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Tribofilm
Tribofilms (boundary lubricant films, boundary lubricating films, tribo-boundary films or boundary films) are films that form on tribologically stressed surfaces. Tribofilms are mostly solid surface films that result from a chemical reaction of lubricant components or tribological surfaces. Tribofilms play an important role in reducing friction and wear in lubricated systems. They form as a result of complex mechanochemical interactions between surface materials and lubricants, and the study of tribofilm formation processes is a major field of tribology. Generally, a tribofilm is any film that forms in a tribosystem "as a result of interaction Interaction is action that occurs between two or more objects, with broad use in philosophy and the sciences. It may refer to: Science * Interaction hypothesis, a theory of second language acquisition * Interaction (statistics) * Interactions o ... between chemical components of the ubricantwith the lubricated surface". The term is mos ...
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Tribology
Tribology is the science and engineering of interacting surfaces in relative Motion (physics), motion. It includes the study and application of the principles of friction, lubrication and wear. Tribology is highly interdisciplinary, drawing on many academic fields, including physics, chemistry, materials science, mathematics, biology and engineering. People who work in the field of tribology are referred to as ''tribologists''. The fundamental objects of study in tribology are tribosystems, which are physical systems of contacting surfaces. In lubricated tribosystems, contact stress can create tribofilms. Subfields of tribology include biotribology, nanotribology, space tribology and tribotronics. Etymology The word ''tribology'' derives from the Ancient Greek, Greek root τριβ- of the verb , ''wiktionary:tribo-, tribo'', "I rub" in classic Greek, and the suffix ''-logy'' from , ''wiktionary:-logia, -logia'' "study of", "knowledge of". Peter Jost coined the word in 1966, in t ...
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Tribology
Tribology is the science and engineering of interacting surfaces in relative Motion (physics), motion. It includes the study and application of the principles of friction, lubrication and wear. Tribology is highly interdisciplinary, drawing on many academic fields, including physics, chemistry, materials science, mathematics, biology and engineering. People who work in the field of tribology are referred to as ''tribologists''. The fundamental objects of study in tribology are tribosystems, which are physical systems of contacting surfaces. In lubricated tribosystems, contact stress can create tribofilms. Subfields of tribology include biotribology, nanotribology, space tribology and tribotronics. Etymology The word ''tribology'' derives from the Ancient Greek, Greek root τριβ- of the verb , ''wiktionary:tribo-, tribo'', "I rub" in classic Greek, and the suffix ''-logy'' from , ''wiktionary:-logia, -logia'' "study of", "knowledge of". Peter Jost coined the word in 1966, in t ...
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Zinc Dithiophosphate
Zinc dialkyldithiophosphates (often referred to as ZDDP) are a family of coordination compounds developed in the 1940s that feature zinc bound to the anion of a dialkyldithiophosphoric salt (e.g., ammonium diethyl dithiophosphate). These uncharged compounds are not salts. They are soluble in nonpolar solvents, and the longer-chain derivatives easily dissolve in mineral and synthetic oils used as lubricants. They come under CAS number . In aftermarket oil additives, the percentage of ZDDP ranges approximately between 2 and 15%. Zinc dithiophosphates have many names, including ZDDP, ZnDTP, and ZDP. Applications The main application of ZDDPs are as anti-wear additives in lubricants including greases, hydraulic oils, and motor oils. ZDDPs also act as corrosion inhibitors and antioxidants. They are almost ubiquitous in lubricants, and treatment rates are usually between 600 ppm for modern, energy-conserving low-viscosity oils to 2000 ppm of this additive in some racing oils. It ha ...
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Solid
Solid is one of the State of matter#Four fundamental states, four fundamental states of matter (the others being liquid, gas, and Plasma (physics), plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural rigidity and resistance to a force applied to the surface. Unlike a liquid, a solid object does not flow to take on the shape of its container, nor does it expand to fill the entire available volume like a gas. The atoms in a solid are bound to each other, either in a regular geometric lattice (crystal, crystalline solids, which include metals and ordinary ice), or irregularly (an amorphous solid such as common window glass). Solids cannot be compressed with little pressure whereas gases can be compressed with little pressure because the molecules in a gas are loosely packed. The branch of physics that deals with solids is called solid-state physics, and is the main branch of condens ...
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Lubricant
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity. In addition to industrial applications, lubricants are used for many other purposes. Other uses include cooking (oils and fats in use in frying pans, in baking to prevent food sticking), bioapplications on humans (e.g. lubricants for artificial joints), ultrasound examination, medical examination, and sexual intercourse. It is mainly used to reduce friction and to contribute to a better and efficient functioning of a mechanism. History Lubricants have been in some use for thousands of years. Calcium soaps have been identified on the axles of chariots dated to 1400 BC. Building stones were slid on oil-impregrated lumb ...
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Mechanochemistry
Mechanochemistry (or mechanical chemistry) is the initiation of chemical reactions by mechanical phenomena. Mechanochemistry thus represents a fourth way to cause chemical reactions, complementing thermal reactions in fluids, photochemistry, and electrochemistry. Conventionally mechanochemistry focuses on the transformations of covalent bonds by mechanical force. Not covered by the topic are many phenomena: phase transitions, dynamics of biomolecules (docking, folding), and sonochemistry. Mechanochemistry is not the same as mechanosynthesis, which refers specifically to the machine-controlled construction of complex molecular products. In natural environments, mechanochemical reactions are frequently induced by physical processes such as earthquakes, glacier movement or hydraulic action of rivers or waves. In extreme environments such as subglacial lakes, hydrogen generated by mechnochemical reactions involving crushed silicate rocks and water can support methanogenic microbial com ...
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Tribosystem
A tribosystem is a tribological system that consists of at least two contacting bodies and any environmental factor that affects their interaction. Tribologists study tribological systems in detail, and devise tribological test procedures. Definition According tASTM G40-17 a tribosystem is "any system that contains one or more triboelements, including all mechanical, chemical, and environmental factors relevant to tribological behavior." Here, ''triboelement'' refers to "one of two or more solid bodies that comprise a sliding, rolling, or abrasive contact, or a body subjected to impingement or cavitation." More simply speaking, a tribosystem is a tribological system that consists of at least two contacting bodies, including the environment in which the interaction takes place. The complete description of a tribosystem includes all relevant factors that govern the tribological behavior of the system. Thus, depending on the aim of the tribological analysis, the tribosystem boundar ...
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Chemical Bond
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of electrons as in covalent bonds. The strength of chemical bonds varies considerably; there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force and hydrogen bonding. Strong chemical bonding arises from the sharing or transfer of electrons between the participating atoms. Since opposite electric charges attract, the negatively charged electrons surrounding the nucleus and the positively charged protons within a nucleus attract each other. An electron positioned between two nuclei will be attracted to both of them, and the nuclei will be attracted toward electrons in this position. This attraction constitu ...
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