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Walter Haworth
Sir Walter Norman Haworth Fellow of the Royal Society, FRS (19 March 1883 – 19 March 1950) was a British chemist best known for his groundbreaking work on ascorbic acid (vitamin C) while working at the University of Birmingham. He received the 1937 Nobel Prize in Chemistry "for his investigations on carbohydrates and vitamin C". The prize was shared with Swiss chemist Paul Karrer for his work on other vitamins. Haworth worked out the correct structure of a number of sugars, and is known among organic chemists for his development of the Haworth projection that translates three-dimensional sugar structures into convenient two-dimensional graphical form. Academic career Having worked for some time from the age of fourteen in the local Ryland's linoleum factory managed by his father, he studied for and successfully passed the entrance examination to the University of Manchester in 1903 to study chemistry. He made this pursuit in spite of active discouragement by his parents. He ...
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White Coppice
White Coppice is a hamlet near Chorley, Lancashire, England. It was the most populated part of the township of Anglezarke in the 19th century. Close to the settlement in the early 19th century were quarries and small coal mines. The hamlet lies to the north of Anglezarke Reservoir in the Rivington reservoir chain built to provide water for Liverpool in the mid 19th century. To the south west is a hill known as Healey Nab. White Coppice had a cotton mill at the start of the Industrial Revolution. Its mill lodge provided water for a steam engine, and before that the mill was powered by a waterwheel on the Black Brook (Chorley), Black Brook. Around 1900 the mill was owned by Alfred Ephraim Eccles, a supporter of the Temperance movement. Notable residents * Walter Haworth was born here on 19 March 1883 and won a Nobel Prize in chemistry. * Henry Tate, Sir Henry Tate, 1st Baronet was born on 11 March 1819 in White Coppice. He was an English sugar merchant and philanthropist, note ...
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Chemist
A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe the properties they study in terms of quantities, with detail on the level of molecules and their component atoms. Chemists carefully measure substance proportions, chemical reaction rates, and other chemical properties. In Commonwealth English, pharmacists are often called chemists. Chemists use their knowledge to learn the composition and properties of unfamiliar substances, as well as to reproduce and synthesize large quantities of useful naturally occurring substances and create new artificial substances and useful processes. Chemists may specialize in any number of subdisciplines of chemistry. Materials scientists and metallurgists share much of the same education and skills with chemists. The work of chemists is often related to the ...
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Methyl Sulfate
Methyl bisulfate is a chemical compound with the molecular formula CH4O4S. This compound is the mono-methyl ester of sulfuric acid. The significance of methyl bisulfate is that it is an intermediate in the hydrolysis of the important reagent dimethyl sulfate, (CH3)2SO4: :(CH3)2SO4 + H2O → (CH3)HSO4 + CH3OH Methyl bisulfate is a strong acid: :(CH3)HSO4 → (CH3)SO4− + H+ Methyl bisulfate came into the public view in 1993 with the discovery that certain mercury compounds catalyze the conversion of methane to methylbisulfate in good yields with excellent selectivity in concentrated sulfuric acid. However, because of the toxicity and concerns with the use of mercury it wasn't until 1998 when platinum complexes were found that catalyze the reaction of CH4 by SO3 and O2 that it came into the limelight: :CH4 + SO3 + 1/2 O2 → (CH3)HSO4 This discovery pointed to a possible method for upgrading inexpensive and abundantly available methane (natural gas) into methanol, ...
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Ether
In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be classified into two varieties: if the alkyl or aryl groups are the same on both sides of the oxygen atom, then it is a simple or symmetrical ether, whereas if they are different, the ethers are called mixed or unsymmetrical ethers. A typical example of the first group is the solvent and anaesthetic diethyl ether, commonly referred to simply as "ether" (). Ethers are common in organic chemistry and even more prevalent in biochemistry, as they are common linkages in carbohydrates and lignin. Structure and bonding Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141  pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is ...
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Sir James Irvine
Sir James Colquhoun Irvine KBE JP PhD (Leipzig) DL DSc BSc FRS FRSE FEIS (9 May 1877 – 12 June 1952) was a British organic chemist and Principal and Vice-Chancellor of the University of St Andrews from 1921 until his death. As a research chemist, Irvine worked on the application of methylation techniques to carbohydrates, and isolated the first methylated sugars, trimethyl and tetramethyl glucose. Life Irvine was born in Glasgow to factory-owner John Irvine (a manufacturer of light-castings) and Mary Paton Colquhoun. He was educated at Allan Glen's School. He then studied at the Royal Technical College, Glasgow, before taking a Bachelor of Science in Chemistry at the University of St Andrews. From there, he went to the University of Leipzig, where he studied for a PhD under Ostwald and Wislicenus. Returning to St Andrews, he was awarded a Doctor of Science degree, and taught Chemistry there. He was appointed Professor of Chemistry in 1909 and Dean of Science in 1912. In ...
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Carbohydrate Chemistry
Carbohydrate chemistry is a subdiscipline of chemistry primarily concerned with the detection, synthesis, structure, and function of carbohydrates. Due to the general structure of carbohydrates, their synthesis is often preoccupied with the selective formation of glycosidic linkages and the selective reaction of hydroxyl groups; as a result, it relies heavily on the use of protecting groups. Monosaccharides Individual saccharide residues are termed monosaccharides. Carbohydrate synthesis Carbohydrate synthesis is a sub-field of organic chemistry concerned specifically with the generation of natural and unnatural carbohydrate structures. This can include the synthesis of monosaccharide residues or structures containing more than one monosaccharide, known as oligosaccharides. Glycosidic bond formation * Chemical glycosylation * Fischer glycosidation * Glycosyl halide * Koenigs-Knorr reaction Protecting groups * Carbohydrate acetalisation * Trimethylsilyl * Benzyl Ether * para ...
