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Vitrinite
Vitrinite is one of the primary components of coals and most sedimentary kerogens. Vitrinite is a type of maceral, where "macerals" are organic components of coal analogous to the "minerals" of rocks. Vitrinite has a shiny appearance resembling glass (vitreous). It is derived from the cell-wall material or woody tissue of the plants from which coal was formed. Chemically, it is composed of polymers, cellulose and lignin. The vitrinite group, which consists of various individual vitrinite ''macerals'', is the most common component of coals. It is also abundant in kerogens that are derived from the same biogenic precursors as coals, namely land plants and humic peats. Vitrinite forms diagenetically by the thermal alteration of lignin and cellulose in plant cell walls. It is therefore common in sedimentary rocks that are rich in organic matter, such as shales and marls with a terrigenous origin, or some terrigenous content. Conversely, carbonates, evaporites and well-sorted sandstone ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Maceral
A maceral is a component, organic in origin, of coal or oil shale. The term 'maceral' in reference to coal is analogous to the use of the term 'mineral' in reference to igneous or metamorphic rocks. Examples of macerals are inertinite, vitrinite, and liptinite. Inertinite Inertinite is considered to be the equivalent of charcoal and degraded plant material. It is highly oxidised in nature and may be said to be burnt. A large portion of South Africa's coal reserves consist of inertinite. Vitrinite Vitrinite is shiny, glass-like material that is considered to be composed of cellular plant material such as roots, bark, plant stems and tree trunks. Vitrinite macerals when observed under the microscope show a boxlike, cellular structure, often with oblong voids and cavities which are likely the remains of plant stems. This has a high calorific value (24 - 28 MJ/kg) and a large proportion of volatile matter (24 - 30%). It often occurs interbanded or interlaminated with inertinit ...
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Kerogens
Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It is insoluble in normal organic solvents and it does not have a specific chemical formula. Upon heating, kerogen converts in part to liquid and gaseous hydrocarbons. Petroleum and natural gas form from kerogen. Kerogen may be classified by its origin: lacustrine (e.g., algal), marine (e.g., planktonic), and terrestrial (e.g., pollen and spores). The name "kerogen" was introduced by the Scottish organic chemist Alexander Crum Brown in 1906,''Oxford English Dictionary'' 3rd Ed. (2003) derived from the Greek for "wax birth" (Greek: κηρός "wax" and -gen, γένεση "birth"). The increased production of hydrocarbons from shale has motivated a revival of research into the composition, structure, and properties of kerogen. Many studies have ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Kerogen
Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It is insoluble in normal organic solvents and it does not have a specific chemical formula. Upon heating, kerogen converts in part to liquid and gaseous hydrocarbons. Petroleum and natural gas form from kerogen. Kerogen may be classified by its origin: lacustrine (e.g., algal), marine (e.g., planktonic), and terrestrial (e.g., pollen and spores). The name "kerogen" was introduced by the Scottish organic chemist Alexander Crum Brown in 1906,''Oxford English Dictionary'' 3rd Ed. (2003) derived from the Greek for "wax birth" (Greek: κηρός "wax" and -gen, γένεση "birth"). The increased production of hydrocarbons from shale has motivated a revival of research into the composition, structure, and properties of kerogen. Many studies have ...
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Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologists re ...
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Thermal History Modelling
Thermal history modelling is an exercise undertaken during basin modelling to evaluate the temperature history of stratigraphic layers in a sedimentary basin. The thermal history of a basin is usually calibrated using thermal indicator data, including vitrinite reflectance and fission tracks in the minerals apatite and zircon. The temperatures undergone by rocks in a sedimentary basin are crucial when attempting to evaluate the quantity, nature and volume of hydrocarbons (fossil fuels) produced by diagenesis of kerogens (a group of chemicals formed from the decay of organic matter). Fourier's Law provides a simplified one-dimensional description of the variation in heat flow ''Q'' as a function of thermal conductivity ''k'' and thermal gradient ''dT''/''dz'': :Q=-k\frac (The minus sign indicates that heat flows in the opposite direction to increasing depth, that is, towards the Earth's surface.) If the assumptions used to justify this simplified approximation (i.e. steady-state ...
