Waelz Process
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Waelz Process
The Waelz process is a method of recovering zinc and other relatively low boiling point metals from metallurgical waste (typically EAF flue dust) and other recycled materials using a rotary kiln (''waelz kiln''). The zinc enriched product is referred to as ''waelz oxide'', and the reduced zinc by product as ''waelz slag''. History and description The concept of using a rotary kiln for the recovery of Zinc by volatization dates to at least 1888. A process was patented by Edward Dedolph in 1910. Subsequently, the Dedpolph patent was taken up and developed by Metallgesellschaft (Frankfurt) with Chemische Fabrik Griesheim-Elektron but without leading to a production scale ready process. In 1923 the Krupp Grusonwerk independently developed a process (1923), named the ''Waelz process'' (from the German ''Waelzen'', a reference to the motion of the materials in the kiln); the two German firms later collaborated and improved the process marketing under the name ''Waelz-Gemeinschaft'' (Ger ...
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Zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It ...
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Rotary Kiln
A rotary kiln is a pyroprocessing device used to raise materials to a high temperature (calcination) in a continuous process. Materials produced using rotary kilns include: * Cement * Lime * Refractories * Metakaolin * Titanium dioxide * Alumina * Vermiculite * Iron ore pellets They are also used for roasting a wide variety of sulfide ores prior to metal extraction. Principle of operation The kiln is a cylindrical vessel, inclined slightly from the horizontal, which is rotated slowly about its longitudinal axis. The process feedstock is fed into the upper end of the cylinder. As the kiln rotates, material gradually moves down toward the lower end, and may undergo a certain amount of stirring and mixing. Hot gases pass along the kiln, sometimes in the same direction as the process material (co-current), but usually in the opposite direction (counter-current). The hot gases may be generated in an external furnace, or may be generated by a flame inside the kiln. Such a flam ...
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Metallgesellschaft
Metallgesellschaft AG was formerly one of Germany's largest industrial conglomerates based in Frankfurt. It had over 20,000 employees and revenues in excess of 10 billion US dollars. It had over 250 subsidiaries specializing in mining, specialty chemicals (Chemetall), commodity trading, financial services, and engineering (Lurgi AG, Lurgi). Henry Merton & Company, Ltd was previously a branch of the Metallgesellschaft. History Metallgesellschaft AG was incorporated in Frankfurt am Main in 1881 by Wilhelm Ralph Merton, his father Ralph Merton, and Leo Ellinger. Merton was responsible for business strategy, Ellinger for operations, and a cousin of Merton, Zachary Hochschild, for marketing and international activities. Their main competition were the two other large metal trading companies of Germany: ''Aron Hirsch & Sohn'' in Halberstadt, and ''Beer, Sondheimer & Co'' in Frankfurt am Main. Although Metallgesellschaft was a joint stock company, it was operated like a family business ...
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Krupp Grusonwerk
The Krupp family (see pronunciation), a prominent 400-year-old German dynasty from Essen, is notable for its production of steel, artillery, ammunition and other armaments. The family business, known as Friedrich Krupp AG (Friedrich Krupp AG Hoesch-Krupp after acquiring Hoesch AG in 1991 and lasting until 1999), was the largest company in Europe at the beginning of the 20th century, and was the premier weapons manufacturer for Germany in both world wars. Starting from the Thirty Years' War until the end of the Second World War, it produced battleships, U-boats, tanks, howitzers, guns, utilities, and hundreds of other commodities. The dynasty began in 1587 when trader Arndt Krupp moved to Essen and joined the merchants' guild. He bought and sold real estate, and became one of the city's richest men. His descendants produced small guns during the Thirty Years' War and eventually acquired fulling mills, coal mines and an iron forge. During the Napoleonic Wars, Friedrich ...
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Zinc Oxide
Zinc oxide is an inorganic compound with the formula . It is a white powder that is insoluble in water. ZnO is used as an additive in numerous materials and products including cosmetics, food supplements, rubbers, plastics, ceramics, glass, cement, lubricants, paints, ointments, adhesives, sealants, pigments, foods, batteries, ferrites, fire retardants, and first-aid tapes. Although it occurs naturally as the mineral zincite, most zinc oxide is produced synthetically. ZnO is a wide-band gap semiconductor of the II-VI semiconductor group. The native doping of the semiconductor due to oxygen vacancies or zinc interstitials is n-type. Other favorable properties include good transparency, high electron mobility, wide band gap, and strong room-temperature luminescence. Those properties make ZnO valuable for a variety of emerging applications: transparent electrodes in liquid crystal displays, energy-saving or heat-protecting windows, and electronics as thin-film transistors and lig ...
