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Xenon Dichloride
Xenon dichloride (XeCl2) is a xenon compound and the only known stable chloride of xenon. The compound can be prepared by using microwave discharges towards the mixture of xenon and chlorine, and it can be isolated from a condensate trap. One experiment tried to use xenon, chlorine and boron trichloride to produce XeCl2·BCl3, but only generated xenon dichloride. However, it is still doubtful whether xenon dichloride is a true compound or a Van der Waals molecule A Van der Waals molecule is a weakly bound complex of atoms or molecules held together by intermolecular attractions such as Van der Waals forces or by hydrogen bonds. The name originated in the beginning of the 1970s when stable molecular clust ... composed of a xenon atom and a chlorine molecule connected by a secondary bond. References Xenon(II) compounds Chlorides Nonmetal halides Van der Waals molecules {{Inorganic-compound-stub ...
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Noble Gas Compound
In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon. From the standpoint of chemistry, the noble gases may be divided into two groups: the relatively reactive krypton (ionisation energy 14.0  eV), xenon (12.1 eV), and radon (10.7 eV) on one side, and the very unreactive argon (15.8 eV), neon (21.6 eV), and helium (24.6 eV) on the other. Consistent with this classification, Kr, Xe, and Rn form compounds that can be isolated in bulk at or near standard temperature and pressure, whereas He, Ne, Ar have been observed to form true chemical bonds using spectroscopic techniques, but only when frozen into a noble gas matrix at temperatures of 40 K or lower, in supersonic jets of noble gas, or under extremely high pressures with metals. ...
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Chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167  pm) is much larger tha ...
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Xenon
Xenon is a chemical element with the symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the formation of xenon hexafluoroplatinate, the first noble gas compound to be synthesized. Xenon is used in flash lamps and arc lamps, and as a general anesthetic. The first excimer laser design used a xenon dimer molecule (Xe2) as the lasing medium, and the earliest laser designs used xenon flash lamps as pumps. Xenon is also used to search for hypothetical weakly interacting massive particles and as a propellant for ion thrusters in spacecraft. Naturally occurring xenon consists of seven stable isotopes and two long-lived radioactive isotopes. More than 40 unstable xenon isotopes undergo radioactive decay, and the isotope ratios of xenon are an important tool for studying the early history of the Solar System. Radioactive xenon-135 is ...
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Microwave Discharge
An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines. Electron ionization Electron ionization is widely used in mass spectrometry, particularly for organic molecules. The gas phase reaction producing electron ionization is :M + e^- -> M^ + 2e^- where M is the atom or molecule being ionized, e^- is the electron, and M^ is the resulting ion. The electrons may be created by an arc discharge between a cathode and an anode. An electron beam ion source (EBIS) is used in atomic physics to produce highly charged ions by bombarding atoms with a powerful electron beam. Its principle of operation is shared by the electron beam ion trap. Electron capture ionization Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A−•. The rea ...
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Condensate Trap
Condensate may refer to: * The liquid phase produced by the condensation of steam or any other gas * The product of a chemical condensation reaction, other than water * Natural-gas condensate, in the natural gas industry * ''Condensate'' (album), a 2011 album by The Original 7ven, the band formerly known as The Time Quantum physics * Canonical quantization or vacuum expectation value, in quantum field theory * Bose–Einstein condensate, a substance which occurs at very low temperatures in a system of bosons * Fermionic condensate, a substance which occurs at very low temperatures in a system of fermions * Gluon condensate, a non-perturbative property of the QCD vacuum Theoretical states * Color-glass condensate, an extreme type of matter theorized to exist in atomic nuclei traveling near the speed of light * Top quark condensate, an alternative theory to the Standard Model See also * Biomolecular condensate In biochemistry, biomolecular condensates are a class of li ...
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Chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However ...
