|
Van Dyke Brown (printing)
Van Dyke brown is a printing process named after Anthony van Dyck. It involves coating a canvas with ferric ammonium citrate, tartaric acid, and silver nitrate, then exposing it to ultraviolet light. The canvas can be washed with water, and hypo to keep the solutions in place. The image created has a Van Dyke brown color when it's completed, and unlike other printing methods, does not require a darkroom. The Van Dyke brown process was patented in Germany in 1895 by Arndt and Troost. It was originally called many different names, such as sepia print or brown print. It has even been called kallitype, however that process uses ferric oxalate Ferric oxalate, also known as iron(III) oxalate, is a chemical compound composed of ferric ions and oxalate ligands; it may also be regarded as the ferric salt of oxalic acid. The anhydrous material is pale yellow; however, it may be hydrated to f ... instead of ferric ammonium citrate. Concerns have been voiced about the archival qualiti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anthony Van Dyck
Sir Anthony van Dyck (, many variant spellings; 22 March 1599 – 9 December 1641) was a Brabantian Flemish Baroque artist who became the leading court painter in England after success in the Southern Netherlands and Italy. The seventh child of Frans van Dyck, a wealthy Antwerp silk merchant, Anthony painted from an early age. He was successful as an independent painter in his late teens, and became a master in the Antwerp guild in 1618. By this time he was working in the studio of the leading northern painter of the day, Peter Paul Rubens, who became a major influence on his work. Van Dyck worked in London for some months in 1621, then returned to Flanders for a brief time, before travelling to Italy, where he stayed until 1627, mostly in Genoa. In the late 1620s he completed his greatly admired ''Iconography'' series of portrait etchings, mostly of other artists. He spent five years in Flanders after his return from Italy, and from 1630 was court painter for the arch ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferric Ammonium Citrate
Ammonium ferric citrate (also known as Ferric Ammonium Citrate or Ammoniacal ferrous citrate) has the formula (NH4)5 e(C6H4O7)2 A distinguishing feature of this compound is that it is very soluble in water, in contrast to ferric citrate which is not very soluble. In its crystal structure each moiety of citric acid has lost four protons. The deprotonated hydroxyl group and two of the carboxylate groups ligate to the ferric center, while the third carboxylate group coordinates with the ammonium. Uses Ammonium ferric citrate has a range of uses, including: * As a food ingredient, it has an INS number 381, and is used as an acidity regulator. Most notably used in the Scottish beverage Irn-Bru. * Water purification * As a reducing agent of metal salts of low activity like gold and silver * With potassium ferricyanide as part of the cyanotype photographic process * Used in Kligler's Iron Agar (KIA) test to identify enterobacteriaceae bacteria by observing their metabolism of diff ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tartaric Acid
Tartaric acid is a white, crystalline organic acid that occurs naturally in many fruits, most notably in grapes, but also in bananas, tamarinds, and citrus. Its salt, potassium bitartrate, commonly known as cream of tartar, develops naturally in the process of fermentation. It is commonly mixed with sodium bicarbonate and is sold as baking powder used as a leavening agent in food preparation. The acid itself is added to foods as an antioxidant E334 and to impart its distinctive sour taste. Naturally occurring tartaric acid is a useful raw material in organic chemical synthesis. Tartaric acid is an alpha-hydroxy-carboxylic acid, is diprotic and aldaric in acid characteristics, and is a dihydroxyl derivative of succinic acid. History Tartaric acid has been known to winemakers for centuries. However, the chemical process for extraction was developed in 1769 by the Swedish chemist Carl Wilhelm Scheele. Tartaric acid played an important role in the discovery of chemical chiral ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Silver Nitrate
Silver nitrate is an inorganic compound with chemical formula . It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called ''lunar caustic'' because silver was called ''luna'' by ancient alchemists who associated silver with the moon. In solid silver nitrate, the silver ions are three- coordinated in a trigonal planar arrangement. Synthesis and structure Albertus Magnus, in the 13th century, documented the ability of nitric acid to separate gold and silver by dissolving the silver. Indeed silver nitrate can be prepared by dissolving silver in nitric acid followed by evaporation of the solution. The stoichiometry of the reaction depends upon the concentration of nitric acid used. :3 Ag + 4 HNO3 (cold and diluted) → 3 AgNO3 + 2 H2O + NO :Ag + 2 HNO3 (hot and concentrated) → AgNO3 + H2O + NO2 The structure of silver nitrate has been examined by X-ray crystallography sever ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ultraviolet Light
