Co-firing
   HOME

TheInfoList



OR:

{{No footnotes, date=November 2010 Co-firing is the
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
of two (or more) different types of materials at the same time. One of the advantages of co-firing is that an existing plant can be used to burn a new fuel, which may be cheaper or more environmentally friendly. For example, biomass is sometimes co-fired in existing
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
plants instead of new biomass plants. Another example is that biomass primary fuel fractions can be cofired with waste-derived fuels in biomass plants leading to an environmentally friendly destruction of waste fractions and cost-effective heat and power production. Co-firing can also be used to improve the combustion of fuels with low energy content. For example, landfill gas contains a large amount of
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
, which is non-combustible. If the landfill gas is burned without removing the carbon dioxide, the equipment may not perform properly or emissions of pollutants may increase. Co-firing it with
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
increases the heat content of the fuel and improves combustion and equipment performance. As long as the
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
or
heat In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is ...
produced with the biomass and landfill gas was otherwise going to be produced with non-renewable fuels, the benefits are essentially equivalent whether they are cofired or combusted alone. Also, co-firing can be used to lower the emission of some
pollutants A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like o ...
. For example, co-firing biomass with coal results in less sulfur emissions than burning coal by itself.


Origin

Co-firing (also referred to as complementary firing or co-combustion) is the
combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...
of two different
fuels A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but ...
in the same combustion system. Fuels can be
solid fuels Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuel ...
,
liquid fuels Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable ...
or gaseous, and its source either
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
or
renewable A renewable resource, also known as a flow resource, is a natural resource which will replenish to replace the portion depleted by usage and consumption, either through natural reproduction or other recurring processes in a finite amount of ti ...
. Therefore, use of
heavy fuel oil Heavy Fuel Oil (HFO) is a category of fuel oils of a tar-like consistency. Also known as bunker fuel, or residual fuel oil, HFO is the result or remnant from the distillation and cracking process of petroleum. For this reason, HFO is contaminate ...
assisting coal power stations may technically be considered co-firing. However, the term co-firing is used in the present technological framework to designate combined combustion of two (or more) fuels sustained in time, as a normal daily practice. The interest in co-firing and the use of this term sprung up in the 1980s in the U.S. and Europe, and referred specifically to the use of
waste Waste (or wastes) are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste prod ...
solid residues (paper, plastic, solvents, tars, etc.) or biomass in
coal power station A coal-fired power station or coal power plant is a thermal power station which burns coal to generate electricity. Worldwide, there are about 8,500 coal-fired power stations totaling over 2,000 gigawatts capacity. They generate about a th ...
s that were designed only for the combustion of coal, and attempted, because of the existence of those new opportunity fuels, to carry out a combined combustion in order to increase benefit margins. This interest in co-firing has grown in the last decade mainly due to increasing social concern about
global warming In common usage, climate change describes global warming—the ongoing increase in global average temperature—and its effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes to E ...
and greenhouse gas (GHG) emissions. The consequences of this concern are new policies on energy and the environment aimed at reducing emissions. Co-firing is regarded as a great opportunity for replacing coal (solid fossil fuel) used for power generation with
renewable A renewable resource, also known as a flow resource, is a natural resource which will replenish to replace the portion depleted by usage and consumption, either through natural reproduction or other recurring processes in a finite amount of ti ...
fuels (biomass) with lower costs and a direct decrease in
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and ...
. During the last few decades research has provided very diverse solutions for co-firing biomass in coal power stations with a limited impact on efficiency, operation and lifespan. In the present context the definition of co-firing could be: The use together of two (or more) fuels, the primary being fossil and the secondary from another source (renewable or residual), in a boiler originally designed for fossil fuel, either using the original combustion system or additional devices.