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University College London
, mottoeng = Let all come who by merit deserve the most reward , established = , type = Public research university , endowment = £143 million (2020) , budget = £1.544 billion (2019/20) , chancellor = Anne, Princess Royal(as Chancellor of the University of London) , provost = Michael Spence , head_label = Chair of the council , head = Victor L. L. Chu , free_label = Visitor , free = Sir Geoffrey Vos , academic_staff = 9,100 (2020/21) , administrative_staff = 5,855 (2020/21) , students = () , undergrad = () , postgrad = () , coordinates = , campus = Urban , city = London, England , affiliations = , colours = Purple and blue celeste , nickname ...
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Fossil Fuel
A fossil fuel is a hydrocarbon-containing material formed naturally in the Earth's crust from the remains of dead plants and animals that is extracted and burned as a fuel. The main fossil fuels are coal, oil, and natural gas. Fossil fuels may be burned to provide heat for use directly (such as for cooking or heating), to power engines (such as internal combustion engines in motor vehicles), or to generate electricity. Some fossil fuels are refined into derivatives such as kerosene, gasoline and propane before burning. The origin of fossil fuels is the anaerobic decomposition of buried dead organisms, containing organic molecules created by photosynthesis. The conversion from these materials to high-carbon fossil fuels typically require a geological process of millions of years. In 2019, 84% of primary energy consumption in the world and 64% of its electricity was from fossil fuels. The large-scale burning of fossil fuels causes serious environmental damage. Over 80% of t ...
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Basin Modelling
Basin modelling is the term broadly applied to a group of geological disciplines that can be used to analyse the formation and evolution of sedimentary basins, often but not exclusively to aid evaluation of potential hydrocarbon reserves. At its most basic, a basin modelling exercise must assess: # The burial history of the basin (see back-stripping). # The thermal history of the basin (see thermal history modelling). # The maturity history of the source rock In petroleum geology, source rock is rock which has generated hydrocarbons or which could generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sediments that may have been depos ...s. # The expulsion, migration and trapping of hydrocarbons. By doing so, valuable inferences can be made about such matters as hydrocarbon generation and timing, maturity of potential source rocks and migration paths of expelled hydrocarbons. References * Duppenbecker S. J. ...
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Exinite
In coal geology, liptinite is the finely-ground and macerated remains found in coal deposits. It replaced the term exinite as one of the four categories of kerogen. Liptinites were originally formed by spores, pollen, dinoflagellate cysts, leaf cuticles, and plant resins and waxes.Taylor et al., 1998. Organic Petrography. Gebrüder Borntraeger, Berlin. pp. 176 M.C. Stopes introduced the term ''exinite'' in 1935 to describe the microscopic constituent of coal, rich in volatiles and relatively rich in hydrogen, that is represented by the exines of spores. C.A. Seyler in 1932, however, used the term with its present meaning, designating the following group of macerals: sporinite, cutinite, alginite (telalginite and lamalginite), resinite. Macerals A maceral is a component, organic in origin, of coal or oil shale. The term 'maceral' in reference to coal is analogous to the use of the term 'mineral' in reference to igneous or metamorphic rocks. Examples of macerals are inertinite ...
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Geology
Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Earth sciences, including hydrology, and so is treated as one major aspect of integrated Earth system science and planetary science. Geology describes the structure of the Earth on and beneath its surface, and the processes that have shaped that structure. It also provides tools to determine the relative and absolute ages of rocks found in a given location, and also to describe the histories of those rocks. By combining these tools, geologists are able to chronicle the geological history of the Earth as a whole, and also to demonstrate the age of the Earth. Geology provides the primary evidence for plate tectonics, the evolutionary history of life, and the Earth's past climates. Geologists broadly study the properties and processes of E ...
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