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30 PHz) to 400 nm (750 THz), shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight, and constitutes about 10% of the total electromagnetic radiation output from the Sun. It is also produced by electric arcs and specialized lights, such as mercury-vapor lamps, tanning lamps, and black lights. Although long-wavelength ultraviolet is not considered an ionizing radiation because its photons lack the energy to ionize atoms, it can cause chemical reactions and causes many substances to glow or fluoresce. Consequently, the chemical and biological effects of UV are greater than simple heating effects, and many practical applications of UV radiation derive from its interactions with organic molecules. Short-wave ultraviolet light damages DNA and sterilizes surfaces with which it comes into contact. For h ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodium Thiosulfate
Sodium thiosulfate (sodium thiosulphate) is an inorganic compound with the formula . Typically it is available as the white or colorless pentahydrate, . The solid is an efflorescent (loses water readily) crystalline substance that dissolves well in water. Sodium thiosulfate is used in gold mining, water treatment, analytical chemistry, the development of silver-based photographic film and prints, and medicine. The medical uses of sodium thiosulfate include treatment of cyanide poisoning and pityriasis. It is on the World Health Organization's List of Essential Medicines. Uses Sodium thiosulfate is used predominantly in industry. For example, it is used to convert dyes to their soluble colorless forms, which are called leuco. It is also used to bleach "wool, cotton, silk, ...soaps, glues, clay, sand, bauxite, and... edible oils, edible fats, and gelatin." Medical uses Sodium thiosulfate is used in the treatment of cyanide poisoning. Other uses include topical treatment of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Darkroom
A darkroom is used to process photographic film, to make prints and to carry out other associated tasks. It is a room that can be made completely dark to allow the processing of the light-sensitive photographic materials, including film and photographic paper. Various equipment is used in the darkroom, including an enlarger, baths containing chemicals, and running water. Darkrooms have been used since the inception of photography in the early 19th century. Darkrooms have many various manifestations, from the elaborate space used by Ansel Adams to a retooled ambulance wagon used by Timothy H. O'Sullivan. From the initial development of the film to the creation of prints, the darkroom process allows complete control over the medium. Due to the popularity of color photography and complexity of processing color film (''see C-41 process'') and printing color photographs and also to the rise, first of instant photography technology and later digital photography, darkrooms are dec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kallitype
Kallitype is a process for making photographic prints. Patented in 1889 by W. W. J. Nicol (1855-1929), the Kallitype print is an iron-silver process. A chemical process similar to the Van Dyke brown based on the use of a combination of ferric and silver salts. While Van Dyke brown and argyrotype use ferric ammonium citrate, the light-sensitive element used for the Kallitype is ferric oxalate. The use of ferric oxalate allows for both extended shadow definition (higher DMAX) and contrast control. Many developing solutions can be used to give a different image color (brown, sepia, blue, maroon and black). Kallitype images generally have a richer tonal range than the cyanotype. These prints were popular in the 19th century, and then their popularity faded away. Sometimes known as "the poor man's platinum print", when the image is toned in platinum or palladium the result is nearly chemically identical to a true Platinotype. It is believed that many Kallitypes were passed off as true ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ferric Oxalate
Ferric oxalate, also known as iron(III) oxalate, is a chemical compound composed of ferric ions and oxalate ligands; it may also be regarded as the ferric salt of oxalic acid. The anhydrous material is pale yellow; however, it may be hydrated to form several hydrates, such as potassium ferrioxalate, or , which is bright green in colour. Structure Tetrahydrate The crystal structure of the tetrahydrate was determined in 2015. It has a triclinic unit cell containing two iron atoms. Each iron atom has octahedral coordination bonds to the oxygen atoms of three oxalate molecules and one water molecule. Two of those three oxalates, lying in approximately perpendicular planes, are tetradentate, and connect the iron atoms into zigzag chains. The third oxalate molecule is bidentate, and connects iron atoms of adjacent chains, creating an open-layered structure. Half of the water molecules lie, unbound, between those chains. Mössbauer spectrum of indicates that iron is present in a u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