Types

The concept of co-firing is quite simple. It consists in the use of two or more fuels inside the same combustion device. It is applicable to all kind of combustion systems traditionally used for power generation ( pulverized fuel,
fluidized bed combustion Fluidized bed combustion (FBC) is a combustion technology used to burn solid fuels. In its most basic form, fuel particles are suspended in a hot, bubbling fluidity bed of ash and other particulate materials (sand, limestone etc.) through which ...
and
grate firing Grate firing is a type of industrial combustion system used for solid fuels. It now is used mainly for burning waste and biomass, but also for smaller coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock st ...
). Co-firing in
cement kilns A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixe ...
is already a quite widespread solution for
valorization of waste Waste valorization, beneficial reuse, value recovery or waste reclamation is the process of waste products or residues from an economic process being valorized (given economic value), by reuse or recycling in order to create economically useful ma ...
materials mostly, as well as for biomass. The iron industry ( blast furnace) and domestic sector (coal
stoves A stove or range is a device that burns fuel or uses electricity to generate heat inside or on top of the apparatus, to be used for general warming or cooking. It has evolved highly over time, with cast-iron and induction versions being develope ...
) are also sectors where co-firing could be implemented. The use of a secondary fuel ( biomass or
waste Waste (or wastes) are unwanted or unusable materials. Waste is any substance discarded after primary use, or is worthless, defective and of no use. A by-product, by contrast is a joint product of relatively minor economic value. A waste prod ...
) replacing a share of the original fossil fuel may require trivial changes in the facility, or a complete
retrofitting Retrofitting is the addition of new technology or features to older systems. Retrofits can happen for a number of reasons, for example with big capital expenditures like naval vessels, military equipment or manufacturing plants, businesses or go ...
with important reforms. Modifications will depend on the characteristics of the fuels, the original combustion technology, the plant layout and the type and location of auxiliary systems. The percentage of original fuel replaced, also known as co-firing rate (either expressed in mass or in energy basis) is furthermore a definitive parameter limiting the technical solutions valid for a specific plant. The co-firing systems, according to the current state of the art and the future perspectives, can be classified into direct and indirect co-firing technologies. The former refer to those systems where combustion of both fuels takes place at the same combustion device or into the same boiler simultaneously. The secondary fuel (biomass, waste) may be either mixed with coal before the combustion starts or fed by a separate device, e.g. specific biomass burners. Indirect co-firing, on the contrary, separates the combustion of both solid fuels, though
Combustion Gas Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
ses may be mixed afterwards. Direct biomass co-firing systems entail advantages of simplicity and economics. However direct co-firing systems are also more sensitive to variations in fuel quality and heterogeneity. Additionally other problems limit the rate of secondary fuel replacing the original fossil fuels. In example ash deposition (
fouling Fouling is the accumulation of unwanted material on solid surfaces. The fouling materials can consist of either living organisms ( biofouling) or a non-living substance (inorganic or organic). Fouling is usually distinguished from other sur ...
and slagging) and corrosion usually increase with the use of biomass and wastes replacing coal, what may shorten the lifespan of diverse devices in contact with
Combustion Gas Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion ...
ses like superheaters,
heat exchangers A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct conta ...
,
selective catalytic reduction Selective catalytic reduction (SCR) is a means of converting nitrogen oxides, also referred to as with the aid of a catalyst into diatomic nitrogen (), and water (). A reductant, typically anhydrous ammonia (), aqueous ammonia (), or a urea () ...
(SCR), etc. Direct co-firing systems include next technological solutions: * ''Co-milling'' (in case of solid fuels): blending of primary (coal) and secondary (biomass or waste) fuel, combined milling (in original system) and injection through the coal burners (or feeding system) * ''Co-feeding:'' separate treatment of primary and secondary fuels (milling in case of solid fuels), and incorporation of secondary fuel to the main flow. In case of solid fuels the mixture takes place downstream the coal mill. * ''Combined burner:'' fuels are treated separately (milled in case of solid fuels) and transported to the burner, where primary fuel uses the original ports and secondary fuel uses new ports or unused ducts. In this case, though feeding does not involve fuel physical mixing, combustion stages takes place simultaneously and with similar aerodynamics to original design. * ''New burners:'' fuels use independent feeding lines. Primary fuel uses original injection system, whereas secondary fuel is transported to specific dedicated burners or inlet ports penetrating into the combustion chamber. New burners (injection systems) may replace former burners of primary fossil fuel, or may be installed in new positions in the combustion chamber. This option may involve the use of different combustion systems. For example, in a pulverized coal power station a grate firing system may be installed at the bottom of the combustion chamber, though this solution is rare. Indirect co-firing systems imply usually more complex and expensive solutions, but they reduce usually problems related with corrosion, fouling, slagging, etc. This, a priori, allows co-firing rates larger than direct systems, that is, larger percentages of coal substituted by biomass or waste. In addition, indirect co-firing systems are in general better for fuel mixtures where secondary fuel may include potential contaminants like heavy metals or other dangerous inorganic compounds. Main indirect co-firing systems are listed next: * ''Separated burning:'' burning of secondary fuel in a separate boiler or system and introduction of flue gases downstream the radiant section of the original boiler. * ''Coupled plant:'' separate burning in a new boiler specially designed and built for firing the secondary fuel. Original and new system couple their heating fluid circuits. Combustion gases are not mixed and
Exhaust gas Exhaust gas or flue gas is emitted as a result of the combustion of fuels such as natural gas, gasoline (petrol), diesel fuel, fuel oil, biodiesel blends, or coal. According to the type of engine, it is discharged into the atmosphere through an ...
must be treated separately. * '' Gasification systems:'' the secondary fuel is transformed into gas (with
heating value The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy relea ...
) by means of a
gasifier Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reactin ...
. The resulting syngas is either directly or with a previous treatment, injected in the original combustion chamber or boiler through new dedicated ducts. * ''
Pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
:'' biomass is transformed into a mixture of gas, bio-oils and char by means of
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
. Fractions may be separated and introduced into the boiler in different sites.


Advantages of co-firing

Use of biomass in co-firing incorporate additional environmental, socio-economic and strategy advantages regarding the use of biomass in dedicated biomass plants. In case of waste residues there are no additional benefits, however the combustion of waste may change the emissions regulations to satisfy more strict regulations. For example, limits in emissions from environmental regulations for large scale combustion facilities are more permissive than regulations for incineration plants. Except for the previous drawback related to waste co-firing, the following advantages are common for waste and biomass co-firing: * ''Specific investment (per unit of installed power):'' reduced in comparison with conventional biomass facilities since plant using fossil fuel already exists and only diverse modifications are required * ''Power generation with better efficiency:'' generally biomass power plants produce electricity with relative low efficiency (18 to 22%) compared with the huge coal units (32 to 38%) with optimised cycles given the economy of scale * ''Flexible operation:'' original plant can operate still at 100% load with fossil fuel. Co-firing facility is less sensitive to seasonality in biomass production and to biomass availability and price * ''Carrot for development of biomass markets:'' diverse European countries have proven the promotion of co-firing is a key for the development of biomass markets as well as for the creation of expertise on biomass handling and combustion


External links


USDOE United States Department of EnergyIEA - International Energy Agency
* ttp://www.icrepq.com/pdfs/PL2.%20VALERO.pdf CIRCE - Co-firing of low rank coal and biomass: a chance for biomass penetration in the renewablesbr>Janne Kärki et al., Toward Carbon-Negative Power Plants With Biomass Cofiring and CCS
Combustion Incineration