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Thermoelectric Battery
A thermoelectric battery stores energy when charged by converting heat into chemical energy and produces electricity when discharged. Such systems potentially offer an alternative means of disposing of waste heat from plants that burn fossil fuels and/or nuclear energy. History Thomas Johann Seebeck (1780-1831) discovered the thermoelectric effect in 1821. The symmetrical Peltier effect ( Jean Charles Athanse Peltier, 1785-1845) uses an electric current to produce temperature differences. In the middle part of the twentieth century the thermo-electric generator was often used in place of galvanic batteries. Copper/ammonia In 2014 researchers demonstrated a prototype system that uses copper electrodes and ammonia as the electrolyte. The device converted some 29 percent of the battery's chemical energy into electricity. The ammonia electrolyte is only used as an anolyte (electrolyte surrounding an anode) that reacts with the copper electrode as waste heat warms the ammoni ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Energy
Chemical energy is the energy of chemical substances that is released when they undergo a chemical reaction and transform into other substances. Some examples of storage media of chemical energy include batteries, Schmidt-Rohr, K. (2018). "How Batteries Store and Release Energy: Explaining Basic Electrochemistry", ''J. Chem. Educ.'' 95: 1801-1810. http://dx.doi.org/10.1021/acs.jchemed.8b00479 food, and gasoline (as well as oxygen gas, which is of high chemical energy due to its relatively weak double bond and indispensable for chemical-energy release in gasoline combustion). Schmidt-Rohr, K. (2015). "Why Combustions Are Always Exothermic, Yielding About 418 kJ per Mole of O2", ''J. Chem. Educ.'' 92: 2094-2099. http://dx.doi.org/10.1021/acs.jchemed.5b00333 Breaking and re-making of chemical bonds involves energy, which may be either absorbed by or evolved from a chemical system. If reactants with relatively weak electron-pair bonds convert to more strongly bonded products, energ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Waste Heat
Waste heat is heat that is produced by a machine, or other process that uses energy, as a byproduct of doing work. All such processes give off some waste heat as a fundamental result of the laws of thermodynamics. Waste heat has lower utility (or in thermodynamics lexicon a lower exergy or higher entropy) than the original energy source. Sources of waste heat include all manner of human activities, natural systems, and all organisms, for example, incandescent light bulbs get hot, a refrigerator warms the room air, a building gets hot during peak hours, an internal combustion engine generates high-temperature exhaust gases, and electronic components get warm when in operation. Instead of being "wasted" by release into the ambient environment, sometimes waste heat (or cold) can be used by another process (such as using hot engine coolant to heat a vehicle), or a portion of heat that would otherwise be wasted can be reused in the same process if make-up heat is added to the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thomas Johann Seebeck
Thomas Johann Seebeck (; 9 April 1770 – 10 December 1831) was a Baltic German physicist, who, in 1822, observed a relationship between heat and magnetism. Later, in 1823, Ørsted called this phenomenon thermoelectric effect. Seebeck was born in Reval (today Tallinn) to a wealthy Baltic German merchant family. He received a medical degree in 1802 from the University of Göttingen, but preferred to study physics. From 1821 to 1823, Seebeck performed a series of experiments trying to understand Ørsted's findings from 1820. During his experiments, he observed that a junction of dissimilar metals produces a deflexion on a magnetic needle (compass) when exposed to a temperature gradient. Because Ørsted had discovered that an electric current produces a deflexion on a compass transversal to the wire, Seebeck's results were interpreted as a thermoelectric effect. This is now called the Peltier–Seebeck effect and is the basis of thermocouples and thermopiles. Seebeck effect In ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermoelectric Effect
The thermoelectric effect is the direct conversion of temperature differences to electric voltage and vice versa via a thermocouple. A thermoelectric device creates a voltage when there is a different temperature on each side. Conversely, when a voltage is applied to it, heat is transferred from one side to the other, creating a temperature difference. At the atomic scale, an applied temperature gradient causes charge carriers in the material to diffuse from the hot side to the cold side. This effect can be used to generate electricity, measure temperature or change the temperature of objects. Because the direction of heating and cooling is affected by the applied voltage, thermoelectric devices can be used as temperature controllers. The term "thermoelectric effect" encompasses three separately identified effects: the Seebeck effect, Peltier effect, and Thomson effect. The Seebeck and Peltier effects are different manifestations of the same physical process; textbooks may re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Peltier Effect
The thermoelectric effect is the direct conversion of temperature differences to electric voltage and vice versa via a thermocouple. A thermoelectric device creates a voltage when there is a different temperature on each side. Conversely, when a voltage is applied to it, heat is transferred from one side to the other, creating a temperature difference. At the atomic scale, an applied temperature gradient causes charge carriers in the material to diffuse from the hot side to the cold side. This effect can be used to generate electricity, measure temperature or change the temperature of objects. Because the direction of heating and cooling is affected by the applied voltage, thermoelectric devices can be used as temperature controllers. The term "thermoelectric effect" encompasses three separately identified effects: the Seebeck effect, Peltier effect, and Thomson effect. The Seebeck and Peltier effects are different manifestations of the same physical process; textbooks may re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Jean Charles Athanase Peltier
