can also have high temporal coherence, which allows them to emit light with a very narrow spectrum. Alternatively, temporal coherence can be used to produce ultrashort pulses of light w ...
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Active Laser Medium
The active laser medium (also called gain medium or lasing medium) is the source of optical gain within a laser. The gain results from the stimulated emission of photons through electronic or molecular transitions to a lower energy state from a higher energy state previously populated by a pump source. Examples of active laser media include: * Certain crystals, typically doped with rare-earth ions (e.g. neodymium, ytterbium, or erbium) or transition metal ions (titanium or chromium); most often yttrium aluminium garnet ( Y3 Al5 O12), yttrium orthovanadate (YVO4), or sapphire (Al2O3); and not often Caesium cadmium bromide ( Cs Cd Br3) (Solid-state lasers) * Glasses, e.g. silicate or phosphate glasses, doped with laser-active ions; * Gases, e.g. mixtures of helium and neon (HeNe), nitrogen, argon, krypton, carbon monoxide, carbon dioxide, or metal vapors; (Gas lasers) * Semiconductors, e.g. gallium arsenide (GaAs), indium gallium arsenide (InGaAs), or gallium nitride (GaN). * Liqui ...
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Brittle
A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a sharp snapping sound. When used in materials science, it is generally applied to materials that fail when there is little or no plastic deformation before failure. One proof is to match the broken halves, which should fit exactly since no plastic deformation has occurred. Brittleness in different materials Polymers Mechanical characteristics of polymers can be sensitive to temperature changes near room temperatures. For example, poly(methyl methacrylate) is extremely brittle at temperature 4˚C, but experiences increased ductility with increased temperature. Amorphous polymers are polymers that can behave differently at different temperatures. They may behave like a glass at low temperatures (the glassy ...
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Yttrium Compounds
An yttrium compound is a chemical compound containing yttrium (element symbol: Y). Among these compounds, yttrium generally has a +3 valence. The solubility properties of yttrium compounds are similar to those of the lanthanides. For example oxalates and carbonates are hardly soluble in water, but soluble in excess oxalate or carbonate solutions as complexes are formed. Sulfates and double sulfates are generally soluble. They resemble the "yttrium group" of heavy lanthanide elements. Chalcogenides The oxides and hydroxides of yttrium are yttrium oxide (Y2O3) and yttrium hydroxide (Y(OH)3), respectively, and they are both white solids which are hardly soluble in water. Among them, yttrium oxide can be prepared by heating yttrium carbonate or yttrium oxalate. Alternatively the oxychloride, Y3O4Cl can be heated in air to yield the oxide. Yttrium hydroxide can be precipitated by the reaction of soluble yttrium compounds with sodium hydroxide or ammonia, and can also be obtained ...
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Neodymium Compounds
Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.Burke M.W. (1996) Lighting II: Sources. In: Image Acquisition. Springer, Dordrecht. File:Neodymium tl1.jpg, Neodymium compounds in fluorescent tube light—from left to right, the sulfate, nitrate, and chloride File:Neodymium fluorescent1.jpg, Neodymium compounds in compact fluorescent lamp light File:Neodymium daylight1.jpg, Neodymium compounds in normal daylight Halides Neodymium can form four trihalides of the form NdX3. It reacts vigorously with all the stable halogens: : violet substance: mauve substance: violet substance: green substance The dihalides NdCl2 and NdBr2 are dark green solids,Georg ...
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Crystals
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macroscopic single crystals are usually identifiable by their geometrical shape, consisting of flat faces with specific, characteristic orientations. The scientific study of crystals and crystal formation is known as crystallography. The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. The word ''crystal'' derives from the Ancient Greek word (), meaning both "ice" and "rock crystal", from (), "icy cold, frost". Examples of large crystals include snowflakes, diamonds, and table salt. Most inorganic solids are not crystals but polycrystals, i.e. many microscopic crystals fused together into a single solid. Polycrystals include most metals, rocks, ceramics, and ice. A third category of s ...
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Solubility
In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubility of a substance in a specific solvent is generally measured as the concentration of the solute in a saturated solution, one in which no more solute can be dissolved. At this point, the two substances are said to be at the solubility equilibrium. For some solutes and solvents, there may be no such limit, in which case the two substances are said to be " miscible in all proportions" (or just "miscible"). The solute can be a solid, a liquid, or a gas, while the solvent is usually solid or liquid. Both may be pure substances, or may themselves be solutions. Gases are always miscible in all proportions, except in very extreme situations,J. de Swaan Arons and G. A. M. Diepen (1966): "Gas—Gas Equilibria". ''Journal of Chemical Physics'', ...
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Harmonic Generation
Harmonic generation (HG, also called multiple harmonic generation) is a nonlinear optical process in which n photons with the same frequency interact with a nonlinear material, are "combined", and generate a new photon with n times the energy of the initial photons (equivalently, n times the frequency and the wavelength divided by n). General process In a medium having a substantial nonlinear susceptibility, harmonic generation is possible. Note that for even orders (n = 2,4,\dots), the medium must have no center of symmetry (non-centrosymmetrical). Because the process requires that many photons are present at the same time and at the same place, the generation process has a low probability to occur, and this probability decreases with the order n. To generate efficiently, the symmetry of the medium must allow the signal to be amplified (through phase matching, for instance), and the light source must be intense and well-controlled spatially (with a collimated laser) and temporal ...
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Sapphire Chirped-pulse Amplifiers
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphirus" from the Greek "sappheiros", which referred to lapis lazuli. It is typically blue, but natural "fancy" sapphires also occur in yellow, purple, orange, and green colors; "parti sapphires" show two or more colors. Red corundum stones also occur, but are called rubies rather than sapphires. Pink-colored corundum may be classified either as ruby or sapphire depending on locale. Commonly, natural sapphires are cut and polished into gemstones and worn in jewelry. They also may be created synthetically in laboratories for industrial or decorative purposes in large crystal boules. Because of the remarkable hardness of sapphires 9 on the Mohs scale (the third hardest mineral, after diamond at 10 and moissanite at 9.5) sapphires are also u ...
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