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Boron Trichloride
Boron trichloride is the inorganic compound with the formula BCl3. This colorless gas is a reagent in organic synthesis. It is highly reactive toward water. Production and structure Boron reacts with halogens to give the corresponding trihalides. Boron trichloride is, however, produced industrially by direct chlorination of boron oxide and carbon at 501 °C. :B2O3 + 3 C + 3 Cl2 → 2 BCl3 + 3 CO The carbothermic reaction is analogous to the Kroll process for the conversion of titanium dioxide to titanium tetrachloride. In the laboratory BF3 reacted with AlCl3 gives BCl3 via halogen exchange. BCl3 is a trigonal planar molecule like the other boron trihalides, and has a bond length of 175pm. A degree of π-bonding has been proposed to explain the short B− Cl distance although there is some debate as to its extent. It does not dimerize, although NMR studies of mixtures of boron trihalides shows the presence of mixed halides. The absence of dimerisation contrasts with the t ...
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Van Der Waals Molecule
A Van der Waals molecule is a weakly bound complex of atoms or molecules held together by intermolecular attractions such as Van der Waals forces or by hydrogen bonds. The name originated in the beginning of the 1970s when stable molecular clusters were regularly observed in molecular beam microwave spectroscopy. Examples Examples of well-studied vdW molecules are Ar2, H2-Ar, H2O-Ar, benzene-Ar, (H2O)2, and (HF)2. Others include the largest diatomic molecule: He2 and LiHe. Supersonic beam spectroscopy In (supersonic) molecular beams temperatures are very low (usually less than 5 K). At these low temperatures Van der Waals (vdW) molecules are stable and can be investigated by microwave, far-infrared spectroscopy and other modes of spectroscopy. Also in cold equilibrium gases vdW molecules are formed, albeit in small, temperature dependent concentrations. Rotational and vibrational transitions in vdW molecules have been observed in gases, mainly by UV and IR spectro ...
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Van Der Waals Force
In molecular physics, the van der Waals force is a distance-dependent interaction between atoms or molecules. Unlike ionic or covalent bonds, these attractions do not result from a chemical electronic bond; they are comparatively weak and therefore more susceptible to disturbance. The van der Waals force quickly vanishes at longer distances between interacting molecules. Named after Dutch physicist Johannes Diderik van der Waals, the van der Waals force plays a fundamental role in fields as diverse as supramolecular chemistry, structural biology, polymer science, nanotechnology, surface science, and condensed matter physics. It also underlies many properties of organic compounds and molecular solids, including their solubility in polar and non-polar media. If no other force is present, the distance between atoms at which the force becomes repulsive rather than attractive as the atoms approach one another is called the van der Waals contact distance; this phenomenon resul ...
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Xenon(II) Compounds
Xenon is a chemical element with the Symbol (chemistry), symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Atmosphere of Earth, Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the formation of xenon hexafluoroplatinate, the first noble gas compound to be synthesized. Xenon is used in Flashtube#Xenon, flash lamps and xenon arc lamp, arc lamps, and as a general anaesthesia, general anesthetic. The first excimer laser design used a xenon Dimer (chemistry), dimer molecule (Xe2) as the Active laser medium, lasing medium, and the earliest laser designs used xenon flash lamps as Laser pumping, pumps. Xenon is also used to search for hypothetical weakly interacting massive particles and as a propellant for ion thrusters in spacecraft. Naturally occurring xenon consists of Isotopes of xenon, seven stable isotopes and two long-lived radioactive isotopes. More than 40 unstable xenon iso ...
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Chlorides
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167  pm) is much larger than ...
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Nonmetal Halides
In chemistry, a nonmetal is a chemical element that generally lacks a predominance of metallic properties; they range from colorless gases (like hydrogen) to shiny solids (like carbon, as graphite). The electrons in nonmetals behave differently from those in metals. With some exceptions, those in nonmetals are fixed in place, resulting in nonmetals usually being poor conductors of heat and electricity and brittle or crumbly when solid. The electrons in metals are generally free moving and this is why metals are good conductors and most are easily flattened into sheets and drawn into wires. Nonmetal atoms tend to attract electrons in chemical reactions and to form acidic compounds. Two nonmetals, hydrogen and helium, make up about 99% of ordinary matter in the observable universe by mass. Five nonmetallic elements, hydrogen, carbon, nitrogen, oxygen and silicon, largely make up the Earth's crust, atmosphere, oceans and biosphere. Most nonmetals have biological, technological ...
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