Unsymmetrical Dimethylhydrazine
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Unsymmetrical Dimethylhydrazine
Unsymmetrical dimethylhydrazine (UDMH; 1,1-dimethylhydrazine, НДМГ or codenamed Geptil) is a chemical compound with the formula H2NN(CH3)2 that is used as a rocket propellant. It is a colorless liquid, with a sharp, fishy, ammonia-like smell typical for organic amines. Samples turn yellowish on exposure to air and absorb oxygen and carbon dioxide. It is miscible with water, ethanol, and kerosene. In concentration between 2.5% and 95% in air, its vapors are flammable. It is not sensitive to shock. Symmetrical dimethylhydrazine, 1,2-dimethylhydrazine is also known but is not as useful. Production UDMH is produced industrially by two routes. Based on the Olin Raschig process, one method involves reaction of monochloramine with dimethylamine giving 1,1-dimethylhydrazinium chloride: :(CH3)2NH + NH2Cl → (CH3)2NNH2 ⋅ HCl In the presence of suitable catalysts, acetylhydrazine can be N-dimethylated using formaldehyde and hydrogen to give the N,N-dimethyl-N'-acetylhydrazine, w ...
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Hypergolic
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other. The two propellant components usually consist of a fuel and an oxidizer. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme toxicity and/or corrosiveness. In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination: dinitrogen tetroxide plus hydrazine and/or its relatives monomethylhydrazine (MMH) and unsymmetrical dimethylhydrazine (UDMH). History In 1935, Hellmuth Walter discovered that hydrazine hydrate was hypergolic with high-test peroxide of 80-83%. He was probably the first to discover this phenomenon, and set to work devel ...
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Rocket Fuel
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and nozzle, not by "pushing" against the air behind or below it. Rocket engines perform best in outer space because of the lack of air pressure on the outside of the engine. In space it is also possible to fit a longer nozzle without suffering from flow separation. Most chemical propellants release energy through redox chemistry, m ...
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Proton (rocket)
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei). One or more protons are present in the Atomic nucleus, nucleus of every atom. They provide the attractive electrostatic central force which binds the atomic electrons. The number of protons in the nucleus is the defining property of an element, and is referred to as the atomic number (represented by the symbol ''Z''). Since each chemical element, element has a unique number of protons, each element has its own unique atomic number, which determines the number of atomic electrons and consequently the chemical characteristics of the element. The word ''proton'' is Greek language, G ...
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UR-100N
The UR-100N, also known as RS-18A is an intercontinental ballistic missile in service with Soviet and Russian Strategic Missile Troops. The missile was given the NATO reporting name SS-19 Stiletto and carries the industry designation 15A30. Development Development of the UR-100N began at OKB-52 in 1970 and flight tests were carried out from 1973 through 1975. In 1976, the improved UR-100NUTTKh (NATO designation SS-19 Mod 3) version entered development with flight tests in the later half of the decade. The rocket's control system was developed at NPO "Electropribor" (Kharkiv, Ukraine). Description The UR-100N is a fourth-generation silo-launched liquid-propellant ICBM similar to the UR-100 but with much increased dimensions, weights, performance, and payload. The missile was not designed to use existing UR-100 silos, and therefore had new silos constructed for it. The missile has a preparation time to start of 25 minutes, a storage period of 22 years, and 6 MIRVs. Operational ...
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UR-100
The UR-100 (russian: УР-100) was an intercontinental ballistic missile (ICBM) developed and deployed by the Soviet Union from 1966 to 1996. UR () in its designation stood for Universal Rocket (russian: links=no, Универсальная Ракета). It was known during the Cold War by the NATO reporting name SS-11 Sego and internally by the GRAU index 8K84. The Strela and Rokot carrier rockets are based on it. The similar designation ''UR-100MR'' (russian: links=no, УР-100МР) actually refers to an entirely different missile, the MR-UR-100 Sotka (SS-17 Spanker). Description The UR-100 was a two-stage liquid-propellant lightweight ICBM. Initial versions carried a single warhead of 0.5 to 1.1 Mt yield, while later versions could carry three or six MIRV warheads. The missile was silo-launched. 15P784 silo design (by KBOM, ''Design Bureau of Common Machinery'', of V.P.Barmin) was greatly simplified in comparison to earlier missiles. Facilities consisted of harden ...
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Specific Impulse
Specific impulse (usually abbreviated ) is a measure of how efficiently a reaction mass engine (a rocket using propellant or a jet engine using fuel) creates thrust. For engines whose reaction mass is only the fuel they carry, specific impulse is exactly proportional to the effective exhaust gas velocity. A propulsion system with a higher specific impulse uses the mass of the propellant more efficiently. In the case of a rocket, this means less propellant needed for a given delta-v, so that the vehicle attached to the engine can more efficiently gain altitude and velocity. In an atmospheric context, specific impulse can include the contribution to impulse provided by the mass of external air that is accelerated by the engine in some way, such as by an internal turbofan or heating by fuel combustion participation then thrust expansion or by external propeller. Jet engines breathe external air for both combustion and by-pass, and therefore have a much higher specific impulse than ...