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University Of St Andrews
(Aien aristeuein) , motto_lang = grc , mottoeng = Ever to ExcelorEver to be the Best , established = , type = Public research university Ancient university , endowment = £117.7 million (2021) , budget = £286.6 million (2020–21) , chancellor = The Lord Campbell of Pittenweem , rector = Leyla Hussein , principal = Sally Mapstone , academic_staff = 1,230 (2020) , administrative_staff = 1,576 , students = () , undergrad = () , postgrad = () , doctoral = , other = , city = St Andrews , state = , country = Scotland , coordinates = , campus = College town , colours = United College, St Andrews St Mary's College School of Medicine S ...
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Royal Commission For The Exhibition Of 1851
The Royal Commission for the Exhibition of 1851 is an institution founded in 1850 to administer the international exhibition of 1851, officially called the Great Exhibition of the Works of Industry of all Nations. The Great Exhibition was held in The Crystal Palace in Hyde Park London, England. The enormous building was designed by Joseph Paxton for the Exhibition and construction was supervised by William Cubitt using a cast iron space frame for the glass panes, with wooden beams for flooring. The founding President of the Commission was Prince Albert of Saxe-Coburg and Gotha and its chief administrator was Henry Cole. The current President is Anne, Princess Royal. The exhibition was a great popular and financial success, and made a huge surplus of 186,000 pounds,or about 22 million pounds in today's money). An unusual decision was made to maintain the Royal Commission as a permanent administrative body and to use the profits for charitable purposes. Its revised Charter charge ...
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1851 Research Fellowship
The 1851 Research Fellowship is a scheme conducted by the Royal Commission for the Exhibition of 1851 to annually award a three-year research scholarship to approximately eight "young scientists or engineers of exceptional promise". The fellowship is open to all nationalities and fields of science, including physical or biological sciences, mathematics, applied science, and any branch of engineering. The fellowship can be held anywhere in the United Kingdom. Several other Fellowships are also awarded by the Royal Commission for the Exhibition of 1851, including the Research Fellowship in the Built Environment, Industrial Fellowships and the Research Fellowship in Design. Alumni The research fellowship known as the 1851 Exhibition Scholarship, has been awarded to numerous scientists and engineers over the years, many of whom have become leaders in their fields. Award recipients include: * Herbert E. Watson, Ramsey Professor in Chemical Engineering at University College London *Char ...
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Linoleum
Linoleum, sometimes shortened to lino, is a floor covering made from materials such as solidified linseed oil (linoxyn), Pine Resin, pine resin, ground Cork (material), cork dust, sawdust, and mineral fillers such as calcium carbonate, most commonly on a burlap or canvas backing. Pigments are often added to the materials to create the desired colour finish. Commercially, the material has been largely replaced by sheet vinyl flooring, although in the UK this is often still referred to as lino. The finest linoleum floors, known as "inlaid", are extremely durable, and are made by joining and inlaying solid pieces of linoleum. Cheaper patterned linoleum comes in different grades or gauges, and is printed with thinner layers which are more prone to wear and tear. High-quality linoleum is flexible and thus can be used in buildings where a more rigid material (such as Tile#Floor tiles, ceramic tile) would crack. History Linoleum was invented by Englishman Frederick Walton. In 1855, ...
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Haworth Projection
In chemistry, a Haworth projection is a common way of writing a structural formula to represent the cyclic structure of monosaccharides with a simple three-dimensional perspective. Haworth projection approximate the shapes of the actual molecules better for furanoses -which are in reality nearly planar- than for pyranoses which exist in solution in the chair conformation. Organic chemistry and especially biochemistry are the areas of chemistry that use the Haworth projection the most. The Haworth projection was named after the British chemist Sir Norman Haworth. A Haworth projection has the following characteristics: * Carbon is the implicit type of atom. In the example on the right, the atoms numbered from 1 to 6 are all carbon atoms. Carbon 1 is known as the anomeric carbon. * Hydrogen atoms on carbon are implicit. In the example, atoms 1 to 6 have extra hydrogen atoms not depicted. * A thicker line indicates atoms that are closer to the observer. In the example on the ...
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Vitamin
A vitamin is an organic molecule (or a set of molecules closely related chemically, i.e. vitamers) that is an Nutrient#Essential nutrients, essential micronutrient that an organism needs in small quantities for the proper functioning of its metabolism. Essential nutrients cannot be biosynthesis, synthesized in the organism, either at all or not in sufficient quantities, and therefore must be obtained through the Diet (nutrition), diet. Vitamin C can be synthesized by some species but not by others; it is not a vitamin in the first instance but is in the second. The term ''vitamin'' does not include the three other groups of essential nutrients: mineral (nutrient), minerals, essential fatty acids, and essential amino acids. Most vitamins are not single molecules, but groups of related molecules called vitamers. For example, there are eight vitamers of vitamin E: four tocopherols and four tocotrienols. Some sources list fourteen vitamins, by including choline, but major health ...
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