Torrification
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Torrification
Torrefaction of biomass, e.g., wood or grain, is a mild form of pyrolysis at temperatures typically between 200 and 320 °C. Torrefaction changes biomass properties to provide a better fuel quality for combustion and gasification applications. Torrefaction produces a relatively dry product, which reduces or eliminates its potential for organic decomposition. Torrefaction combined with densification creates an energy-dense fuel carrier of 20 to 21  GJ/ton lower heating value (LHV). Torrefaction makes the material undergo Maillard reactions. Torrefied biomass can be used as an energy carrier or as a feedstock used in the production of bio-based fuels and chemicals. Biomass can be an important energy source. However, there exists a large diversity of potential biomass sources, each with its own unique characteristics. To create efficient biomass-to-energy chains, torrefaction of biomass, combined with densification ( pelletisation or briquetting), is a promising step towa ...
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Carbonization
Carbonization is the conversion of organic matters like plants and dead animal remains into carbon through destructive distillation. Complexity in carbonization Carbonization is a pyrolytic reaction, therefore, is considered a complex process in which many reactions take place concurrently such as dehydrogenation, condensation, hydrogen transfer and isomerization. Carbonization differs from coalification in that it occurs much faster, due to its reaction rate being faster by many orders of magnitude. For the final pyrolysis temperature, the amount of heat applied controls the degree of carbonization and the residual content of foreign elements. For example, at T ~ 1200 K the carbon content of the residue exceeds a mass fraction of 90 wt.%, whereas at T ~ 1600 K more than 99 wt.% carbon is found. Carbonization is often exothermic, which means that it could in principle be made self-sustaining and be used as a source of energy that does not produce carbon dioxide. In the case ...
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Bioresource Technology
''Bioresource Technology'' is a peer reviewed scientific journal published biweekly by Elsevier, covering the field of bioresource technology. The journal was established in 1979 as ''Agricultural Wastes'' and renamed to ''Biological Wastes'' in 1987, before obtaining its current title in 1991. It covers all areas concerning biomass, biological waste treatment, bioenergy Biomass is plant-based material used as a fuel for heat or electricity production. It can be in the form of wood, wood residues, energy crops, agricultural residues, and waste from industry, farms, and households. Some people use the terms biom ..., biotransformations and bioresource systems analysis, and technologies associated with conversion or production. References External links * Elsevier academic journals Biweekly journals English-language journals Publications established in 1979 Biotechnology journals Waste management journals {{Engineering-journal-stub ...
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Dana Bourgeois
Dana Bourgeois (born 1953) is a luthier, writer, lecturer and is considered one of the United States' top acoustic guitar makers. Bourgeois's innovations in design and voicing techniques have earned him worldwide acclaim for his acoustic guitars from professional players, hobbyists and collectors alike. Some notable musicians playing Bourgeois guitars include Luke Bryan, Ricky Skaggs, Bryan Smith, Ry Cooder, Scott Fore, Bryan Sutton, Vince Gill, Lee Roy Parnell, James Taylor and Guy Clark, Background Dana Bourgeois was born and raised in Westbrook, Maine. As a child, his interest in guitars developed after seeing The Beatles on the ''Ed Sullivan Show'' in 1964. Bourgeois attended Bowdoin College, where he studied art history, and graduated in 1975. While at college, Bourgeois read a book called ''Classic Guitar Construction'' by Irving Stone, whose method in the book was, purportedly, "totally impossible." After that, Bourgeois, working from his room on campus and using a machin ...
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Fischer–Tropsch Process
The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of and pressures of one to several tens of atmospheres. The process was first developed by Franz Fischer and Hans Tropsch at the Kaiser Wilhelm Institute for Coal Research in Mülheim an der Ruhr, Germany, in 1925. As a premier example of C1 chemistry, the Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification. The process then converts these gases into synthetic oil, synthetic lubrication oil and synthetic fuel. This process has received intermittent attention as a source of low-s ...
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Lower Heating Value
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions. The chemical reaction is typically a hydrocarbon or other organic molecule reacting with oxygen to form carbon dioxide and water and release heat. It may be expressed with the quantities: * energy/mole of fuel * energy/mass of fuel * energy/volume of the fuel There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like are allowed to condense. The high heat values are conventionally measured with a bomb calorimeter. Low heat values are calculated from high heat value test data. They may also be calculated as the difference betw ...
