UPd2Al3
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UPd2Al3
UPd2Al3 is a heavy-fermion superconductor with a hexagonal crystal structure and critical temperature Tc=2.0K that was discovered in 1991. Furthermore, UPd2Al3 orders antiferromagnetically at TN=14K, and UPd2Al3 thus features the unusual behavior that this material, at temperatures below 2K, is simultaneously superconducting and magnetically ordered. Later experiments demonstrated that superconductivity in UPd2Al3 is magnetically mediated, and UPd2Al3 therefore serves as a prime example for non-phonon-mediated superconductors. Discovery Heavy-fermion superconductivity was discovered already in the late 1970s (with CeCu2Si2 being the first example), but the number of heavy-fermion compounds known to superconduct was still very small in the early 1990s, when Christoph Geibel in the group of Frank Steglich found two closely related heavy-fermion superconductors, UNi2Al3 (Tc=1K) and UPd2Al3 (Tc=2K), which were published in 1991. At that point, the Tc=2.0K of UPd2Al3 was the highest cr ...
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Heavy-fermion Superconductor
Heavy fermion superconductors are a type of unconventional superconductor. The first heavy fermion superconductor, CeCu2Si2, was discovered by Frank Steglich Frank Steglich (born 14 March 1941) is a German physicist. He studied physics in the University of Münster and the University of Göttingen. He received the Gottfried Wilhelm Leibniz Prize by the Deutsche Forschungsgemeinschaft in 1986 and a num ... in 1978. Since then over 30 heavy fermion superconductors were found (in materials based on Ce, U), with a critical temperature up to 2.3 K (in CeCoIn5). Heavy Fermion materials are intermetallic compounds, containing rare earth or actinide elements. The f-electrons of these atoms hybridize with the normal conduction electrons leading to quasiparticles with an enhanced effective mass. From specific heat measurements (ΔC/C(TC) one knows that the Cooper pairs in the superconducting state are also formed by the heavy quasiparticles. In contrast to normal superconductors it c ...
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Drude Model
The Drude model of electrical conduction was proposed in 1900 by Paul Drude to explain the transport properties of electrons in materials (especially metals). Basically, Ohm's law was well established and stated that the current ''J'' and voltage ''V'' driving the current are related to the resistance ''R'' of the material. The inverse of the resistance is known as the conductance. When we consider a metal of unit length and unit cross sectional area, the conductance is known as the conductivity, which is the inverse of resistivity. The Drude model attempts to explain the resistivity of a conductor in terms of the scattering of electrons (the carriers of electricity) by the relatively immobile ions in the metal that act like obstructions to the flow of electrons. The model, which is an application of kinetic theory, assumes that the microscopic behaviour of electrons in a solid may be treated classically and behaves much like a pinball machine, with a sea of constantly jittering e ...
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Uranium Compounds
Uranium compounds are compounds formed by the element uranium (U). Although uranium is a radioactive actinide, its compounds are well studied due to its long half-life and its applications. It usually forms in the +4 and +6 oxidation states, although it can also form in other oxidation states. Oxidation states and oxides Oxides Calcined uranium yellowcake, as produced in many large mills, contains a distribution of uranium oxidation species in various forms ranging from most oxidized to least oxidized. Particles with short residence times in a calciner will generally be less oxidized than those with long retention times or particles recovered in the stack scrubber. Uranium content is usually referenced to , which dates to the days of the Manhattan Project when was used as an analytical chemistry reporting standard. Phase relationships in the uranium-oxygen system are complex. The most important oxidation states of uranium are uranium(IV) and uranium(VI), and their two corre ...
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Intermetallics
An intermetallic (also called an intermetallic compound, intermetallic alloy, ordered intermetallic alloy, and a long-range-ordered alloy) is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds. Although the term "intermetallic compounds", as it applies to solid phases, has been in use for many years, its introduction was regretted, for example by Hume-Rothery in 1955. Definitions Research definition Schulze in 1967 defined intermetallic compounds as ''solid phases containing two or more metallic elements, with optionally one or more non-metallic elements, whose crystal structure differs from that of the other constituents''. Under this definition, the following are included: #Electron (or Hume-Rothery) compounds #Size packing phases. e.g. Lav ...
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Correlated Electrons
In statistics, correlation or dependence is any statistical relationship, whether causal or not, between two random variables or bivariate data. Although in the broadest sense, "correlation" may indicate any type of association, in statistics it usually refers to the degree to which a pair of variables are ''linearly'' related. Familiar examples of dependent phenomena include the correlation between the height of parents and their offspring, and the correlation between the price of a good and the quantity the consumers are willing to purchase, as it is depicted in the so-called demand curve. Correlations are useful because they can indicate a predictive relationship that can be exploited in practice. For example, an electrical utility may produce less power on a mild day based on the correlation between electricity demand and weather. In this example, there is a causal relationship, because extreme weather causes people to use more electricity for heating or cooling. Howe ...
