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Ullmannite
Ullmannite is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite. Physical properties Ullmannite is steel-gray to tin white in color with a metallic luster, has a Mohs hardness of 5 to 5.5 and a specific gravity of 6.65. Initially thought to be of two species, tetrahedral and cubic, it was later confirmed that both samples conformed to the 23 point group of the isometric crystal class and typically exhibits cubic, octahedral, or pyritohedral forms although euhedral crystals are rare. Variance in its chemical composition has been shown to be responsible for loss of symmetry and variations in striation patterns. Ullmannite crystals are usually less than 2 mm, however larger have been identified in especially antimony rich environments. Ullmannite commonly displays interpenetration t ...
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Cubic (crystal System)
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one lattice point on each corner of the cube; this means each simple cubic unit cell has in total one lattice point. Each atom at a lattice point is then shared equally between eight adjacent cu ...
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Cubic Crystal System
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of these crystals: *Primitive cubic (abbreviated ''cP'' and alternatively called simple cubic) *Body-centered cubic (abbreviated ''cI'' or bcc) *Face-centered cubic (abbreviated ''cF'' or fcc, and alternatively called ''cubic close-packed'' or ccp) Each is subdivided into other variants listed below. Although the ''unit cells'' in these crystals are conventionally taken to be cubes, the primitive unit cells often are not. Bravais lattices The three Bravais lattices in the cubic crystal system are: The primitive cubic lattice (cP) consists of one lattice point on each corner of the cube; this means each simple cubic unit cell has in total one lattice point. Each atom at a lattice point is then shared equally between eight adjacent cu ...
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Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite *Galena *Sphalerite * Chalcopyrite * Pyrrhotite * Millerite * Pentlandite * Covellite * Cinnabar * Realgar *Orpiment * Stibnite *Pyrite * Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite * Gersdorffite Sulfosalts: * Pyrargyrite * Proustite *Tetrahedrite * Tennantite * Enargite * B ...
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Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production ...
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Cobaltite
Cobaltite is a sulfide mineral composed of cobalt, arsenic, and sulfur, Co As S. Its impurities may contain up to 10% iron and variable amounts of nickel.Klein, Cornelus and Cornrlius Hurlbut, 1996, ''Manual of Mineralogy'', 20th ed., Wiley, p.288, Structurally, it resembles pyrite (FeS2) with one of the sulfur atoms replaced by an arsenic atom. Although rare, it is mined as a significant source of the strategically important metal cobalt. Secondary weathering incrustations of erythrite, hydrated cobalt arsenate, are common. A variety containing much iron replacing cobalt, and known as ferrocobaltite (german: link=no, Stahlkobalt), was found at Siegen in Westphalia. The name is from the German, ''Kobold'', "underground spirit" in allusion to the "refusal" of cobaltiferous ores to smelt as they are expected to, including the foul-smelling, poisonous fumes the ores gave off. Cobaltite, which contains both arsenic and sulfur, was one of these ores. It occurs in high-temperature ...
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Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, smaller islands. With an area of , Australia is the largest country by area in Oceania and the world's List of countries and dependencies by area, sixth-largest country. Australia is the oldest, flattest, and driest inhabited continent, with the least fertile soils. It is a Megadiverse countries, megadiverse country, and its size gives it a wide variety of landscapes and climates, with Deserts of Australia, deserts in the centre, tropical Forests of Australia, rainforests in the north-east, and List of mountains in Australia, mountain ranges in the south-east. The ancestors of Aboriginal Australians began arriving from south east Asia approximately Early human migrations#Nearby Oceania, 65,000 years ago, during the Last Glacial Period, last i ...
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Austria
Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous city and state. A landlocked country, Austria is bordered by Germany to the northwest, the Czech Republic to the north, Slovakia to the northeast, Hungary to the east, Slovenia and Italy to the south, and Switzerland and Liechtenstein to the west. The country occupies an area of and has a population of 9 million. Austria emerged from the remnants of the Eastern and Hungarian March at the end of the first millennium. Originally a margraviate of Bavaria, it developed into a duchy of the Holy Roman Empire in 1156 and was later made an archduchy in 1453. In the 16th century, Vienna began serving as the empire's administrative capital and Austria thus became the heartland of the Habsburg monarchy. After the dissolution of the H ...
