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Unconventional Superconductors
Unconventional superconductors are materials that display superconductivity which does not conform to either the conventional BCS theory or Nikolay Bogolyubov's theory or its extensions. History The superconducting properties of CeCu2Si2, a type of heavy fermion material, were reported in 1979 by Frank Steglich. For a long time it was believed that CeCu2Si2 was a singlet d-wave superconductor, but since the mid 2010s, this notion has been strongly contested. In the early eighties, many more unconventional, heavy fermion superconductors were discovered, including UBe13, UPt3 and URu2Si2. In each of these materials, the anisotropic nature of the pairing was implicated by the power-law dependence of the nuclear magnetic resonance (NMR) relaxation rate and specific heat capacity on temperature. The presence of nodes in the superconducting gap of UPt3 was confirmed in 1986 from the polarization dependence of the ultrasound attenuation. The first unconventional triplet superconduc ...
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Superconductivity
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source. The superconductivity phenomenon was discovered in 1911 by Dutch physicist Heike Kamerlingh Onnes. Like ferromagnetism and atomic spectral lines, superconductivity is a phenomenon which can only be explained by quantum mechanics. It is characterized by the Meissner effect, the complete ejection of magnetic field lines from the interior of the superconductor during its transitions into the sup ...
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Kelvin
The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and physicist William Thomson, 1st Baron Kelvin (1824–1907). The Kelvin scale is an absolute thermodynamic temperature scale, meaning it uses absolute zero as its null (zero) point. Historically, the Kelvin scale was developed by shifting the starting point of the much-older Celsius scale down from the melting point of water to absolute zero, and its increments still closely approximate the historic definition of a degree Celsius, but since 2019 the scale has been defined by fixing the Boltzmann constant to be exactly . Hence, one kelvin is equal to a change in the thermodynamic temperature that results in a change of thermal energy by . The temperature in degree Celsius is now defined as the temperature in kelvins minus 273.15, meaning t ...
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Magnesium Diboride
Magnesium diboride is the inorganic compound with the formula MgB2. It is a dark gray, water-insoluble solid. The compound has attracted attention because it becomes superconductor, superconducting at 39 K (−234 °C). In terms of its composition, MgB2 differs strikingly from most low-temperature superconductors, which feature mainly transition metals. Its superconducting mechanism is primarily described by BCS theory. Superconductivity Magnesium diboride's superconducting properties were discovered in 2001. Its critical temperature#Superconductivity, critical temperature (''T''c) of is the highest amongst conventional superconductors. Among conventional (BCS theory, phonon-mediated) superconductors, it is unusual. Its electronic structure is such that there exist two types of electrons at the Fermi level with widely differing behaviours, one of them (Sigma bond, sigma-bonding) being much more strongly superconducting than the other (Pi bond, pi-bonding). This is at ...
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Cooper Pair
In condensed matter physics, a Cooper pair or BCS pair (Bardeen–Cooper–Schrieffer pair) is a pair of electrons (or other fermions) bound together at low temperatures in a certain manner first described in 1956 by American physicist Leon Cooper. Cooper pair Cooper showed that an arbitrarily small attraction between electrons in a metal can cause a paired state of electrons to have a lower energy than the Fermi energy, which implies that the pair is bound. In conventional superconductors, this attraction is due to the electron–phonon interaction. The Cooper pair state is responsible for superconductivity, as described in the BCS theory developed by John Bardeen, Leon Cooper, and John Schrieffer for which they shared the 1972 Nobel Prize. Although Cooper pairing is a quantum effect, the reason for the pairing can be seen from a simplified classical explanation. An electron in a metal normally behaves as a free particle. The electron is repelled from other electrons due to thei ...
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Strontium Ruthenate
Strontium ruthenate may refer to two compounds: * Monostrontium ruthenate, SrRuO3, a ferromagnetic perovskite. * Distrontium ruthenate Distrontium ruthenate, also known as strontium ruthenate, is an oxide of strontium and ruthenium with the chemical formula Sr2RuO4. It was the first reported perovskite superconductor that did not contain copper. Strontium ruthenate is struct ..., Sr2RuO4, a perovskite superconductor that does not contain copper. {{set index Strontium compounds Ruthenium(IV) compounds Transition metal oxides ...
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Thallium Barium Calcium Copper Oxide
Thallium barium calcium copper oxide, or TBCCO (pronounced "tibco"), is a family of high-temperature superconductors having the generalized chemical formula Tl''m'' Ba2 Ca''n''−1 Cu''n'' O2''n''+''m''+2. Tl2Ba2Ca2Cu3O10 (TBCCO-2223) was discovered in Prof. Allen M. Hermann's laboratory in the physics department of the University of Arkansas in October 1987 by the post-doctoral researcher Zhengzhi Sheng and Prof. Hermann. The bulk superconductivity in this material was confirmed by observations of magnetic flux expulsion and flux trapping signals (under zero field cooled and field cooled conditions) with a SQUID magnetometer in the superconductor laboratory of Timir Datta in the University of South Carolina. Allen Hermann announced his discovery and the critical temperature of 127 K, in Houston, Texas at the World Congress on Superconductivity organized by Paul Chu in February 1988. The first series of the Tl-based superconductor containing one Tl–O layer has the genera ...