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Superconductors
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source. The superconductivity phenomenon was discovered in 1911 by Dutch physicist Heike Kamerlingh Onnes. Like ferromagnetism and atomic spectral lines, superconductivity is a phenomenon which can only be explained by quantum mechanics. It is characterized by the Meissner effect, the complete ejection of magnetic field lines from the interior of the superconductor during its transitions into the sup ...
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Fulde–Ferrell–Larkin–Ovchinnikov Phase
The Fulde–Ferrell–Larkin–Ovchinnikov (FFLO) phase (also occasionally called the Larkin–Ovchinnikov–Fulde–Ferrell phase, or LOFF) can arise in a superconductor in large magnetic field. Among its characteristics are Cooper pairs with nonzero total momentum and a spatially non-uniform order parameter, leading to normal conducting areas in the superconductor. History Two independent publications in 1964, one by Peter Fulde and Richard A. Ferrell and the other by Anatoly Larkin and Yuri Ovchinnikov, theoretically predicted a new state appearing in a certain regime of superconductors at low temperatures and in high magnetic fields. This particular superconducting state is nowadays known as the Fulde–Ferrell–Larkin–Ovchinnikov state, abbreviated FFLO state (also LOFF state). Since then, experimental observations of the FFLO state have been searched for in different classes of superconducting materials, first in thin films and later in exotic superconductors such as he ...
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Nature (journal)
''Nature'' is a British weekly scientific journal founded and based in London, England. As a multidisciplinary publication, ''Nature'' features peer-reviewed research from a variety of academic disciplines, mainly in science and technology. It has core editorial offices across the United States, continental Europe, and Asia under the international scientific publishing company Springer Nature. ''Nature'' was one of the world's most cited scientific journals by the Science Edition of the 2019 ''Journal Citation Reports'' (with an ascribed impact factor of 42.778), making it one of the world's most-read and most prestigious academic journals. , it claimed an online readership of about three million unique readers per month. Founded in autumn 1869, ''Nature'' was first circulated by Norman Lockyer and Alexander Macmillan as a public forum for scientific innovations. The mid-20th century facilitated an editorial expansion for the journal; ''Nature'' redoubled its efforts in exp ...
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Fermi Velocity
The Fermi energy is a concept in quantum mechanics usually referring to the energy difference between the highest and lowest occupied single-particle states in a quantum system of non-interacting fermions at absolute zero temperature. In a Fermi gas, the lowest occupied state is taken to have zero kinetic energy, whereas in a metal, the lowest occupied state is typically taken to mean the bottom of the conduction band. The term "Fermi energy" is often used to refer to a different yet closely related concept, the Fermi level, Fermi ''level'' (also called electrochemical potential).The use of the term "Fermi energy" as synonymous with Fermi level (a.k.a. electrochemical potential) is widespread in semiconductor physics. For example:''Electronics (fundamentals And Applications)''by D. Chattopadhyay''Semiconductor Physics and Applications''by Balkanski and Wallis. There are a few key differences between the Fermi level and Fermi energy, at least as they are used in this article: * The F ...
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Crystal Structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of the crystal are described by the con ...
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Neutron Scattering
Neutron scattering, the irregular dispersal of free neutrons by matter, can refer to either the naturally occurring physical process itself or to the man-made experimental techniques that use the natural process for investigating materials. The natural/physical phenomenon is of elemental importance in nuclear engineering and the nuclear sciences. Regarding the experimental technique, understanding and manipulating neutron scattering is fundamental to the applications used in crystallography, physics, physical chemistry, biophysics, and materials research. Neutron scattering is practiced at research reactors and spallation neutron sources that provide neutron radiation of varying intensities. Neutron diffraction (elastic scattering) techniques are used for analyzing structures; where inelastic neutron scattering is used in studying atomic vibrations and other excitations. Scattering of fast neutrons "Fast neutrons" (see neutron temperature) have a kinetic energy above ...
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Magnetic Moment
In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets), permanent magnets, elementary particles (such as electrons), various molecules, and many astronomical objects (such as many planets, some moons, stars, etc). More precisely, the term ''magnetic moment'' normally refers to a system's magnetic dipole moment, the component of the magnetic moment that can be represented by an equivalent magnetic dipole: a magnetic north and south pole separated by a very small distance. The magnetic dipole component is sufficient for small enough magnets or for large enough distances. Higher-order terms (such as the magnetic quadrupole moment) may be needed in addition to the dipole moment for extended objects. The magnetic dipole moment of an object is readily defined in terms of the torque that the objec ...
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