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TiO2
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index International, CI 77891. It is a white solid that is insoluble to water, although mineral forms can appear black. As a pigment, it has a wide range of applications, including paint, sunscreen, and food coloring. When used as a food coloring, it has E number E171. World production in 2014 exceeded 9 million tonnes. It has been estimated that titanium dioxide is used in two-thirds of all pigments, and pigments based on the oxide have been valued at a price of $13.2 billion. Structure In all three of its main dioxides, titanium exhibits octahedral geometry, being bonded to six oxide anions. The oxides in turn are bonded to three Ti centers. The overall crystal structure of rutile is tetragonal in symmetry whereas anatase and brookite are orthorhombic. The oxygen substructu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titanic Acid
Titanic acid is a general name for a family of chemical compounds of the elements titanium, hydrogen, and oxygen, with the general formula . Various simple titanic acids have been claimed, mainly in the older literature. No crystallographic and little spectroscopic support exists for these materials. Some older literature including Brauer's Handbook refers to as titanic acid. *''Metatitanic acid'' (), *''Orthotitanic acid'' () or . It is described as a white salt-like powder under "". *''Peroxotitanic acid'' () has also been described as resulting from the treatment of titanium dioxide in sulfuric acid with hydrogen peroxide. The resulting yellow solid decomposes with loss of . *''Pertitanic acid'' () *''Pertitanic acid'' () References Further reading * Titanium(IV) compounds Hydroxides Transition metal oxoacids {{Inorganic-compound-stub he:חומצה טיטנית ru:Титанаты ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Thin films of TiO2-coated glass show antifogging and self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a transforma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zirconium Dioxide
Zirconium dioxide (), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the mineral baddeleyite. A dopant stabilized cubic structured zirconia, cubic zirconia, is synthesized in various colours for use as a gemstone and a diamond simulant. Production, chemical properties, occurrence Zirconia is produced by calcining zirconium compounds, exploiting its high thermostability.Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. Structure Three phases are known: monoclinic below 1170 °C, tetragonal between 1170 °C and 2370 °C, and cubic above 2370 °C. The trend is for higher symmetry at higher temperatures, as is usually the case. A small percentage of the oxides of calcium or yttrium stabilize in the cubic phase. The very rare mineral tazheranite, , ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anatase Crystal Structure
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Thin films of TiO2-coated glass show antifogging and self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a transforma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics. Structure and properties Ilmenite is a heavy (specific gravity 4.7), moderately hard (Mohs hardness 5.6 to 6), opaque black mineral with a submetallic luster. It is almost always massive, with thick tabular crystals being quite rare. It shows no discernible cleavage, breaking instead with a conchoidal to uneven fracture. Ilmenite crystallizes in the trigonal system with space group ''R''. The ilmenite crystal structure consists of an ordered derivative of the corundum structure; in corundum all cations are identical but in ilmenite Fe2+ and Ti4+ ions occupy alternating layers perpendicular to the trigonal c axis. Pure ilmenite is paramagnetic (showing only very weak attrac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) of titanium dioxide are known to occur naturally: brookite, akaogiite, and rutile, with rutile being the most common and most stable of the bunch. Anatase is formed at relatively low temperatures and found in minor concentrations in igneous and metamorphic rocks. Thin films of TiO2-coated glass show antifogging and self-cleaning properties under ultraviolet radiation. Anatase is always found as small, isolated, and sharply developed crystals, and like rutile, it crystallizes in a tetragonal system. Anatase is metastable at all temperatures and pressures, with rutile being the equilibrium polymorph. Nevertheless, anatase is often the first titanium dioxide phase to form in many processes due to its lower surface energy, with a transforma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Close Packing
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occupied by spheres – that can be achieved by a lattice packing is :\frac \approx 0.74048. The same packing density can also be achieved by alternate stackings of the same close-packed planes of spheres, including structures that are aperiodic in the stacking direction. The Kepler conjecture states that this is the highest density that can be achieved by any arrangement of spheres, either regular or irregular. This conjecture was proven by T. C. Hales. Highest density is known only for 1, 2, 3, 8, and 24 dimensions. Many crystal structures are based on a close-packing of a single kind of atom, or a close-packing of large ions with smaller ions filling the spaces between them. The cubic and hexagonal arrangements are very close to one anoth ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rutile Structure
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially polarization optics, for longer visible and infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum. Rutile derives its name from the Latin ('red'), in reference to the deep red color observed in some specimens when viewed by transmitted light. Rutile was first described in 1803 by Abraham Gottlob Werner. Occurrence Rutile is a common accessory mineral in high-temperature and high-pressure metamorphic rocks and in igneous rocks. Thermodynamically, ru ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive index, refractive indices at visible wavelengths of any known crystal and also exhibits a particularly large birefringence and high dispersion (optics), dispersion. Owing to these properties, it is useful for the manufacture of certain optical elements, especially Polarization (waves), polarization optics, for longer light, visible and infrared, infrared wavelengths up to about 4.5 micrometres. Natural rutile may contain up to 10% iron and significant amounts of niobium and tantalum. Rutile derives its name from the Latin ('red'), in reference to the deep red color observed in some specimens when viewed by transmitted light. Rutile was first described in 1803 by Abraham Gottlob Werner. Occurrence Rutile is a common accessory ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Leucoxene
Leucoxene is a fine granular alteration product of titanium minerals. It varies in color from yellow to brown. It consists mainly of rutile or anatase. It is observed in some igneous rocks and iron ore deposits as the result of the alteration of ilmenite, perovskite, or titanite Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals .... References * Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Mindat.org Oxide minerals {{oxide-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ruby
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphires. Ruby is one of the traditional cardinal gems, alongside amethyst, sapphire, emerald, and diamond. The word ''ruby'' comes from ''ruber'', Latin for red. The color of a ruby is due to the element chromium. Some gemstones that are popularly or historically called rubies, such as the Black Prince's Ruby in the British Imperial State Crown, are actually spinels. These were once known as "Balas rubies". The quality of a ruby is determined by its color, cut, and clarity, which, along with carat weight, affect its value. The brightest and most valuable shade of red, called blood-red or pigeon blood, commands a large premium over other rubies of similar quality. After color follows clarity: similar to diamonds, a clear stone will com ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