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Bismuth Strontium Calcium Copper Oxide
Bismuth strontium calcium copper oxide (BSCCO, pronounced ''bisko''), is a type of cuprate superconductor having the generalized chemical formula Bi2 Sr2 Ca''n''−1 Cu''n'' O2''n''+4+''x'', with ''n'' = 2 being the most commonly studied compound (though ''n'' = 1 and ''n'' = 3 have also received significant attention). Discovered as a general class in 1988, BSCCO was the first high-temperature superconductor which did not contain a rare-earth element. It is a cuprate superconductor, an important category of high-temperature superconductors sharing a two-dimensional layered (perovskite) structure (see figure at right) with superconductivity taking place in a copper-oxide plane. BSCCO and YBCO are the most studied cuprate superconductors. Specific types of BSCCO are usually referred to using the sequence of the numbers of the metallic ions. Thus Bi-2201 is the ''n'' = 1 compound ( Bi2 Sr2 Cu O6+''x''), Bi-2212 is the ''n'' = 2 compound ( Bi2 Sr2 ...
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Conventional Superconductor
Conventional superconductors are materials that display superconductivity as described by BCS theory or its extensions. This is in contrast to unconventional superconductors, which do not. Conventional superconductors can be either type-I or type-II. Most elemental superconductors are conventional. Niobium and vanadium are type-II, while most other elemental superconductors are type-I. Critical temperatures of some elemental superconductors: Most compound and alloy superconductors are type-II materials. The most commonly used conventional superconductor in applications is a niobium-titanium alloy - this is a type-II superconductor with a superconducting critical temperature of 11 K. The highest critical temperature so far achieved in a conventional superconductor was 39 K (-234 °C) in magnesium diboride Magnesium diboride is the inorganic compound with the formula MgB2. It is a dark gray, water-insoluble solid. The compound has attracted attention because it becomes superco ...
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Liquid Helium
Liquid helium is a physical state of helium at very low temperatures at standard atmospheric pressures. Liquid helium may show superfluidity. At standard pressure, the chemical element helium exists in a liquid form only at the extremely low temperature of . Its boiling point and critical point depend on which isotope of helium is present: the common isotope helium-4 or the rare isotope helium-3. These are the only two stable isotopes of helium. See the table below for the values of these physical quantities. The density of liquid helium-4 at its boiling point and a pressure of one atmosphere (101.3 kilopascals) is about , or about one-eighth the density of liquid water. Liquefaction Helium was first liquefied on July 10, 1908, by the Dutch physicist Heike Kamerlingh Onnes at the University of Leiden in the Netherlands. At that time, helium-3 was unknown because the mass spectrometer had not yet been invented. In more recent decades, liquid helium has been used as a cryogenic ref ...
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Technological Applications Of Superconductivity
Some of the technological applications of superconductivity include: * the production of sensitive magnetometers based on SQUIDs (superconducting quantum interference devices) * fast digital circuits (including those based on Josephson junctions and rapid single flux quantum technology), * powerful superconducting electromagnets used in maglev trains, magnetic resonance imaging (MRI) and nuclear magnetic resonance (NMR) machines, magnetic confinement fusion reactors (e.g. tokamaks), and the beam-steering and focusing magnets used in particle accelerators * low-loss power cables * RF and microwave filters (e.g., for mobile phone base stations, as well as military ultra-sensitive/selective receivers) * fast fault current limiters * high sensitivity particle detectors, including the transition edge sensor, the superconducting bolometer, the superconducting tunnel junction detector, the kinetic inductance detector, and the superconducting nanowire single-photon detector * railgun and c ...
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Liquid Nitrogen
Liquid nitrogen—LN2—is nitrogen in a liquid state at low temperature. Liquid nitrogen has a boiling point of about . It is produced industrially by fractional distillation of liquid air. It is a colorless, low viscosity liquid that is widely used as a coolant. Physical properties The diatomic character of the N2 molecule is retained after liquefaction. The weak van der Waals interaction between the N2 molecules results in little interatomic interaction, manifested in its very low boiling point. The temperature of liquid nitrogen can readily be reduced to its freezing point by placing it in a vacuum chamber pumped by a vacuum pump. Liquid nitrogen's efficiency as a coolant is limited by the fact that it boils immediately on contact with a warmer object, enveloping the object in an insulating layer of nitrogen gas bubbles. This effect, known as the Leidenfrost effect, occurs when any liquid comes in contact with a surface which is significantly hotter than its boiling ...
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Yttrium Barium Copper Oxide
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen (77 K) at about 93 K. Many YBCO compounds have the general formula Y Ba2 Cu3 O7−''x'' (also known as Y123), although materials with other Y:Ba:Cu ratios exist, such as Y Ba2 Cu4 Oy (Y124) or Y2 Ba4 Cu7 Oy (Y247). At present, there is no singularly recognised theory for high-temperature superconductivity. It is part of the more general group of rare-earth barium copper oxides (ReBCO) in which, instead of yttrium, other rare earths are present. History In April 1986, Georg Bednorz and Karl Müller, working at IBM in Zurich, discovered that certain semiconducting oxides became superconducting at relatively high temperature, in particular, a lanthanum barium copper oxide becomes superconducting at 35 K. This oxide was an oxyge ...
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