Jean Charles Athanase Peltier (; ; 22 February 1785 – 27 October 1845) was a French physicist. He was originally a watch dealer, but at the age of 30 began experiments and observations in physics. Peltier was the author of numerous papers in different departments of physics. His name is specially associated with the thermal effects at junctions in a voltaic circuit, the Peltier effect. Peltier introduced the concept of electrostatic induction (1840), based on the modification of the distribution of electric charge in a material under the influence of a second object closest to it and its own electrical charge. Biography Peltier trained as a watchmaker; until his 30s was a watch dealer. Peltier worked with Abraham Louis Breguet in Paris. Later, he worked with various experiments on electrodynamics and noticed that in an electronic element when current flows through, a temperature gradient or temperature difference is generated at a current flow. In 1836 he published his wor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Galvanic Cell
A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous Oxidation-Reduction reactions. A common apparatus generally consists of two different metals, each immersed in separate beakers containing their respective metal ions in solution that are connected by a salt bridge or separated by a porous membrane. Volta was the inventor of the voltaic pile, the first Battery (electricity), electrical battery. In common usage, the word "battery" has come to include a single galvanic cell, but a battery properly consists of multiple cells. History In 1780, Luigi Galvani discovered that when two different metals (e.g., copper and zinc) are in contact and then both are touched at the same time to two different parts of a muscle of a frog leg, to close the circuit, the frog's leg contracts. He called this "bioelectricity, animal electricity". The frog ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrolyte
An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout the solvent. Solid-state electrolytes also exist. In medicine and sometimes in chemistry, the term electrolyte refers to the substance that is dissolved. Electrically, such a solution is neutral. If an electric potential is applied to such a solution, the cations of the solution are drawn to the electrode that has an abundance of electrons, while the anions are drawn to the electrode that has a deficit of electrons. The movement of anions and cations in opposite directions within the solution amounts to a current. Some gases, such as hydrogen chloride (HCl), under conditions of high temperature or low pressure can also function as electrolytes. El ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Anolyte
Electrolysed water (electrolyzed water, EOW, ECA, electrolyzed oxidizing water, electro-activated water or electro-chemically activated water solution) is produced by the electrolysis of ordinary tap water containing dissolved sodium chloride. The electrolysis of such salt solutions produces a solution of hypochlorous acid and sodium hydroxide. The resulting water can be used as a disinfectant. Creation The electrolysis occurs in a specially designed reactor which allows the separation of the cathodic and anodic solutions. In this process, hydrogen gas and hydroxide ions can be produced at the cathode, leading to an alkaline solution that consists essentially of sodium hydroxide. At the anode, chloride ions can be oxidized to elemental chlorine, which is present in acidic solution and can be corrosive to metals. If the solution near the anode is acidic then it will contain elemental chlorine, if it is alkaline then it will comprise sodium hydroxide. The key to delivering a p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Power Density
Power density is the amount of power (time rate of energy transfer) per unit volume. In energy transformers including batteries, fuel cells, motors, power supply units etc., power density refers to a volume, where it is often called volume power density, expressed as W/m3. In reciprocating internal combustion engines, power density (power per swept volume or brake horsepower per cubic centimeter) is an important metric, based on the ''internal'' capacity of the engine, not its external size. Examples See also *Surface power density, energy per unit of area *Energy density, energy per unit volume * Specific energy, energy per unit mass * Power-to-weight ratio/specific power, power per unit mass **Specific absorption rate Specific absorption rate (SAR) is a measure of the rate at which energy is absorbed per unit mass by a human body when exposed to a radio frequency (RF) electromagnetic field. It can also refer to absorption of other forms of energy by tissue, inc ... ( ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Telluride (chemistry)
The telluride ion is the anion Te2− and its derivatives. It is analogous to the other chalcogenide anions, the lighter O2−, S2−, and Se2−, and the heavier Po2−. In principle, Te2− is formed by the two-e− reduction of tellurium. The redox potential is −1.14 V. :Te(s) + 2 e− ↔ Te2− Although solutions of the telluride dianion have not been reported, soluble salts of bitelluride (TeH−) are known. Organic tellurides ''Tellurides'' also describe a class of organotellurium compounds formally derived from Te2−. An illustrative member is dimethyl telluride, which results from the methylation of telluride salts: :2 CH3I + Na2Te → (CH3)2Te + 2 NaI Dimethyl telluride is formed by the body when tellurium is ingested. Such compounds are often called telluroethers because they are structurally related to ethers with tellurium replacing oxygen, although the length of the C–Te bond is much longer than a C–O bond. C–Te–C angles tend to be close ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fulvalene
Fulvalene (bicyclopentadienylidene) is the member of the fulvalene family with the molecular formula C10H8. It is of theoretical interest as one of the simplest non-benzenoid conjugated hydrocarbons. Fulvalene is an unstable isomer of the more common benzenoid aromatic compounds naphthalene and azulene. Fulvalene consists of two 5-membered rings, each with two double bonds, joined by yet a fifth double bond. It has D2h symmetry. History An earlier attempt at synthesis of fulvalene in 1951 by Pauson and Kealy resulted in the accidental discovery of ferrocene. Its synthesis was first reported in 1958 by E. A. Matzner, working under William von Eggers Doering. In this method, cyclopentadienyl anion is coupled with iodine to the dihydrofulvalene. Double deprotonation of dihydrofulvalene with ''n''-butyllithium gives the dilithio derivative, which oxidizes with oxygen. Fulvalene was spectroscopically observed at from photolysis of diazocyclopentadiene, which induces dimer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