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Germany
Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated between the Baltic and North seas to the north, and the Alps to the south; it covers an area of , with a population of almost 84 million within its 16 constituent states. Germany borders Denmark to the north, Poland and the Czech Republic to the east, Austria and Switzerland to the south, and France, Luxembourg, Belgium, and the Netherlands to the west. The nation's capital and most populous city is Berlin and its financial centre is Frankfurt; the largest urban area is the Ruhr. Various Germanic tribes have inhabited the northern parts of modern Germany since classical antiquity. A region named Germania was documented before AD 100. In 962, the Kingdom of Germany formed the bulk of the Holy Roman Empire. During the 16th ce ...
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Hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with the assistance of. Roderick McKenzie.'' Oxford: Clarendon Press. and θέρμη, ''heat'' ). Hydrothermal circulation occurs most often in the vicinity of sources of heat within the Earth's crust. In general, this occurs near volcanic activity, but can occur in the shallow to mid crust along deeply penetrating fault irregularities or in the deep crust related to the intrusion of granite, or as the result of orogeny or metamorphism. Seafloor hydrothermal circulation Hydrothermal circulation in the oceans is the passage of the water through mid-oceanic ridge systems. The term includes both the circulation of the well-known, high-temperature vent waters near the ridge crests, and the much-lower-temperature, diffuse flow of water through sed ...
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Dyscrasite
The silver antimonide mineral dyscrasite has the chemical formula Ag3Sb. It is an opaque, silver white, metallic mineral which crystallizes in the orthorhombic crystal system. It forms pyramidal crystals up to and can also form cylindrical and prismatic crystals.Anthony, J.W., Bideau, R.A., Bladh, K.W., and Nichols, M.C. (1990) Handbook of Mineralogy: Volume I: Elements, Sulfides, Sulfosalts. 588 p. Mineral Data Publishing, Tucson, Arizona. http://rruff.geo.arizona.edu/doclib/hom/dyscrasite.pdf Crystallography and properties Dyscrasite is a metal ore and is opaque. In reflected light, however, it demonstrates weak anisotropism. Dyscrasite’s color under plane polarized light is most likely dark grey/black. When spun on a rotatable stage of a microscope (under plane polarized light), dyscrasite’s color should slightly change shades. This property is called pleochroism. Dyscrasite exhibits very weak reflected light pleochroism. Dyscrasite belongs to the orthorhombic crys ...
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Tetrahedrite
Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, the antimony rich phase is more common. Other elements also substitute in the structure, most notably iron and zinc, along with less common silver, mercury and lead. Bismuth also substitutes for the antimony site and ''bismuthian tetrahedrite'' or ''annivite'' is a recognized variety. The related, silver dominant, mineral species freibergite, although rare, is notable in that it can contain up to 18% silver. Mineralogy Tetrahedrite gets its name from the distinctive tetrahedron shaped cubic crystals. The mineral usually occurs in massive form, it is a steel gray to black metallic mineral with Mohs hardness of 3.5 to 4 and specific gravity of 4.6 to 5.2. Tetrahedrite occurs in low to moderate temperature hydrothermal veins and in some co ...
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Galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crystallizes in the cubic crystal system often showing octahedral forms. It is often associated with the minerals sphalerite, calcite and fluorite. Occurrence Galena is the main ore of lead, used since ancient times, since lead can be smelted from galena in an ordinary wood fire. Galena typically is found in hydrothermal veins in association with sphalerite, marcasite, chalcopyrite, cerussite, anglesite, dolomite, calcite, quartz, barite, and fluorite. It is also found in association with sphalerite in low-temperature lead-zinc deposits within limestone beds. Minor amounts are found in contact metamorphic zones, in pegmatites, and disseminated in sedimentary rock. In some deposits the galena contains up to 0.5% silver, a by ...
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