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Liquefied Petroleum Gas
Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking equipment, and vehicles. It is increasingly used as an aerosol propellant and a refrigerant, replacing chlorofluorocarbons in an effort to reduce damage to the ozone layer. When specifically used as a vehicle fuel, it is often referred to as autogas or even just as gas. Varieties of LPG that are bought and sold include mixes that are mostly propane (), mostly butane (), and, most commonly, mixes including both propane and butane. In the northern hemisphere winter, the mixes contain more propane, while in summer, they contain more butane. In the United States, mainly two grades of LPG are sold: commercial propane and HD-5. These specifications are published by the Gas Processors Association (GPA) and the American Society of Testing and Ma ...
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Gasification
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock. An advantage of gasification is that syngas can be more efficient than direct combustion of the original feedstock material because it can be combusted at higher temperatures so that the thermodynamic upper li ...
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Coal-fired Power Station
A coal-fired power station or coal power plant is a thermal power station which burns coal to generate electricity. Worldwide, there are about 8,500 coal-fired power stations totaling over 2,000 gigawatts Nameplate capacity, capacity. They generate about a third of the Electric energy consumption, world's electricity, but cause many illnesses and early deaths, mainly from air pollution. A coal-fired power station is a type of fossil fuel power station. The coal is usually Pulverizer, pulverized and then burned in a pulverized coal-fired boiler. The furnace heat converts boiler water to steam, which is then used to spin turbines that turn electric generator, generators. Thus chemical energy stored in coal is converted successively into thermal energy, mechanical energy and, finally, electrical energy. Coal-fired power stations emit over 10 gigatonne, Gt of carbon dioxide each year, about one fifth of world greenhouse gas emissions, so are the single largest Attribution of re ...
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Co-firing
{{No footnotes, date=November 2010 Co-firing is the combustion of two (or more) different types of materials at the same time. One of the advantages of co-firing is that an existing plant can be used to burn a new fuel, which may be cheaper or more environmentally friendly. For example, biomass is sometimes co-fired in existing coal plants instead of new biomass plants. Another example is that biomass primary fuel fractions can be cofired with waste-derived fuels in biomass plants leading to an environmentally friendly destruction of waste fractions and cost-effective heat and power production. Co-firing can also be used to improve the combustion of fuels with low energy content. For example, landfill gas contains a large amount of carbon dioxide, which is non-combustible. If the landfill gas is burned without removing the carbon dioxide, the equipment may not perform properly or emissions of pollutants may increase. Co-firing it with natural gas increases the heat content of the fue ...
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Energy & Fuels
''Energy & Fuels'' is a peer-reviewed scientific journal published by the American Chemical Society. It was established in 1987. Its publication frequency switched from bimonthly to monthly in 2009. The editor-in-chief is Hongwei Wu (Curtin University). According to the American Chemical Society, ''Energy & Fuels'' publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. Editors The following are the current list of Associate Editors serving the Journal. * Anthony Dufour, The National Center for Scientific Research (CNRS) * H. Scott Fogler, University of Michigan * Praveen Linga, National University of Singapore * Anja Oasmaa, VTT Technical Research Centre of Finland Ltd. * Ah-Hyung (Alissa) Park, Columbia University * Andrew Pomerantz, Schlumberger-Doll * Luiz P. Ramos, Federal University of Parana * Ryan P. Rodgers, Florida State Universi ...
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Hydrophobic
In chemistry, hydrophobicity is the physical property of a molecule that is seemingly repelled from a mass of water (known as a hydrophobe). In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among them. Hydrophobic molecules in water often cluster together, forming micelles. Water on hydrophobic surfaces will exhibit a high contact angle. Examples of hydrophobic molecules include the alkanes, oils, fats, and greasy substances in general. Hydrophobic materials are used for oil removal from water, the management of oil spills, and chemical separation processes to remove non-polar substances from polar compounds. Hydrophobic is often used interchangeably with lipophilic, "fat-loving". However, the two terms are not synonymous. While hydrophobic substances are usually lipophilic, there are exceptions, suc ...
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Lignocellulose
Lignocellulose refers to plant dry matter (biomass), so called lignocellulosic biomass. It is the most abundantly available raw material on the Earth for the production of biofuels. It is composed of two kinds of carbohydrate polymers, cellulose and hemicellulose, and an aromatic-rich polymer called lignin. Any biomass rich in cellulose, hemicelluloses, and lignin are commonly referred to as lignocellulosic biomass. Each component has a distinct chemical behavior. Being a composite of three very different components makes the processing of lignocellulose challenging. The evolved resistance to degradation or even separation is referred to as recalcitrance. Overcoming this recalcitrance to produce useful, high value products requires a combination of heat, chemicals, enzymes, and microorganisms. These carbohydrate-containing polymers contain different sugar monomers (six and five carbon sugars) and they are covalently bound to lignin. Lignocellulosic biomass can be broadly classified ...
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