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Zinc Silicate (other)
Zinc silicate may refer to: * Hemimorphite, a zinc sorosilicate * Willemite Willemite is a zinc silicate mineral () and a minor ore of zinc. It is highly fluorescent (green) under shortwave ultraviolet light. It occurs in a variety of colors in daylight, in fibrous masses and apple-green gemmy masses. Troostite is a vari ..., a zinc neosilicate * Sauconite a zinc phyllosilicate {{Short pages monitor ...
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Zinc Ferrite
Zinc ferrites are a series of synthetic inorganic compounds of zinc and iron (ferrite) with the general formula of ZnxFe3−xO4. Zinc ferrite compounds can be prepared by aging solutions of Zn(NO3)2, Fe(NO3)3, and triethanolamine in the presence and in the absence of hydrazine, or reacting iron oxides and zinc oxide at high temperature. Spinel (Zn, Fe) Fe2O4 appears as a tan-colored solid that is insoluble in water, acids, or diluted alkali. Because of their high opacity, zinc ferrites can be used as pigments, especially in applications requiring heat stability. For example, zinc ferrite prepared from yellow iron oxide can be used as a substitute for applications in temperatures above . When added to high corrosion-resistant coatings, the corrosion protection increases with an increase in the concentration of zinc ferrite. A recent investigation shows that the zinc ferrite, which is paramagnetic in the bulk form, becomes ferrimagnetic in nanocrystalline thin film format. A larg ...
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Zinc Sulphide
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be transparent, and it is used as a window for visible optics and infrared optics. Structure ZnS exists in two main crystalline forms. This dualism is an example of polymorphism. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or sphalerite. The hexagonal form is known as the mineral wurtzite, although it also can be produced synthetically.. The transition from the sphalerite form to the wurtzite form occurs at around 1020 °C. A tetragonal form is also known as the very rare mineral called polhemusite, with the formula . Applicatio ...
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Galvanised
Galvanization or galvanizing ( also spelled galvanisation or galvanising) is the process of applying a protective zinc coating to steel or iron, to prevent rusting. The most common method is hot-dip galvanizing, in which the parts are submerged in a bath of hot, molten zinc. Protective action The zinc coating, when intact, prevents corrosive substances from reaching the underlying iron. Additional electroplating such as a chromate conversion coating may be applied to provide further surface passivation to the substrate material. History and etymology The earliest known example of galvanized iron was encountered by Europeans on 17th-century Indian armour in the Royal Armouries Museum collection. The term "galvanized" continues to be used metaphorically of any stimulus which results in activity by a person or group of people. In modern usage, the term "galvanizing" has largely come to be associated with zinc coatings, to the exclusion of other metals. Galvanic paint, a prec ...
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Electric Arc Furnace
An electric arc furnace (EAF) is a furnace that heats material by means of an electric arc. Industrial arc furnaces range in size from small units of approximately one-tonne capacity (used in foundries for producing cast iron products) up to about 400-tonne units used for secondary steelmaking. Arc furnaces used in research laboratories and by dentists may have a capacity of only a few dozen grams. Industrial electric arc furnace temperatures can reach , while laboratory units can exceed . In electric arc furnaces, the charged material (the material entered into the furnace for heating, not to be confused with electric charge) is directly exposed to an electric arc, and the current from the furnace terminals passes through the charged material. Arc furnaces differ from induction furnaces, in which the charge is heated instead by eddy currents. History In the 19th century, a number of people had employed an electric arc to melt iron. Sir Humphry Davy conducted an experimental ...
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Best Available Technology
The best available technology or best available techniques (BAT) is the technology approved by legislators or regulators for meeting output standards for a particular process, such as pollution abatement. Similar terms are ''best practicable means'' or ''best practicable environmental option''. BAT is a moving target on practices, since developing societal values and advancing techniques may change what is currently regarded as "reasonably achievable", "best practicable" and "best available". A literal understanding will connect it with a "spare no expense" doctrine which prescribes the acquisition of the best state of the art technology available, without regard for traditional cost-benefit analysis. In practical use, the cost aspect is also taken into account. See also discussions on the topic of the precautionary principle which, along with considerations of ''best available technologies'' and ''cost-benefit analyses'', is also involved in discussions leading to formulation of ...
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