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Monomethylhydrazine
Monomethylhydrazine (mono-methyl hydrazine, MMH) is a highly toxic, volatile hydrazine derivative with the chemical formula . It is used as a rocket propellant in bipropellant rocket engines because it is hypergolic with various oxidizers such as nitrogen tetroxide () and nitric acid (). As a propellant, it is described in specification MIL-PRF-27404. MMH is a hydrazine derivative that was once used in the orbital maneuvering system (OMS) and reaction control system (RCS) engines of NASA's Space Shuttle, which used MMH and MON-3 (a mixture of nitrogen tetroxide with approximately 3% nitric oxide). This chemical is toxic and carcinogenic, but it is easily stored in orbit, providing moderate performance for very low fuel tank system weight. MMH and its chemical relative unsymmetrical dimethylhydrazine (UDMH) have a key advantage that they are stable enough to be used in regeneratively cooled rocket engines. The European Space Agency (ESA) has attempted to seek new options in terms o ...
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Orbital Maneuvering System
In spaceflight, an orbital maneuver (otherwise known as a burn) is the use of propulsion systems to change the orbit of a spacecraft. For spacecraft far from Earth (for example those in orbits around the Sun) an orbital maneuver is called a ''deep-space maneuver (DSM)''. The rest of the flight, especially in a transfer orbit, is called ''coasting''. General Rocket equation The Tsiolkovsky rocket equation, or ideal rocket equation is an equation that is useful for considering vehicles that follow the basic principle of a rocket: where a device that can apply acceleration to itself (a thrust) by expelling part of its mass with high speed and moving due to the conservation of momentum. Specifically, it is a mathematical equation that relates the delta-v (the maximum change of speed of the rocket if no other external forces act) with the effective exhaust velocity and the initial and final mass of a rocket (or other reaction engine.) For any such maneuver (or journey involvin ...
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Space Shuttle
The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program name was Space Transportation System (STS), taken from a 1969 plan for a system of reusable spacecraft where it was the only item funded for development. The first ( STS-1) of four orbital test flights occurred in 1981, leading to operational flights (STS-5) beginning in 1982. Five complete Space Shuttle orbiter vehicles were built and flown on a total of 135 missions from 1981 to 2011. They launched from the Kennedy Space Center (KSC) in Florida. Operational missions launched numerous satellites, interplanetary probes, and the Hubble Space Telescope (HST), conducted science experiments in orbit, participated in the Shuttle-''Mir'' program with Russia, and participated in construction and servicing of the International Space Station (ISS). ...
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Liquid Rocket
A liquid-propellant rocket or liquid rocket utilizes a rocket engine that uses liquid propellants. Liquids are desirable because they have a reasonably high density and high specific impulse (''I''sp). This allows the volume of the propellant tanks to be relatively low. It is also possible to use lightweight centrifugal turbopumps to pump the rocket propellant from the tanks into the combustion chamber, which means that the propellants can be kept under low pressure. This permits the use of low-mass propellant tanks that do not need to resist the high pressures needed to store significant amounts of gasses, resulting in a low mass ratio for the rocket. An inert gas stored in a tank at a high pressure is sometimes used instead of pumps in simpler small engines to force the propellants into the combustion chamber. These engines may have a higher mass ratio, but are usually more reliable, and are therefore used widely in satellites for orbit maintenance. Liquid rockets can be monop ...
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Hydrazine
Hydrazine is an inorganic compound with the chemical formula . It is a simple pnictogen hydride, and is a colourless flammable liquid with an ammonia-like odour. Hydrazine is highly toxic unless handled in solution as, for example, hydrazine hydrate (). Hydrazine is mainly used as a foaming agent in preparing polymer foams, but applications also include its uses as a precursor to polymerization catalysts, pharmaceuticals, and agrochemicals, as well as a long-term storable propellant for in-space spacecraft propulsion. Additionally, hydrazine is used in various rocket fuels and to prepare the gas precursors used in air bags. Hydrazine is used within both nuclear and conventional electrical power plant steam cycles as an oxygen scavenger to control concentrations of dissolved oxygen in an effort to reduce corrosion. the world hydrazine hydrate market amounted to $350 million. About two million tons of hydrazine hydrate were used in foam blowing agents in 2015. Hydrazines r ...
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Liquid Oxygen
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an application which has continued to the present. Physical properties Liquid oxygen has a pale blue color and is strongly paramagnetic: it can be suspended between the poles of a powerful horseshoe magnet. Liquid oxygen has a density of , slightly denser than liquid water, and is cryogenic with a freezing point of and a boiling point of at . Liquid oxygen has an expansion ratio of 1:861 under and , and because of this, it is used in some commercial and military aircraft as a transportable source of breathing oxygen. Because of its cryogenic nature, liquid oxygen can cause the materials it touches to become extremely brittle. Liquid oxygen is also a very powerful oxidizing agent: organic materials will burn rapidly and energetically in liquid o ...
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